Microscopic origins of the zero-field splitting parameters for 6S(3d5) state ions at tetragonal symmetry crystal field

Zi-Yuan Yang

doi:10.1016/j.physb.2010.08.064

Microscopic origins of the zero-field splitting parameters for 6S(3d5) state ions at tetragonal symmetry crystal field

Physica B Condensed Matter ◽

10.1016/j.physb.2010.08.064 ◽

2010 ◽

Vol 405 (23) ◽

pp. 4740-4745 ◽

Cited By ~ 3

Author(s):

Zi-Yuan Yang

Keyword(s):

Crystal Field ◽

Tetragonal Symmetry ◽

Zero Field ◽

Zero Field Splitting ◽

Field Splitting

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Clarification of the confusion concerning the crystal-field quantities vs. the zero-field splitting quantities in magnetism studies: Part I—Survey of literature dealing with specific compounds

Physica B Condensed Matter ◽

10.1016/j.physb.2007.10.219 ◽

2008 ◽

Vol 403 (10-11) ◽

pp. 1882-1897 ◽

Cited By ~ 24

Author(s):

C. Rudowicz

Keyword(s):

Crystal Field ◽

Zero Field ◽

Zero Field Splitting ◽

Field Splitting

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Zero-field splitting of a6S-state ion in tetragonal symmetry

Journal of Physics Condensed Matter ◽

10.1088/0953-8984/3/15/008 ◽

1991 ◽

Vol 3 (15) ◽

pp. 2529-2533 ◽

Cited By ~ 2

Author(s):

Wang Kang-ying ◽

Yu Wan-lun

Keyword(s):

Tetragonal Symmetry ◽

Zero Field ◽

Zero Field Splitting ◽

Field Splitting

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Analysis of low symmetry aspects revealed by the zero-field splitting parameters and the crystal field parameters for Cr3+ ions doped into yttrium aluminum borate YAl3(BO3)4 crystal

Optical Materials ◽

10.1016/j.optmat.2014.03.025 ◽

2014 ◽

Vol 36 (8) ◽

pp. 1342-1349 ◽

Cited By ~ 14

Author(s):

Muhammed Açıkgöz ◽

Paweł Gnutek ◽

Czesław Rudowicz

Keyword(s):

Crystal Field ◽

Zero Field ◽

Aluminum Borate ◽

Zero Field Splitting ◽

Field Splitting ◽

Yttrium Aluminum ◽

Yttrium Aluminum Borate ◽

Crystal Field Parameters ◽

Low Symmetry

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EPR Study of Low Symmetry Mn2+ Centers in LiNbO3. Superposition Model and Crystal Field Analysis of the Zero-Field Splitting Parameters

physica status solidi (b) ◽

10.1002/pssb.2221850212 ◽

1994 ◽

Vol 185 (2) ◽

pp. 417-428 ◽

Cited By ~ 26

Author(s):

T. H. Yeom ◽

S. H. Choh ◽

Y. M. Chang ◽

C. Rudowicz

Keyword(s):

Crystal Field ◽

Field Analysis ◽

Zero Field ◽

Superposition Model ◽

Zero Field Splitting ◽

Field Splitting ◽

Low Symmetry

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Investigation of the Zero-Field Splitting of d8 Ions in Pseudo-tetragonal Ni(II) Compounds

Zeitschrift für Naturforschung A ◽

10.1515/zna-1994-1102 ◽

1994 ◽

Vol 49 (11) ◽

pp. 1013-1015 ◽

Cited By ~ 2

Author(s):

Jia-Jun Chen ◽

Mao-Lu Du ◽

Zhao-Ming Li

Keyword(s):

Metal Ion ◽

Tetragonal Symmetry ◽

Zero Field ◽

Central Metal ◽

Spin Orbit Coupling ◽

Cluster Approach ◽

Zero Field Splitting ◽

Field Splitting ◽

Central Transition ◽

Ion Yields

Abstract This paper presents a cluster approach to the zero-field splitting (ZFS) of the ground state 3A2(F) of d8 ions with tetragonal symmetry, in which not only the spin-orbit coupling of the central transition-metal-ion but also that of ligands contributes. For some pseudo-tetragonal Ni(II) com pounds the calculated values of the ZFS parameter follow the order Cl-> Br-> I-. This agrees with the experimental finding, while the pure crystal field approach considering only the coupling of central metal ion yields the opposite trend.

