scholarly journals Electrophoretic graphene oxide surface passivation on titanium dioxide for dye sensitized solar cell application

2020 ◽  
Vol 5 (3) ◽  
pp. 316-321
Author(s):  
Arya Vasanth ◽  
Niket Suresh Powar ◽  
Divya Krishnan ◽  
Shantikumar V. Nair ◽  
Mariyappan Shanmugam
2020 ◽  
Vol 49 (4) ◽  
pp. 315-324
Author(s):  
Azimah Omar ◽  
Muhamad Saipul Fakir ◽  
Khairus Syifa Hamdan ◽  
Nurul Hidayah Rased ◽  
Nasrudin Abd. Rahim

Purpose The purpose of this paper is to investigate the chemical, optical and photovoltaic properties of titanium dioxide/reduced graphene oxide (TiO2/rGO) photoanodes immersed in natural Roselle and synthetic (N719) dyes for dye-sensitized solar cell (DSSC) application. Design/methodology/approach TiO2 mixed with rGO were doctor-bladed on fluorine doped tin oxide (FTO) glass substrate. The chemical and optical properties of TiO2/rGO photoanodes immersed in Roselle and N719 dyes were characterized using Fourier-transformed infrared (FTIR) and ultraviolet–visible (UV–vis) spectroscopies, respectively. The DSSC’s photovoltaic performances were tested using Visiontec Solar I-V tester at standard illumination of AM1.5 and irradiance level of 100 mW/cm2. Findings The presence of anthocyanin dye from Roselle flower was detected at 604 nm and 718 nm. TiO2/rGO+Roselle dye sample revealed the smallest energy gap of 0.17 eV for ease of electron movement from valence band to conduction band. The TiO2/rGO-based DSSC fabricated with Roselle dye had a power conversion efficiency, ƞ of 0.743 per cent higher than TiO2/rGO photoanode sensitized with N719 dye (0.334 per cent). The obtained J-V curves were analyzed by a single-diode model of Lambert W-function and manual optimization to determine the internal electrical parameters of the DSSC. The average and uncertainty values of Jsc and ƞ were evaluated at different Rsh range of 1362 Ω to 32 k Ω. Research limitations/implications Rs values were kept constant during optimization work. Originality/value New ideality factor of TiO2/rGO-based DSSC was re-determined around 0.9995.


2020 ◽  
Vol 2020 ◽  
pp. 1-11 ◽  
Author(s):  
Weradesh Sangkhun ◽  
Sompit Wanwong ◽  
Nutthapon Wongyao ◽  
Teera Butburee ◽  
Pisist Kumnorkaew ◽  
...  

This work developed a novel ternary composite photoanode of dye-sensitized solar cell (DSSC) composed of (i) N-, S-doped titanium dioxide with exposed {001} facet (N-, S-TiO2{001}), (ii) N-, S-doped reduced graphene oxide (N-, S-rGO), and (iii) commercial titanium dioxide (P25). The DSSC device fabricated with the ternary composite photoanode showed the greatest of power conversion efficiency (8.62%) compared to the device fabricated with P25 photoanode (3.20%). This enhancement was attributed to the synergistic effect of the N-, S-TiO2{001} and the N-, S-rGO, which act as an electron enricher and an electron extractor, respectively.


RSC Advances ◽  
2015 ◽  
Vol 5 (42) ◽  
pp. 33653-33665 ◽  
Author(s):  
Miao Xie ◽  
Jian Wang ◽  
Hong-Qiang Xia ◽  
Fu-Quan Bai ◽  
Ran Jia ◽  
...  

Three natural porphyrin derivatives as dyes adsorbed on the semiconductor titanium dioxide surface were studied theoretically to explore their spectroscopic properties, photovoltaic parameters and potential application future in DSSCs.


2009 ◽  
Vol 517 (16) ◽  
pp. 4663-4667 ◽  
Author(s):  
Wirat Jarernboon ◽  
Samuk Pimanpang ◽  
Santi Maensiri ◽  
Ekaphan Swatsitang ◽  
Vittaya Amornkitbamrung

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