Saturable absorption and two-photon absorption of 1,2,5-thiadiazolo[3,4-g]quinoxaline based derivatives with near-infrared fluorescence

2015 ◽  
Vol 338 ◽  
pp. 257-260 ◽  
Author(s):  
Yabing Du ◽  
Xiaodong Lin ◽  
Tingjian Jia ◽  
Jun Dong
Keyword(s):  
Near Infrared ◽  
Photon Absorption ◽  
Saturable Absorption ◽  
Near Infrared Fluorescence ◽  
Two Photon Absorption ◽  
Two Photon

scholarly journals Nonlinear Absorption and Ultrafast Dynamics of Ag Nanoparticle

Photonics ◽  
2021 ◽  
Vol 8 (7) ◽  
pp. 233
Author(s):  
Jijuan Jiang ◽  
Jun Wang ◽  
Tong Wu ◽  
Yachen Gao
Keyword(s):  
Silver Nanoparticles ◽  
Time Constant ◽  
Laser Intensity ◽  
Photon Absorption ◽  
Saturable Absorption ◽  
Phonon Coupling ◽  
Saturated Absorption ◽  
Coupling Process ◽  
Two Photon Absorption ◽  
Two Photon

Resonant nonlinear optical absorption of silver nanoparticles was studied experimentally via open aperture Z-scan using 130 fs, 400 nm laser pulses. Experimental results show that, at low laser intensity, silver nanoparticles can exhibit saturated absorption. While at high laser intensity, it shows reverse saturated absorption. The saturable absorption is explained in terms of ground state plasmon bleaching, while the reverse saturable absorption is believed to be from two-photon absorption. Saturable optical intensity and two-photon absorption coefficient were obtained to be 1.3×1010 W/m2 and 3.3×10−10 m/W, respectively. The energy relaxation process of Ag nanoparticles after laser excitation was studied via pump-probe technique at 400 nm. Experimental results demonstrated that energy relaxation included electron-phonon coupling process with time constant τ1=(713±50) fs, and phonon-phonon coupling process with time constant τ2=(25.2±3) ps, respectively.

Two-photon absorption spectra of a near-infrared 2-azaazulene polymethine dye: solvation and ground-state symmetry breaking

2013 ◽  
Vol 15 (20) ◽  
pp. 7666 ◽  
Author(s):  
Honghua Hu ◽  
Olga V. Przhonska ◽  
Francesca Terenziani ◽  
Anna Painelli ◽  
Dmitry Fishman ◽  
...  
Keyword(s):  
Symmetry Breaking ◽  
Absorption Spectra ◽  
Ground State ◽  
Near Infrared ◽  
Photon Absorption ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Polymethine Dye

scholarly journals Polyfluorenylacetylene for near-infrared laser protection: polymer synthesis, optical limiting mechanism and relationship between molecular structure and properties

RSC Advances ◽  
2017 ◽  
Vol 7 (85) ◽  
pp. 53785-53796 ◽  
Author(s):  
Gang Zhao ◽  
Yan Feng ◽  
Shanyi Guang ◽  
Hongyao Xu ◽  
Naibo Lin ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Near Infrared ◽  
Optical Limiting ◽  
High Thermal Stability ◽  
Photon Absorption ◽  
Structure And Properties ◽  
Absorption Mechanism ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Good Solubility

The incorporation of styryl/stilbene–fluorene into polyacetylenes not only endowed the polymers with novel near-infrared optical limiting properties based on a two-photon absorption mechanism but good solubility and high thermal stability.

scholarly journals Two-photon excited deep-red and near-infrared emissive organic co-crystals

2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Yu Wang ◽  
Huang Wu ◽  
Penghao Li ◽  
Su Chen ◽  
Leighton O. Jones ◽  
...  
Keyword(s):  
Cross Sections ◽  
Optical Materials ◽  
Near Infrared ◽  
Infrared Emission ◽  
Photon Absorption ◽  
Electromagnetic Spectrum ◽  
Absorption Bands ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Near Infrared Emission

Abstract Two-photon excited near-infrared fluorescence materials have garnered considerable attention because of their superior optical penetration, higher spatial resolution, and lower optical scattering compared with other optical materials. Herein, a convenient and efficient supramolecular approach is used to synthesize a two-photon excited near-infrared emissive co-crystalline material. A naphthalenediimide-based triangular macrocycle and coronene form selectively two co-crystals. The triangle-shaped co-crystal emits deep-red fluorescence, while the quadrangle-shaped co-crystal displays deep-red and near-infrared emission centered on 668 nm, which represents a 162 nm red-shift compared with its precursors. Benefiting from intermolecular charge transfer interactions, the two co-crystals possess higher calculated two-photon absorption cross-sections than those of their individual constituents. Their two-photon absorption bands reach into the NIR-II region of the electromagnetic spectrum. The quadrangle-shaped co-crystal constitutes a unique material that exhibits two-photon absorption and near-infrared emission simultaneously. This co-crystallization strategy holds considerable promise for the future design and synthesis of more advanced optical materials.

