Preparation of polyaniline nanotubes by a template-free self-assembly method

2011 ◽  
Vol 65 (13) ◽  
pp. 2015-2018 ◽  
Author(s):  
Zhengzheng Huang ◽  
Enhui Liu ◽  
Haijie Shen ◽  
Xiaoxia Xiang ◽  
Yingying Tian ◽  
...  
Keyword(s):  
Self Assembly ◽  
Assembly Method ◽  
Template Free ◽  
Polyaniline Nanotubes

Preparation and Characterization of Polyaniline Nanotubes Doped with Different Acid

2013 ◽  
Vol 401-403 ◽  
pp. 663-666
Author(s):  
Xue Lian Bai ◽  
Jian Ting Mei ◽  
Zhong Guo Mu ◽  
Yun Bai
Keyword(s):  
Acetic Acid ◽  
Self Assembly ◽  
Ammonium Persulfate ◽  
Tetraacetic Acid ◽  
X Ray Diffraction ◽  
X Ray ◽  
Structure And Property ◽  
Assembly Method ◽  
Polyaniline Nanotubes

Polyaniline (PANI) nanotubes were synthesized separately using amino acetic acid (AA), ethylenediamine tetraacetic acid (EDTA), oxalic acid (OA) as dopant and ammonium persulfate (APS) as oxidant by a self-assembly method. SEM, TEM,FTIR and X-ray diffraction (XRD) and applying the 4 probes method characterized the morphology, structure and property of the product. It was found that nanotubes morphology were synthesized when the [Aci/[A ratio is 1:2.The room template conductivity of the products were studied.

Template-Free Synthesis and Properties of Polyaniline Nanostructures Doped with Different Oxidants

2011 ◽  
Vol 688 ◽  
pp. 334-338 ◽  
Author(s):  
He Yang ◽  
Yun Ze Long ◽  
Hang Jun Ding
Keyword(s):  
Self Assembly ◽  
Room Temperature ◽  
Three Dimensional ◽  
Ammonium Persulfate ◽  
Molar Ratio ◽  
Temperature Conductivity ◽  
Room Temperature Conductivity ◽  
Assembly Method ◽  
Temperature Dependence Of Conductivity ◽  
Template Free

In this work, we report on conducting polyaniline (PANI) nanostructures synthesized by a simplified template-free self-assembly method, which are doped with different oxidants such as ammonium persulfate (APS), FeCl3, Fe(NO3)3, and Fe2(SO4)3. It is found that the morphologies of the as-prepared PANI nanowires are dependent on the oxidant and the molar ratio of aniline to oxidant. The PANI nanostructures are semiconducting with room-temperature conductivity ranging from 10-2to 100S/cm, and the temperature dependence of conductivity follows three-dimensional Mott variable range hopping (3D Mott-VRH) model. In addition, the PANI pellets exhibit hydrophilic behavior.

scholarly journals Template-Free Self-Assembly of Two-Dimensional Polymers into Nano/Microstructured Materials

Molecules ◽  
2021 ◽  
Vol 26 (11) ◽  
pp. 3310
Author(s):  
Shengda Liu ◽  
Jiayun Xu ◽  
Xiumei Li ◽  
Tengfei Yan ◽  
Shuangjiang Yu ◽  
...  
Keyword(s):  
Self Assembly ◽  
Recent Progress ◽  
Two Dimensional ◽  
Subsequent Removal ◽  
The Past ◽  
2D Polymers ◽  
Template Free ◽  
Self Assembled ◽  
The Relationship ◽  
Polymer Tubes

In the past few decades, enormous efforts have been made to synthesize covalent polymer nano/microstructured materials with specific morphologies, due to the relationship between their structures and functions. Up to now, the formation of most of these structures often requires either templates or preorganization in order to construct a specific structure before, and then the subsequent removal of previous templates to form a desired structure, on account of the lack of “self-error-correcting” properties of reversible interactions in polymers. The above processes are time-consuming and tedious. A template-free, self-assembled strategy as a “bottom-up” route to fabricate well-defined nano/microstructures remains a challenge. Herein, we introduce the recent progress in template-free, self-assembled nano/microstructures formed by covalent two-dimensional (2D) polymers, such as polymer capsules, polymer films, polymer tubes and polymer rings.

