In3+ substitution effects and defect distribution in Li0.25Mg0.5Mn0.1Fe2.15−xInxO4 studied by positron annihilation and Mössbauer spectroscopy

2004 ◽  
Vol 353 (1-2) ◽  
pp. 75-81 ◽  
Author(s):  
Sanjukta Ghosh ◽  
P.M.G. Nambissan ◽  
R. Bhattacharya
Keyword(s):  
Mössbauer Spectroscopy ◽  
Positron Annihilation ◽  
Mossbauer Spectroscopy ◽  
Substitution Effects ◽  
Defect Distribution ◽  
Mößbauer Spectroscopy

scholarly journals Investigation of Defects and Atomic Ordering in Fe72Al28 by Positron Annihilation and Mössbauer Spectroscopy

1995 ◽  
Vol 05 (C1) ◽  
pp. C1-157-C1-161 ◽  
Author(s):  
Y. Jiraskova ◽  
O. Schneeweiss ◽  
M. Sob ◽  
I. Novotny ◽  
I. Prochazka ◽  
...  
Keyword(s):  
Mössbauer Spectroscopy ◽  
Positron Annihilation ◽  
Mossbauer Spectroscopy ◽  
Atomic Ordering ◽  
Mößbauer Spectroscopy

Positron Annihilation and Mössbauer Spectroscopy of B2 Alloys

1992 ◽  
Vol 105-110 ◽  
pp. 897-900 ◽  
Author(s):  
Adam G. Balogh ◽  
I. Dézsi ◽  
J. Pelloth ◽  
R.A. Brand ◽  
Werner Puff ◽  
...  
Keyword(s):  
Mössbauer Spectroscopy ◽  
Positron Annihilation ◽  
Mossbauer Spectroscopy ◽  
Mößbauer Spectroscopy

An analysis of iron-dextran complexes by Mössbauer spectroscopy and positron annihilation technique

1994 ◽  
Vol 54 (4) ◽  
pp. 285-295 ◽  
Author(s):  
M.I. Oshtrakh ◽  
E.A. Kopelyan ◽  
V.A. Semionkin ◽  
A.B. Livshits ◽  
V.E. Krylova ◽  
...  
Keyword(s):  
Mössbauer Spectroscopy ◽  
Positron Annihilation ◽  
Mossbauer Spectroscopy ◽  
Iron Dextran ◽  
Mößbauer Spectroscopy

Study of Fe75Al25 Alloys by the Mössbauer Spectroscopy Positron Annihilation Lifetime Spectroscopy (PALS), XRD and SEM

2013 ◽  
Vol 203-204 ◽  
pp. 137-141 ◽  
Author(s):  
Aneta Hanc-Kuczkowska ◽  
Jerzy Kansy ◽  
Grzegorz Dercz ◽  
Lucjan Pająk ◽  
Józef Lelątko ◽  
...  
Keyword(s):  
Mössbauer Spectroscopy ◽  
Positron Annihilation ◽  
Mossbauer Spectroscopy ◽  
Vacancy Concentration ◽  
Positron Annihilation Lifetime Spectroscopy ◽  
X Ray Diffraction ◽  
Slow Cooling ◽  
Positron Annihilation Lifetime ◽  
Mößbauer Spectroscopy

The structure, point defect and ordering parameter of Fe25Al samples is examined with the Mössbauer spectroscopy Positron Annihilation Lifetime Spectroscopy XRD and SEM. The studies are carried out for samples in as-cast state and after heat treatments: annealing for 24 hours at 900°C (or 1050°C) and either slow cooling with furnace or quenching to oil. Among the research method used, Mössbauer spectroscopy for determination of hyperfine structure parameters was adopted. These parameters, sensitive to changes in spin and charge electron densities in the nearest neighbourhood of a Mössbauer isotope nucleus, caused by specific configurations of atoms, are directly connected with the degree of ordering of a compound. Spectral analysis has been carried out using an authors’ software developed based on a theoretical model relating the shape of a Mössbauer spectrum to the sample microstructure. It has been shown that Mössbauer spectroscopy enables quantitative evaluation of the degree of ordering of phases occurring in samples characterised by large graining, in the case of which it is not possible to determine the long-range order parameter by X-ray diffraction. The PALS method only one type of defects is detected. The positron lifetime in these defects (V) suggests that they are quenched-in Fe-monovacancies (VFe). The vacancy concentration strongly depends on the rate of cooling.

Sign in / Sign up

Export Citation Format

Share Document