Nondegenerate and degenerate two-photon absorption in cuprous oxide thin film

2019 ◽  
Vol 28 (02) ◽  
pp. 1950015 ◽  
Author(s):  
Huijun Liang ◽  
Qunchao Ma ◽  
Jian Liu ◽  
Xinwei Shi ◽  
Gongjin Yang ◽  
...  
Keyword(s):  
Thin Film ◽  
Cuprous Oxide ◽  
Near Infrared ◽  
Rf Magnetron Sputtering ◽  
Photonic Devices ◽  
Photon Absorption ◽  
Oxide Thin Film ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Nir Absorption

A cuprous oxide (Cu2O) thin film was prepared by radio-frequency (RF) magnetron sputtering. The crystal structure, linear transmission spectrum and film thickness were characterized by X-ray diffraction (XRD), ultraviolet–visible–near infrared (UV–Vis–NIR) absorption spectroscopy and ellipsometry. By performing the pump-probe and [Formula: see text]-scan technique, respectively, nondegenerate and degenerate two-photon absorption (D-TPA) coefficients of the Cu2O thin film at several different excitation wavelengths were experimentally determined. The nondegenerate two-photon absorption (ND-TPA) coefficient always exhibits larger magnitude than the corresponding D-TPA coefficient. In particular, the ND-TPA coefficient shows a maximum value of [Formula: see text][Formula: see text]cm/GW. This study indicates that the cuprous oxide could be a potential material for ultrafast nonlinear photonic devices based on two-photon absorption due to its large ND-TPA coefficient.

scholarly journals Highly efficient singlet oxygen generation, two-photon photodynamic therapy and melanoma ablation by rationally designed mitochondria-specific near-infrared AIEgens

2020 ◽  
Vol 11 (9) ◽  
pp. 2494-2503 ◽  
Author(s):  
Zheng Zheng ◽  
Haixiang Liu ◽  
Shaodong Zhai ◽  
Haoke Zhang ◽  
Guogang Shan ◽  
...  
Keyword(s):  
Photodynamic Therapy ◽  
Singlet Oxygen ◽  
Near Infrared ◽  
Molecular Engineering ◽  
Photon Absorption ◽  
Oxygen Generation ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Singlet Oxygen Generation ◽  
Highly Efficient

Mitochondria-targeted photosensitizers with highly efficient singlet oxygen generation, bright near-infrared AIE and good two-photon absorption are obtained through ingenious molecular engineering for cancer cell-selective photodynamic therapy.

scholarly journals Ultrafast sub–30-fs all-optical switching based on gallium phosphide

2019 ◽  
Vol 5 (6) ◽  
pp. eaaw3262 ◽  
Author(s):  
Gustavo Grinblat ◽  
Michael P. Nielsen ◽  
Paul Dichtl ◽  
Yi Li ◽  
Rupert F. Oulton ◽  
...  
Keyword(s):  
Gallium Phosphide ◽  
Optical Switching ◽  
Near Infrared ◽  
Optical Nonlinearity ◽  
Photon Absorption ◽  
Linear Absorption ◽  
Two Photon Absorption ◽  
Two Photon ◽  
All Optical ◽  
All Optical Switching

Gallium phosphide (GaP) is one of the few available materials with strong optical nonlinearity and negligible losses in the visible (λ > 450 nm) and near-infrared regime. In this work, we demonstrate that a GaP film can generate sub–30-fs (full width at half maximum) transmission modulation of up to ~70% in the 600- to 1000-nm wavelength range. Nonlinear simulations using parameters measured by theZ-scan approach indicate that the transmission modulation arises from the optical Kerr effect and two-photon absorption. Because of the absence of linear absorption, no slower free-carrier contribution is detected. These findings place GaP as a promising ultrafast material for all-optical switching at modulation speeds of up to 20 THz.

scholarly journals Two-photon absorption in penicillamine capped CdS tetrapods

2017 ◽  
Vol 5 (7) ◽  
pp. 1724-1729 ◽  
Author(s):  
D. Wawrzyńczyk
Keyword(s):  
Wavelength Range ◽  
Near Infrared ◽  
Water Soluble ◽  
Photon Absorption ◽  
Two Photon Absorption ◽  
Semiconducting Nanoparticles ◽  
Two Photon ◽  
Infrared Excitation

Synthesized penicillamine stabilized CdS tetrapods showed two-photon absorption in a wavelength range between 600 and 850 nm, and strong two-photon excited emission upon near infrared excitation. These water soluble colloidal, semiconducting nanoparticles show potential for applications in nonlinear bioimaging.

scholarly journals Two-photon absorption and saturable absorption of mid-IR in graphene

2019 ◽  
Vol 114 (9) ◽  
pp. 091111 ◽  
Author(s):  
Andrew Malouf ◽  
Ori Henderson-Sapir ◽  
Sze Set ◽  
Shinji Yamashita ◽  
David J. Ottaway
Keyword(s):  
Photon Absorption ◽  
Saturable Absorption ◽  
Two Photon Absorption ◽  
Two Photon

Synthesis of a Nickel Bis(dithiolene) Complex with Strong Near-Infrared Two-Photon Absorption

2008 ◽  
Vol 485 (1) ◽  
pp. 915-927 ◽  
Author(s):  
Jian-Yang Cho ◽  
Jie Fu ◽  
Lazaro A. Padilha ◽  
Stephen Barlow ◽  
Eric W. Van Stryland ◽  
...  
Keyword(s):  
Near Infrared ◽  
Photon Absorption ◽  
Two Photon Absorption ◽  
Two Photon
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