A host material with a small singlet–triplet exchange energy for phosphorescent organic light-emitting diodes: Guest, host, and exciplex emission

2012 ◽  
Vol 13 (10) ◽  
pp. 1937-1947 ◽  
Author(s):  
Shi-Jian Su ◽  
Chao Cai ◽  
Junichi Takamatsu ◽  
Junji Kido
Molecules ◽  
2021 ◽  
Vol 26 (18) ◽  
pp. 5568
Author(s):  
Jie Li ◽  
Heqi Gong ◽  
Jincheng Zhang ◽  
Hui Liu ◽  
Li Tao ◽  
...  

The realization of a deep-blue-emitting exciplex system is a herculean task in the field of organic light-emitting diodes (OLEDs) on account of a large red-shifted and broadened exciplex emission spectrum in comparison to those of the corresponding single compounds. Herein, 2,5,8-tris(di(4-fluorophenyl)amine)-1,3,4,6,7,9,9b-heptaazaphenalene (HAP-3FDPA) was designed as an electron acceptor by integrating three bis(4-fluorophenyl)amine groups into a heptazine core, while 1,3-di(9H-carbazol-9-yl)benzene (mCP) possessing two electron-donating carbazole moieties was chosen as the electron donor. Excitingly, the exciplex system of 8 wt% HAP-3FDPA:mCP exhibited deep-blue emission and a high photoluminescence quantum yield of 53.2%. More importantly, an OLED containing this exciplex system as an emitting layer showed deep-blue emission with Commission Internationale de l’Eclairage coordinates of (0.16, 0.12), a peak luminance of 15,148 cd m−2, and a rather high maximum external quantum efficiency of 10.2% along with a low roll-off. This study not only reports an efficient exciplex-based deep-blue emitter but also presents a feasible pathway to construct highly efficient deep-blue OLEDs based on exciplex systems.


2018 ◽  
Vol 6 (17) ◽  
pp. 4800-4806 ◽  
Author(s):  
Dianming Sun ◽  
Zhongjie Ren ◽  
Shouke Yan

A TADF polymer COPO is used as an assistant host material to improve the performance of Ir(mPPy)3-based solution-processed devices.


2007 ◽  
Vol 91 (25) ◽  
pp. 251111 ◽  
Author(s):  
Myeong-Suk Kim ◽  
Byoung-Ki Choi ◽  
Tae-Woo Lee ◽  
Dongwoo Shin ◽  
Sung Kee Kang ◽  
...  

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