Tungsten oxide multifunctional nanostructures: Enhanced environmental and sensing applications

2019 ◽  
Vol 221 ◽  
pp. 250-257 ◽  
Author(s):  
Muhammad Tahir Zahoor ◽  
Mashkoor Ahmad ◽  
Khan Maaz ◽  
Shafqat Karim ◽  
Khalid Waheed ◽  
...  
Sensors ◽  
2019 ◽  
Vol 19 (15) ◽  
pp. 3405 ◽  
Author(s):  
Lili Yang ◽  
Artem Marikutsa ◽  
Marina Rumyantseva ◽  
Elizaveta Konstantinova ◽  
Nikolay Khmelevsky ◽  
...  

Tungsten oxide is a renowned material for resistive type gas sensors with high sensitivity to nitrogen oxides. Most studies have been focused on sensing applications of WO3 for the detection of NO2 and a sensing mechanism has been established. However, less is known about NO sensing routes. There is disagreement on whether NO is detected as an oxidizing or reducing gas, due to the ambivalent redox behavior of nitric oxide. In this work, nanocrystalline WO3 with different particle size was synthesized by aqueous deposition of tungstic acid and heat treatment. A high sensitivity to NO2 and NO and low cross-sensitivities to interfering gases were established by DC-resistance measurements of WO3 sensors. Both nitrogen oxides were detected as the oxidizing gases. Sensor signals increased with the decrease of WO3 particle size and had similar dependence on temperature and humidity. By means of in situ infrared (DRIFT) spectroscopy similar interaction routes of NO2 and NO with the surface of tungsten oxide were unveiled. Analysis of the effect of reaction conditions on sensor signals and infrared spectra led to the conclusion that the interaction of WO3 surface with NO was independent of gas-phase oxidation to NO2.


Ceramics ◽  
2018 ◽  
Vol 1 (1) ◽  
pp. 120-127 ◽  
Author(s):  
Ahmed Afify ◽  
Ahmed Elsayed ◽  
Mohamed Hassan ◽  
Mohamed Ataalla ◽  
Amr Mohamed ◽  
...  

A wet chemical method was used to obtain tungsten oxide nanoparticles from tungsten tetrachloride and natural microfibrous inorganic clay (sepiolite) as a starting material. Precipitation of tungsten oxide species onto sepiolite under basic conditions and subsequent thermal treatment was investigated, prompted by the abundance of sepiolite in nature and the useful environmental applications that could be attained. Laser granulometry, X-ray diffraction, field emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDX), and high-resolution transmission electron microscopy (HR-TEM) techniques were used to study the particle-size distribution, the morphology, and the composition of the prepared sample. Our findings show the presence of tungsten oxide nanoparticles, which are less than 50 nm, on the needles of the modified sepiolite.


2008 ◽  
Vol 28 (5) ◽  
pp. 913-917 ◽  
Author(s):  
Csaba Balázsi ◽  
Lisheng Wang ◽  
Esra Ozkan Zayim ◽  
Imre Miklós Szilágyi ◽  
Katarína Sedlacková ◽  
...  

2006 ◽  
Vol 915 ◽  
Author(s):  
Andrea Ponzoni ◽  
Elisabetta Comini ◽  
Matteo Ferroni ◽  
Guido Faglia ◽  
Giorgio Sberveglieri

AbstractWO3 layers have been synthesized by thermal evaporation at high temperature in order to induce the crystallization of stable films. Phase stability has been proved by annealing treatments carried out at different temperatures. Annealing effects on gas sensing performances have been explained in terms of crystallinity degree and grain coarsening phenomena.


2016 ◽  
Vol 49 (20) ◽  
pp. 205101 ◽  
Author(s):  
Alexandra Palla-Papavlu ◽  
Mihaela Filipescu ◽  
Christof W Schneider ◽  
Stefan Antohe ◽  
Paolo M Ossi ◽  
...  

NANO ◽  
2008 ◽  
Vol 03 (04) ◽  
pp. 223-227 ◽  
Author(s):  
KATARÍNA SEDLÁCKOVÁ ◽  
RADU IONESCU ◽  
CSABA BALÁZSI

In this work, nanocrystalline hexagonal tungsten oxide was prepared by acidic precipitation from sodium tungstate solution. TEM studies of nanopowders showed that the average size of the hexagonal nanoparticles is 30–50 nm. Novel nanocomposites were prepared by embedding a low amount of gold-decorated carbon nanotubes into the hex- WO 3 matrix. The addition of MWCNTs lowered the temperature range of sensitivity of hex- WO 3 nanocomposites to NO 2 hazardous gas. The sensitivity of hex- WO 3 with Au -decorated MWCNTs to NO 2 is at the temperature range between 25°C and 250°C.


2011 ◽  
Vol 160 (1) ◽  
pp. 549-554 ◽  
Author(s):  
Tuan-Anh Nguyen ◽  
Sungyeol Park ◽  
Jun Beom Kim ◽  
Tae Kyu Kim ◽  
Gi Hun Seong ◽  
...  

Talanta ◽  
2011 ◽  
Vol 85 (4) ◽  
pp. 2166-2174 ◽  
Author(s):  
V. Hariharan ◽  
S. Radhakrishnan ◽  
M. Parthibavarman ◽  
R. Dhilipkumar ◽  
C. Sekar

2007 ◽  
Vol 17 (11) ◽  
pp. 1801-1806 ◽  
Author(s):  
E. Rossinyol ◽  
A. Prim ◽  
E. Pellicer ◽  
J. Arbiol ◽  
F. Hernández-Ramírez ◽  
...  

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