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Determination of the Zero-Field Splitting Parameter and Hyperfine Interaction of Paramagnetic Ions of Half-Integral Spin (S ≧ 3/2) in a Strong Axial Crystal Field

physica status solidi (b) ◽

10.1002/pssb.2220710154 ◽

1975 ◽

Vol 71 (1) ◽

pp. K49-K53 ◽

Cited By ~ 6

Author(s):

O. S. Torosyan ◽

E. G. Sharoyan

Keyword(s):

Hyperfine Interaction ◽

Crystal Field ◽

Zero Field ◽

Zero Field Splitting ◽

Field Splitting ◽

Zero Field Splitting Parameter ◽

Integral Spin ◽

Splitting Parameter ◽

Paramagnetic Ions

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Clarification of terminological confusion concerning the crystal field quantities vs. the effective spin Hamiltonian and zero-field splitting quantities in the papers by Bayrakçeken et al. [Spectrochim. Acta Part A 66 (2007) 462 and 1291]

Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy ◽

10.1016/j.saa.2008.04.025 ◽

2008 ◽

Vol 71 (4) ◽

pp. 1623-1626 ◽

Cited By ~ 1

Author(s):

Czesław Rudowicz

Keyword(s):

Crystal Field ◽

Zero Field ◽

Spin Hamiltonian ◽

Zero Field Splitting ◽

Field Splitting ◽

Effective Spin ◽

Terminological Confusion

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Modeling the zero-field splitting parameters and local structure of Co2+ ions doped into PbMoO4 crystal based on crystal field approach and superposition model analysis

Optical Materials ◽

10.1016/j.optmat.2018.07.003 ◽

2018 ◽

Vol 84 ◽

pp. 466-474 ◽

Cited By ~ 1

Author(s):

Danuta Piwowarska ◽

Paweł Gnutek ◽

Czesław Rudowicz

Keyword(s):

Crystal Field ◽

Local Structure ◽

Model Analysis ◽

Zero Field ◽

Superposition Model ◽

Zero Field Splitting ◽

Field Splitting ◽

Field Approach

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Crystal field levels and zero-field splitting parameters of Cr2+ in the mixed system Rb2MnxCr1−xCl4

Physica B Condensed Matter ◽

10.1016/0921-4526(93)90092-k ◽

1993 ◽

Vol 191 (3-4) ◽

pp. 323-333 ◽

Cited By ~ 21

Author(s):

Czeslaw Rudowicz ◽

Maolu Du ◽

Yau-yuen Yeung ◽

Yi-yang Zhou

Keyword(s):

Crystal Field ◽

Mixed System ◽

Zero Field ◽

Zero Field Splitting ◽

Field Splitting

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Zero-Field Splitting in Transition Metal Complexes: Ab Initio Calculations, Effective Hamiltonians, Model Hamiltonians, and Crystal-Field Models

Handbook of Relativistic Quantum Chemistry ◽

10.1007/978-3-642-40766-6_37 ◽

2016 ◽

pp. 765-796

Author(s):

Rémi Maurice ◽

Ria Broer ◽

Nathalie Guihéry ◽

Coen de Graaf

Keyword(s):

Transition Metal ◽

Ab Initio Calculations ◽

Metal Complexes ◽

Ab Initio ◽

Crystal Field ◽

Transition Metal Complexes ◽

Zero Field ◽

Zero Field Splitting ◽

Field Splitting ◽

Effective Hamiltonians

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