Different Adsorption States between Thiophene and α-Bithiophene Thin Films Prepared by Self-Assembly Method

2003 ◽  
Vol 42 (Part 2, No. 7B) ◽  
pp. L852-L855 ◽  
Author(s):  
Eisuke Ito ◽  
Jaegeun Noh ◽  
Masahiko Hara
Keyword(s):  
Thin Films ◽  
Self Assembly ◽  
Assembly Method

The synthesis of calcium carbonate microparticles with multiple morphologies through self-assembly method

2015 ◽  
Vol 284 ◽  
pp. 253-256 ◽  
Author(s):  
Guang Yuan ◽  
Xiaofeng Chen ◽  
Xian Li ◽  
Qiming Liang ◽  
Guohou Miao ◽  
...  
Keyword(s):  
Calcium Carbonate ◽  
Self Assembly ◽  
Assembly Method

Chemically Responsive Polymer Inverse-Opal Photonic Crystal Films Created by a Self-Assembly Method

2016 ◽  
Vol 120 (22) ◽  
pp. 11938-11946 ◽  
Author(s):  
Huilin Zhao ◽  
Jianping Gao ◽  
Zeng Pan ◽  
Guanbo Huang ◽  
Xiaoyang Xu ◽  
...  
Keyword(s):  
Photonic Crystal ◽  
Self Assembly ◽  
Inverse Opal ◽  
Assembly Method ◽  
Responsive Polymer ◽  
Crystal Films

Hydrogen-Bonding Layer Protecting Polyelectrolyte Capsules and Its Mechanical Property Study with Atomic Force Microscope

2008 ◽  
Vol 8 (6) ◽  
pp. 2996-3002 ◽  
Author(s):  
Liqin Ge ◽  
Xing Wang ◽  
Long Ba ◽  
Zhongze Gu
Keyword(s):  
Hydrogen Bonding ◽  
Atomic Force Microscope ◽  
Elastic Deformation ◽  
Self Assembly ◽  
Laser Scanning ◽  
Confocal Laser ◽  
Bonding Layer ◽  
Layer By Layer ◽  
Assembly Method ◽  
Atomic Force

The hydrogen-bonding multilayered polyelectrolyte capsules with sizes around 6 μm were fabricated by layer-by-layer self-assembly method. The morphology of the obtained capsules was observed with Scanning Electron Microscope (SEM), Confocal Laser Scanning Microscope (CLSM) and Atomic Force Microscope (AFM), respectively. The elastic properties of the capsules were studied with AFM. The capsule was pressed by cantilever with different lengths, a glass bead glued at the end of the cantilever. The force curves were measured on the capsule in air. The Young's modulus of the capsule was obtained (E = 170 MPa for the loading). Results show that this model can predict the elastic deformation of the microcapsule. The accuracy of the elastic deformation of polymer capsule can be ensured using a cantilever of mediate stiffness. Our results show that the existence of the hydrogen-bonding layer makes the multilayered polyelectrolyte harder in comparison with the pure multilayered polyelectrolyte capsules.

An automated setup for production of nanodimensional coatings by the polyelectrolyte self-assembly method

2006 ◽  
Vol 49 (6) ◽  
pp. 849-854 ◽  
Author(s):  
S. A. Portnov ◽  
A. M. Yashchenok ◽  
A. S. Gubskii ◽  
D. A. Gorin ◽  
A. A. Neveshkin ◽  
...  
Keyword(s):  
Self Assembly ◽  
Assembly Method

Regulation of melanoma cell growth by a miR-21 loaded targeted delivery system based on microparticles and nanoparticles targeting phosphatase and tensin homolog (PTEN)

2021 ◽  
Vol 11 (11) ◽  
pp. 1766-1773
Author(s):  
Lei Jin ◽  
Tong Yang
Keyword(s):  
Delivery System ◽  
Self Assembly ◽  
Targeted Delivery ◽  
Melanoma Cells ◽  
Phosphatase And Tensin Homolog ◽  
Tensin Homolog ◽  
Assembly Method ◽  
New Strategy ◽  
Low Levels ◽  
Phosphatase And Tensin Homologue

The modulatory effect of miR-21 on the proliferation of melanoma cells through stimulation of PTEN (Phosphatase and tensin homologue deleted on chromosome 10) expression was investigated in the current study. PTEN, as a tumor suppressor, is expressed in low levels in melanoma tissues and cell lines. Nevertheless, miR-21 can stimulate cancer development and suppress cell apoptosis. Overexpression of PTEN substantially impaired the proliferation of miR-21-treated melanoma cells. In addition, miR-21 and PTEN were observed to exhibit a combinatorial effect, whereas miR-21 could negatively regulate the expression of PTEN. In conclusion, these findings demonstrate that miR-21 affects melanoma development by targeting PTEN, establishing a new strategy for treating malignant melanoma. Furthermore, in this study, microparticles and nanoparticles were employed as carriers to construct, through the self-assembly method, nanocapsules carrying miR-21 in order to develop an efficient nanocapsule delivery system of miR-21 against melanoma cells.

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