Embedded in-situ nanodomains from chemical composition fluctuation in thermoelectric A2Cu3In3Te8 (A = Zn, Cd)

2021 ◽  
Vol 17 ◽  
pp. 100333
Author(s):  
S. Pan ◽  
L. Liu ◽  
Z. Li ◽  
X. Yan ◽  
C. Wang ◽  
...  
Keyword(s):  
Chemical Composition ◽  
Composition Fluctuation

Structural Studies on Mitotic Spindle Fibres

1978 ◽  
Vol 36 (3) ◽  
pp. 615-626
Author(s):  
J.R. Mcintosh
Keyword(s):  
Chemical Composition ◽  
Mitotic Spindle ◽  
Structural Studies ◽  
Mitotic Apparatus ◽  
Chemical Studies ◽  
Medical Interest ◽  
Spindle Fibres

The mitotic apparatus is a structure of obvious biological and medical interest, but it has proved to be a difficult cellular machine to understand. The chemical composition of the spindle is only slightly elucidated, largely because of the difficulties in preparing useful isolates of the structure. Chemical studies of the mitotic spindle have been reviewed elsewhere (Mcintosh, 1977), and will not be discussed further here. One would think that structural studies on the mitotic apparatus (MA) in situ would be straightforward, but even with this approach there is some disagreement in the results obtained with various methods and by different investigators. In this paper I will review briefly the approaches which have been used in structural studies of the MA, pointing out the strengths and problems of each approach. I will summarize the principal findings of the different methods, and identify what seem to be fruitful avenues for further work.

scholarly journals An Atmospheric Origin for HCN-Derived Polymers on Titan

Processes ◽  
2021 ◽  
Vol 9 (6) ◽  
pp. 965
Author(s):  
Zoé Perrin ◽  
Nathalie Carrasco ◽  
Audrey Chatain ◽  
Lora Jovanovic ◽  
Ludovic Vettier ◽  
...  
Keyword(s):  
Chemical Composition ◽  
Gas Phase ◽  
Formation Process ◽  
Upper Atmosphere ◽  
Gas Mixture ◽  
Space Probe ◽  
Atmospheric Haze ◽  
Formation And Evolution ◽  
Haze Formation

Titan’s haze is strongly suspected to be an HCN-derived polymer, but despite the first in situ measurements by the ESA-Huygens space probe, its chemical composition and formation process remain largely unknown. To investigate this question, we simulated the atmospheric haze formation process, experimentally. We synthesized analogues of Titan’s haze, named Titan tholins, in an irradiated N2–CH4 gas mixture, mimicking Titan’s upper atmosphere chemistry. HCN was monitored in situ in the gas phase simultaneously with the formation and evolution of the haze particles. We show that HCN is produced as long as the particles are absent, and is then progressively consumed when the particles appear and grow. This work highlights HCN as an effective precursor of Titan’s haze and confirms the HCN-derived polymer nature of the haze.

scholarly journals Relationship between the Optical Properties and Chemical Composition of Urban Aerosol Particles in Lithuania

2018 ◽  
Vol 2018 ◽  
pp. 1-10 ◽  
Author(s):  
Julija Pauraite ◽  
Kristina Plauškaitė ◽  
Vadimas Dudoitis ◽  
Vidmantas Ulevicius
Keyword(s):  
Optical Properties ◽  
Chemical Composition ◽  
Organic Aerosol ◽  
Single Scattering ◽  
Chemical Compositions ◽  
Spectra Analysis ◽  
Average Value ◽  
Aerosol Mass ◽  
In Situ Investigation

In situ investigation results of aerosol optical properties (absorption and scattering) and chemical composition at an urban background site in Lithuania (Vilnius) are presented. Investigation was performed in May-June 2017 using an aerosol chemical speciation monitor (ACSM), a 7-wavelength Aethalometer and a 3-wavelength integrating Nephelometer. A positive matrix factorisation (PMF) was used for the organic aerosol mass spectra analysis to characterise the sources of ambient organic aerosol (OA). Five OA factors were identified: hydrocarbon-like OA (HOA), biomass-burning OA (BBOA), more and less oxygenated OA (LVOOA and SVOOA, respectively), and local hydrocarbon-like OA (LOA). The average absorption (at 470 nm) and scattering (at 450 nm) coefficients during the entire measurement campaign were 16.59 Mm−1 (standard deviation (SD) = 17.23 Mm−1) and 29.83 Mm−1 (SD = 20.45 Mm−1), respectively. Furthermore, the absorption and scattering Angström exponents (AAE and SAE, respectively) and single-scattering albedo (SSA) were calculated. The average AAE value at 470/660 nm was 0.97 (SD = 0.16) indicating traffic-related black carbon (BCtr) dominance. The average value of SAE (at 450/700 nm) was 1.93 (SD = 0.32) and could be determined by the submicron particle (PM1) dominance versus the supermicron ones (PM > 1 µm). The average value of SSA was 0.62 (SD = 0.13). Several aerosol types showed specific segregation in the SAE versus SSA plot, which underlines different optical properties due to various chemical compositions.

