Magnetic moments and exchange splitting in Mn3s and Mn2p core levels of magnetocaloric Mn1.1Fe0.9P0.6As0.4 and Mn1.1Fe0.9P0.5As0.4Si0.1 compounds

2018 ◽  
Vol 549 ◽  
pp. 127-132
Author(s):  
Jerzy Kubacki ◽  
Ms. Katrzyna Balin ◽  
Marek Kulpa ◽  
Łukasz Hawełek ◽  
Patryk Włodarczyk ◽  
...  
Keyword(s):  
Magnetic Moments ◽  
Exchange Splitting

The effect of Tin additionon on Structural and magnetic properties of the stannoferrite Li0.5+0.5XFe2.5-1.5XSnXO4

2016 ◽  
Vol 12 (3) ◽  
pp. 4307-4321 ◽  
Author(s):  
Ahmed Hassan Ibrahim ◽  
Yehia Abbas
Keyword(s):  
Particle Size ◽  
Fine Particles ◽  
Magnetic Moments ◽  
Lithium Ferrite ◽  
Tem Analysis ◽  
Weiss Temperature ◽  
X Ray ◽  
Two Phases ◽  
Nanocrystalline Ferrite ◽  
20 Nm

The physical properties of ferrites are verysensitive to microstructure, which in turn critically dependson the manufacturing process.Nanocrystalline Lithium Stannoferrite system Li0.5+0.5XFe2.5-1.5XSnXO4,X= (0, 0.2, 0.4, 0.6, 0.8 and 1.0) fine particles were successfully prepared by double sintering ceramic technique at pre-sintering temperature of 500oC for 3 h andthepre-sintered material was crushed and sintered finally in air at 1000oC.The structural and microstructural evolutions of the nanophase have been studied using X-ray powder diffraction (XRD) and the Rietveld method.The refinement results showed that the nanocrystalline ferrite has a two phases of ordered and disordered phases for polymorphous lithium Stannoferrite.The particle size of as obtained samples were found to be ~20 nm through TEM that increases up to ~ 85 nmand isdependent on the annealing temperature. TEM micrograph reveals that the grains of sample are spherical in shape. (TEM) analysis confirmed the X-ray results.The particle size of stannic substituted lithium ferrite fine particle obtained from the XRD using Scherrer equation.Magneticmeasurements obtained from lake shore’s vibrating sample magnetometer (VSM), saturation magnetization ofordered LiFe5O8 was found to be (57.829 emu/g) which was lower than disordered LiFe5O8(62.848 emu/g).Theinterplay between superexchange interactions of Fe3+ ions at A and B sublattices gives rise to ferrimagnetic ordering of magnetic moments,with a high Curie-Weiss temperature (TCW ~ 900 K).

Negative magnetoresistance in insulating CdSe and localized magnetic moments

2008 ◽  
Vol 33 (4) ◽  
pp. 351-356
Author(s):  
Rachid Abdia ◽  
Ablehamid El Kaaouachi ◽  
Abdelhakim Nafidi ◽  
Gérard Biskupski ◽  
Jamal Hemine
Keyword(s):  
Magnetic Moments ◽  
Negative Magnetoresistance

Coordination Compounds of Some 3d-Transition Metal Ions with N1-[4-(4-bromo-phenylsulfonyl)-benzoyl]-N4-(4-methoxyphenyl)- thiosemicarbazide

2008 ◽  
Vol 59 (7) ◽  
Author(s):  
Madalina Angelusiu ◽  
Maria Negoiu ◽  
Stefania-Felicia Barbuceanu ◽  
Tudor Rosu
Keyword(s):  
Coordination Compounds ◽  
Magnetic Moments ◽  
Thermo Gravimetric Analysis ◽  
Electronic Spectroscopy ◽  
Transition Metal Ions ◽  
Synthesis And Characterization ◽  
Gravimetric Analysis ◽  
Thermo Gravimetric ◽  
New Compounds

The paper presents the synthesis and characterization of Cu(II), Co(II), Ni(II), Cd(II), Zn(II) and Hg(II) complexes with N1-[4-(4-bromo-phenylsulfonyl)-benzoyl]-N4-(4-methoxyphenyl)-thiosemicarbazide. The new compounds were characterized by IR, EPR, electronic spectroscopy, magnetic moments, thermo-gravimetric analysis and elemental analysis.

Electron Spin Decoherence by Nuclei

2018 ◽  
Author(s):  
M. M. Glazov
Keyword(s):  
Electron Spin ◽  
Spin Dynamics ◽  
Magnetic Moments ◽  
Host Lattice ◽  
Spin Model ◽  
Relaxation Processes ◽  
Nuclear Spins ◽  
Model Calculations ◽  
Spin Decoherence ◽  
Quantum Mechanical Approach

The discussion of the electron spin decoherence and relaxation phenomena via the hyperfine interaction with host lattice spins is presented here. The spin relaxation processes processes limit the conservation time of spin states as well as the response time of the spin system to external perturbations. The central spin model, where the spin of charge carrier interacts with the bath of nuclear spins, is formulated. We also present different methods to calculate the spin dynamics within this model. Simple but physically transparent semiclassical treatment where the nuclear spins are considered as largely static classical magnetic moments is followed by more advanced quantum mechanical approach where the feedback of electron spin dynamics on the nuclei is taken into account. The chapter concludes with an overview of experimental data and its comparison with model calculations.

