Characterization of PVA–PVdF based solid polymer blend electrolytes

2004 ◽  
Vol 348 (1-4) ◽  
pp. 73-78 ◽  
Author(s):  
S. Rajendran ◽  
M. Sivakumar ◽  
R. Subadevi ◽  
M. Nirmala
Keyword(s):  
Ionics ◽  
2009 ◽  
Vol 16 (3) ◽  
pp. 283-287 ◽  
Author(s):  
S. Rajendran ◽  
V. Shanthi Bama ◽  
M. Ramesh Prabhu
Keyword(s):  

2018 ◽  
Vol 14 (2) ◽  
pp. 221-234
Author(s):  
Ahmed Namah Mohamed ◽  
◽  
Jafer Fahdel Odah ◽  
Haider Tawfiq Naeem

Polymers ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1207
Author(s):  
Gabrielle Foran ◽  
Nina Verdier ◽  
David Lepage ◽  
Cédric Malveau ◽  
Nicolas Dupré ◽  
...  

Solid-state NMR spectroscopy is an established experimental technique which is used for the characterization of structural and dynamic properties of materials in their native state. Many types of solid-state NMR experiments have been used to characterize both lithium-based and sodium-based solid polymer and polymer–ceramic hybrid electrolyte materials. This review describes several solid-state NMR experiments that are commonly employed in the analysis of these systems: pulse field gradient NMR, electrophoretic NMR, variable temperature T1 relaxation, T2 relaxation and linewidth analysis, exchange spectroscopy, cross polarization, Rotational Echo Double Resonance, and isotope enrichment. In this review, each technique is introduced with a short description of the pulse sequence, and examples of experiments that have been performed in real solid-state polymer and/or hybrid electrolyte systems are provided. The results and conclusions of these experiments are discussed to inform readers of the strengths and weaknesses of each technique when applied to polymer and hybrid electrolyte systems. It is anticipated that this review may be used to aid in the selection of solid-state NMR experiments for the analysis of these systems.


2012 ◽  
Vol 585 ◽  
pp. 185-189 ◽  
Author(s):  
Rajni Sharma ◽  
Anjan Sil ◽  
Subrata Ray

In the present work, the effect of Li salt i.e. LiClO4 contained in composite plasticizer (PC+DEC) with three different concentrations on ionic transport and other electrochemical properties of PMMA based gel polymer electrolytes synthesized has been investigated. The electrolytes have been synthesized by solution casting technique by varying the wt (%) of salt and plasticizer. The formation of polymer-salt complexes and their structural characterization have been carried out by FTIR spectroscopic and XRD analyses. The room temperature ionic conductivity of the electrolyte composition 0.6PMMA-0.125(PC+DEC)-0.15LiClO4 (wt %) has been found to be maximum whose magnitude is 0.40×10-5 S/cm as determined by ac impedance analysis. The temperature dependent ionic conductivity of electrolyte sample0.6PMMA-0.125(PC+DEC)-0.15LiClO4 has further been investigated. Thermal analyses of electrolyte samples of all three compositions have also been done.


2018 ◽  
Vol 59 (S1) ◽  
pp. E293-E301 ◽  
Author(s):  
Hafiz Abdul Mannan ◽  
Tan Ming Yih ◽  
Rizwan Nasir ◽  
Hilmi Muhktar ◽  
Dzeti Farhah Mohshim

Sign in / Sign up

Export Citation Format

Share Document