Molecular tectonics: from a binuclear metallamacrocycle to a 1D isostructural coordination network based on tetracyanomethyl[1.1.1.1]metacyclophane and a silver cation
The combination of a Chiral-at-metal Ir(iii) organometallic metallatecton with Cu(ii) leads to the formation of a heterobimetallic (Ir,Cu) grid type 2D coordination network.