Dynamical Nuclear Polarization

2018 ◽  
Author(s):  
M. M. Glazov
Keyword(s):  
Spin Polarization ◽  
Nuclear Spin ◽  
Nuclear Polarization ◽  
Magnetic Moments ◽  
Nonlinear Effects ◽  
Many Body ◽  
Nuclear Spin Polarization ◽  
Optical Resonances ◽  
Dynamical Nuclear Polarization ◽  
Temperature Concept

The transfer of nonequilibrium spin polarization between the electron and nuclear subsystems is studied in detail. Usually, a thermal orientation of nuclei in magnetic field is negligible due to their small magnetic moments, but if electron spins are optically oriented, efficient nuclear spin polarization can occur. The microscopic approach to the dynamical nuclear polarization effect based on the kinetic equation method, along with a phenomenological but very powerful description of dynamical nuclear polarization in terms of the nuclear spin temperature concept is given. In this way, one can account for the interaction between neighbouring nuclei without solving a complex many-body problem. The hyperfine interaction also induces the feedback of polarized nuclei on the electron spin system giving rise to a number of nonlinear effects: bistability of nuclear spin polarization and anomalous Hanle effect, dragging and locking of optical resonances in quantum dots. Theory is illustrated by experimental data on dynamical nuclear polarization.

Magnetic Volume Effect of Hydrogen Diffusion in Palladium

2020 ◽  
Vol 310 ◽  
pp. 29-33
Author(s):  
Sarantuya Nasantogtokh ◽  
Xin Cui ◽  
Zhi Ping Wang
Keyword(s):  
Transition Metal ◽  
Density Of States ◽  
Density Functional ◽  
Hydrogen Diffusion ◽  
Magnetic Moments ◽  
Interstitial Site ◽  
Volume Effect ◽  
Face Centered Cubic ◽  
Hydrogen Atoms ◽  
Octahedral Interstitial Site

The electronic and magnetic properties of palladium hydrogen are investigated using first-principles spin-polarized density functional theory. By studying the magnetic moments and electronic structures of hydrogen atoms diffusing in face-centered cubic structure of transition metal Pd, we found that the results of magnetic moments are exactly the same in the two direct octahedral interstitial site-octahedral interstitial site diffusion paths-i.e. the magnetic moments are the largest in the octahedral interstitial site, and the magnetic moments are the lowest in saddle point positions. We also studied on the density of states of some special points, with the result that the density of states near the Fermi level is mainly contributed by 4d electrons of Pd and the change of magnetic moments with the cell volume in the unit cell of transition metal Pd with a hydrogen atom.

scholarly journals 3D Metal–Organic Frameworks Based on Co(II) and Bithiophendicarboxylate: Synthesis, Crystal Structures, Gas Adsorption, and Magnetic Properties

Molecules ◽  
2021 ◽  
Vol 26 (5) ◽  
pp. 1269
Author(s):  
Vadim A. Dubskikh ◽  
Anna A. Lysova ◽  
Denis G. Samsonenko ◽  
Alexander N. Lavrov ◽  
Konstantin A. Kovalenko ◽  
...  
Keyword(s):  
Room Temperature ◽  
Gas Adsorption ◽  
Magnetic Moments ◽  
Bet Surface Area ◽  
Separation Performance ◽  
Bridging Ligands ◽  
Magnetization Data ◽  
Metal Organic ◽  
Ch4 Adsorption ◽  
Gas Separation Performance

Three new 3D metal-organic porous frameworks based on Co(II) and 2,2′-bithiophen-5,5′-dicarboxylate (btdc2−) [Co3(btdc)3(bpy)2]·4DMF, 1; [Co3(btdc)3(pz)(dmf)2]·4DMF·1.5H2O, 2; [Co3(btdc)3(dmf)4]∙2DMF∙2H2O, 3 (bpy = 2,2′-bipyridyl, pz = pyrazine, dmf = N,N-dimethylformamide) were synthesized and structurally characterized. All compounds share the same trinuclear carboxylate building units {Co3(RCOO)6}, connected either by btdc2– ligands (1, 3) or by both btdc2– and pz bridging ligands (2). The permanent porosity of 1 was confirmed by N2, O2, CO, CO2, CH4 adsorption measurements at various temperatures (77 K, 273 K, 298 K), resulted in BET surface area 667 m2⋅g−1 and promising gas separation performance with selectivity factors up to 35.7 for CO2/N2, 45.4 for CO2/O2, 20.8 for CO2/CO, and 4.8 for CO2/CH4. The molar magnetic susceptibilities χp(T) were measured for 1 and 2 in the temperature range 1.77–330 K at magnetic fields up to 10 kOe. The room-temperature values of the effective magnetic moments for compounds 1 and 2 are μeff (300 K) ≈ 4.93 μB. The obtained results confirm the mainly paramagnetic nature of both compounds with some antiferromagnetic interactions at low-temperatures T < 20 K in 2 between the Co(II) cations separated by short pz linkers. Similar conclusions were also derived from the field-depending magnetization data of 1 and 2.

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