In situ magnetic and electronic investigation of the early stage oxidation of Fe nanoparticles using X-ray photo-emission electron microscopy

2014 ◽  
Vol 16 (48) ◽  
pp. 26624-26630 ◽  
Author(s):  
C. A. F. Vaz ◽  
A. Balan ◽  
F. Nolting ◽  
A. Kleibert
Keyword(s):  
Electron Microscopy ◽  
Chemical Composition ◽  
Iron Nanoparticles ◽  
Early Stage ◽  
Photoemission Electron Microscopy ◽  
X Ray ◽  
Emission Electron ◽  
Fe Nanoparticles ◽  
Photoemission Electron

In situX-ray photoemission electron microscopy reveals the evolution of chemical composition and magnetism of individual iron nanoparticles during oxidation.

Electron microscopy of interphase chromosomes in situ; binding of permanganate to chicken erythrocytes

1976 ◽  
Vol 20 (2) ◽  
pp. 289-307
Author(s):  
H.G. Davies
Keyword(s):  
Electron Microscopy ◽  
Electron Microscope ◽  
Chemical Composition ◽  
Protein Interaction ◽  
Phosphotungstic Acid ◽  
Intact Cell ◽  
Anomalous Behaviour ◽  
Protein Protein Interaction ◽  
Chicken Erythrocytes

From quantitative electron-microscope observations on the binding of permanganate to regions of erythrocytes and reticulocytes of known chemical composition, it is concluded that KMnO4, like phosphotungstic acid (PTA), binds preferentially to sites on proteins. Compared with PTA, KMnO4 binding exhibits less anomalous behaviour. The data support the hypothesis previously put forward that the 2 regions, or phases, in condensed chromatin differ in both molecular composition and concentration. The increase in binding to protein which occurs during nuclear haemolysis is interpreted in terms of protein-protein interaction in the chromatin of the intact cell.

In situ synchrotron radiation investigation of V2O5–Nb2O5 metastable compounds: transformational kinetics at high temperatures with a new structural solution for the orthorhombic V4Nb20O60 phase

2020 ◽  
Vol 49 (48) ◽  
pp. 17584-17593
Author(s):  
Laura Caggiu ◽  
Antonio Iacomini ◽  
Claudio Pistidda ◽  
Valeria Farina ◽  
Nina Senes ◽  
...  
Keyword(s):  
Chemical Composition ◽  
Synchrotron Radiation ◽  
High Temperatures ◽  
Lattice Parameters ◽  
Orthorhombic Space Group ◽  
Space Group ◽  
Metastable Compounds ◽  
Xrd Patterns ◽  
Structural Solution

In situ synchrotron and conventional XRD patterns were solved for the phase developed at 700 °C with the Amm2 orthorhombic space group, lattice parameters a = 21.187 Å; b = 3.827 Å; c = 19.377 Å; β = 119.83° and chemical composition V4Nb20O60 (ρ = 4.09 g cm−3).

scholarly journals The chemical connection between 67P/C-G and IRAS 16293-2422

2017 ◽  
Vol 13 (S332) ◽  
pp. 196-201
Author(s):  
Maria Nikolayevna Drozdovskaya ◽  
Ewine F. van Dishoeck ◽  
Martin Rubin ◽  
Jes Kristian Jørgensen ◽  
Kathrin Altwegg
Keyword(s):  
Chemical Composition ◽  
Solar System ◽  
Chemical Evolution ◽  
Protoplanetary Disks ◽  
In Situ Measurements ◽  
Isotopic Ratios ◽  
Data Sets ◽  
Low Mass ◽  
Comet 67P

AbstractThe chemical evolution of a star- and planet-forming system begins in the prestellar phase and proceeds across the subsequent evolutionary phases. The chemical trail from cores to protoplanetary disks to planetary embryos can be studied by comparing distant young protostars and comets in our Solar System. One particularly chemically rich system that is thought to be analogous to our own is the low-mass IRAS 16293-2422. ALMA-PILS observations have made the study of chemistry on the disk scales (<100 AU) of this system possible. Under the assumption that comets are pristine tracers of the outer parts of the innate protosolar disk, it is possible to compare the composition of our infant Solar System to that of IRAS 16293-2422. The Rosetta mission has yielded a wealth of unique in situ measurements on comet 67P/C-G, making it the best probe to date. Herein, the initial comparisons in terms of the chemical composition and isotopic ratios are summarized. Much work is still to be carried out in the future as the analysis of both of these data sets is still ongoing.

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