Photoinduced switching of electrical conductivity and its memory effect in the organic conductor α-(BEDT-TTF)2I3: Dependence on voltage height and temporal width of pulsed voltages

2010 ◽  
Vol 405 (11) ◽  
pp. S344-S346 ◽  
Author(s):  
T. Iimori ◽  
T. Naito ◽  
N. Ohta
2016 ◽  
Vol 2016 ◽  
pp. 1-7 ◽  
Author(s):  
Eiza Shimizu ◽  
Gil Nonato Santos ◽  
Derrick Ethelbhert Yu

Skewered Iron(III) phthalocyanine conducting polymer can be constructed with the utilization of axial thiocyanato ligands ((μ-thiocyanato)(phthalocyaninato)iron(III)); (FeIII(Pc)(SCN)n) thereby creating additional avenues for electron transport through a linear SCN bridge, apart from the intermolecularπ-πorbital overlap between the Pc molecules. In this paper, we report on the conversion of bulkFeIII(Pc)(SCN)npolymeric organic conductor into crystalline nanostructures through horizontal vapor phase growth process. The needle-like nanostructures are deemed to provide more ordered and, thus, moreπ-πinteractive interskewerFeIII(Pc)(SCN)npolymer orientation, resulting in a twofold increase of its electrical conductivity per materials density unit.


1992 ◽  
Vol 48 (3) ◽  
pp. 337-354 ◽  
Author(s):  
M. Yamaura ◽  
K. Sato ◽  
T. Hagiwara ◽  
K. Iwata

Author(s):  
John C. Russ ◽  
Nicholas C. Barbi

The rapid growth of interest in attaching energy-dispersive x-ray analysis systems to transmission electron microscopes has centered largely on microanalysis of biological specimens. These are frequently either embedded in plastic or supported by an organic film, which is of great importance as regards stability under the beam since it provides thermal and electrical conductivity from the specimen to the grid.Unfortunately, the supporting medium also produces continuum x-radiation or Bremsstrahlung, which is added to the x-ray spectrum from the sample. It is not difficult to separate the characteristic peaks from the elements in the specimen from the total continuum background, but sometimes it is also necessary to separate the continuum due to the sample from that due to the support. For instance, it is possible to compute relative elemental concentrations in the sample, without standards, based on the relative net characteristic elemental intensities without regard to background; but to calculate absolute concentration, it is necessary to use the background signal itself as a measure of the total excited specimen mass.


Author(s):  
Klaus-Ruediger Peters ◽  
Samuel A. Green

High magnification imaging of macromolecules on metal coated biological specimens is limited only by wet preparation procedures since recently obtained instrumental resolution allows visualization of topographic structures as smal l as 1-2 nm. Details of such dimensions may be visualized if continuous metal films with a thickness of 2 nm or less are applied. Such thin films give sufficient contrast in TEM as well as in SEM (SE-I image mode). The requisite increase in electrical conductivity for SEM of biological specimens is achieved through the use of ligand mediated wet osmiuum impregnation of the specimen before critical point (CP) drying. A commonly used ligand is thiocarbohvdrazide (TCH), first introduced to TEM for en block staining of lipids and glvcomacromolecules with osmium black. Now TCH is also used for SEM. However, after ligand mediated osinification nonspecific osmium black precipitates were often found obscuring surface details with large diffuse aggregates or with dense particular deposits, 2-20 nm in size. Thus, only low magnification work was considered possible after TCH appl ication.


Author(s):  
G. M. Michal

Several TEM investigations have attempted to correlate the structural characteristics to the unusual shape memory effect in NiTi, the consensus being the essence of the memory effect is ostensible manifest in the structure of NiTi transforming martensitic- ally from a B2 ordered lattice to a low temperature monoclinic phase. Commensurate with the low symmetry of the martensite phase, many variants may form from the B2 lattice explaining the very complex transformed microstructure. The microstructure may also be complicated by the enhanced formation of oxide or hydride phases and precipitation of intermetallic compounds by electron beam exposure. Variants are typically found in selfaccommodation groups with members of a group internally twinned and the twins themselves are often observed to be internally twinned. Often the most salient feature of a group of variants is their close clustering around a given orientation. Analysis of such orientation relationships may be a key to determining the nature of the reaction path that gives the transformation its apparently perfect reversibility.


Author(s):  
F. I. Grace

An interest in NiTi alloys with near stoichiometric composition (55 NiTi) has intensified since they were found to exhibit a unique mechanical shape memory effect at the Naval Ordnance Laboratory some twelve years ago (thus refered to as NITINOL alloys). Since then, the microstructural mechanisms associated with the shape memory effect have been investigated and several interesting engineering applications have appeared.The shape memory effect implies that the alloy deformed from an initial shape will spontaneously return to that initial state upon heating. This behavior is reported to be related to a diffusionless shear transformation which takes place between similar but slightly different CsCl type structures.


2007 ◽  
Author(s):  
David Marshall ◽  
Paul Atchley

2011 ◽  
Author(s):  
Jason Swift ◽  
Andrew Garcia ◽  
Maura Pilotti ◽  
Salif Mahamane ◽  
Jennifer Almand

1991 ◽  
Vol 18 (3) ◽  
pp. 611-627 ◽  
Author(s):  
Marta L. Fiorotto ◽  
William J. Klish

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