Ring-opening polymerization of glycolide and rac -lactide, catalyzed by aryloxy magnesium complexes: DFT study of reaction profile and stereocontrol mechanism

2017 ◽  
Vol 27 (3) ◽  
pp. 278-280 ◽  
Author(s):  
Pavel V. Ivchenko ◽  
Andrey V. Shlyakhtin ◽  
Ilya E. Nifant’ev
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Dft Study ◽  
Magnesium Complexes ◽  
Reaction Profile

Effects of alkoxide alteration on the ring-opening polymerization of ε-caprolactone initiated by n-Bu3SnOR: a DFT study

2014 ◽  
Vol 26 (3) ◽  
pp. 695-703 ◽  
Author(s):  
Chanchai Sattayanon ◽  
Watit Sontising ◽  
Wanich Limwanich ◽  
Puttinan Meepowpan ◽  
Winita Punyodom ◽  
...  
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Dft Study

Diastereoselective synthesis of chiral aminophenolate magnesium complexes and their application in the stereoselective polymerization of rac-lactide and rac-β-butyrolactone

2016 ◽  
Vol 45 (27) ◽  
pp. 10942-10953 ◽  
Author(s):  
Haobing Wang ◽  
Jianshuang Guo ◽  
Yang Yang ◽  
Haiyan Ma
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Diastereoselective Synthesis ◽  
Magnesium Complexes

A series of magnesium silylamido complexes supported by chiral aminophenolate ligands were synthesized, and their catalytic behaviors toward the ring-opening polymerization of rac-lactide (LA) and rac-β-butyrolactone (BBL) were explored.

(Benz)Imidazolin-2-iminato Aluminum, Zinc, and Magnesium Complexes and Their Applications in Ring Opening Polymerization of ε-Caprolactone

2019 ◽  
Vol 58 (19) ◽  
pp. 13426-13439 ◽  
Author(s):  
Heng Liu ◽  
Maxim Khononov ◽  
Natalia Fridman ◽  
Matthias Tamm ◽  
Moris S. Eisen
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Magnesium Complexes

Discrete Cationic Zinc and Magnesium Complexes for Dual Organic/Organometallic-Catalyzed Ring-Opening Polymerization of Trimethylene Carbonate

2012 ◽  
Vol 18 (30) ◽  
pp. 9360-9370 ◽  
Author(s):  
Pierre Brignou ◽  
Sophie M. Guillaume ◽  
Thierry Roisnel ◽  
Didier Bourissou ◽  
Jean-François Carpentier
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Trimethylene Carbonate ◽  
Magnesium Complexes

PMLABe Diol Synthesized by Ring-Opening Polymerization of Racemic Benzyl β-Malolactonate Initiated by Rare-Earth Trisborohydride Complexes: An Experimental and DFT Study

2014 ◽  
Vol 20 (44) ◽  
pp. 14387-14402 ◽  
Author(s):  
Cédric G. Jaffredo ◽  
Matthias Schmid ◽  
Iker del Rosal ◽  
Teddy Mevel ◽  
Peter W. Roesky ◽  
...  
Keyword(s):  
Rare Earth ◽  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Dft Study
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