Fabrication of flower-like tin/carbon composite microspheres as long-lasting anode materials for lithium ion batteries

2017 ◽  
Vol 185 ◽  
pp. 6-13 ◽  
Author(s):  
Tae-Woo Kang ◽  
Hyung-Seok Lim ◽  
Seong-Jin Park ◽  
Yang-Kook Sun ◽  
Kyung-Do Suh
2009 ◽  
Vol 189 (1) ◽  
pp. 16-21 ◽  
Author(s):  
Zhaojun Luo ◽  
Dongdong Fan ◽  
Xianlong Liu ◽  
Huanyu Mao ◽  
Caifang Yao ◽  
...  

2014 ◽  
Vol 258 ◽  
pp. 305-313 ◽  
Author(s):  
Lingmin Yao ◽  
Xianhua Hou ◽  
Shejun Hu ◽  
Jie Wang ◽  
Min Li ◽  
...  

2018 ◽  
Vol 10 (29) ◽  
pp. 24549-24553 ◽  
Author(s):  
Seong Heon Kim ◽  
Yong Su Kim ◽  
Woon Joong Baek ◽  
Sung Heo ◽  
Dong-Jin Yun ◽  
...  

2019 ◽  
Vol 12 (01) ◽  
pp. 1850094 ◽  
Author(s):  
Yue Lu ◽  
Peng Chang ◽  
Libin Wang ◽  
Joseph Nzabahimana ◽  
Xianluo Hu

Silicon (Si) has been considered as one of the most promising anode materials in lithium-ion battery. However, practical applications of Si are hindered by undesirable cycling stability resulting from poor electrical conductivity and huge volumetric change during cycling process. Here, we prepared a yolk-shell silicon/carbon composite by etching carbon-coated heat-treated silicon monoxide (SiO) precursor. The as-prepared Si/SiOx@Void@C composite of inner silicon/silicon oxides and outer carbon shell with voids between them (Si/SiOx@Void@C), shows impressive cycling stability (1020[Formula: see text]mAh[Formula: see text]g[Formula: see text] at 1[Formula: see text]A[Formula: see text]g[Formula: see text] over 200 cycles) and excellent rate performance (775[Formula: see text]mAh[Formula: see text]g[Formula: see text] at 6[Formula: see text]A[Formula: see text]g[Formula: see text]). The remarkable electrochemical performance is due to the enhanced electrical conductivity originated from the carbon shell and the volume buffer effect of the yolk-shell structure. A combination of the yolk-shell structure with Si/C composites is believed to be a promising way to improve the performance of Si-based materials in lithium-ion batteries.


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