Electrostatic self-assembled design strategy for tetracarboxylic Nickel(II) naphthalocyanine ultrathin film for high-performance nonlinear optical properties

2016 ◽  
Vol 60 ◽  
pp. 6-12 ◽  
Author(s):  
Weina Song ◽  
Xiangwu Xiao ◽  
Chunying He ◽  
Guijie Mao ◽  
Yachen Gao ◽  
...  
2006 ◽  
Vol 496 (2) ◽  
pp. 311-316 ◽  
Author(s):  
Li Jiang ◽  
Fushen Lu ◽  
Yachen Gao ◽  
Yinglin Song ◽  
Huibiao Liu ◽  
...  

2002 ◽  
Vol 117 (8) ◽  
pp. 4016-4021 ◽  
Author(s):  
E. Mishina ◽  
Y. Miyakita ◽  
Q.-K. Yu ◽  
S. Nakabayashi ◽  
H. Sakaguchi

2003 ◽  
pp. 279-290
Author(s):  
R. V. Markov ◽  
A. I. Plekhanov ◽  
Z. M. Ivanova ◽  
V. V. Shelkovnikov ◽  
J. Knoester

2009 ◽  
Vol 13 (12) ◽  
pp. 1243-1249 ◽  
Author(s):  
Chunying He ◽  
Guang Shi ◽  
Wubiao Duan ◽  
Yiqun Wu ◽  
Zhimin Chen ◽  
...  

Films with alternating layers containing anionic tetracarboxylic copper phthalocyanine [ CuPc(COONa)4 ] and cationic polydiallydimethylammonium chloride (PDDA) were fabricated by electrostatic self-assembled layer-by-layer (LBL) technique. The delicate structure of the film was characterized by a series of techniques. The third-order nonlinear optical properties of the film were measured by the Z-scan technique with laser duration of 4 ns and 21 ps at the wavelength of 532 nm. The film exhibited excellent nonlinear absorption and self-focusing effect. The second-order molecular hyperpolarizability γ value of the film was much larger than that of CuPc(COONa)4 aqueous solution under the irradiation of whether ns or ps pulses. A series of damage experiments of the film for the intense laser pulses were conducted to prove the reliability of the experimental results under the conditions.


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