ACE-FTS ozone, water vapour, nitrous oxide, nitric acid, and carbon monoxide profile comparisons with MIPAS and MLS

2017 ◽  
Vol 186 ◽  
pp. 63-80 ◽  
Author(s):  
Patrick E. Sheese ◽  
Kaley A. Walker ◽  
Chris D. Boone ◽  
Peter F. Bernath ◽  
Lucien Froidevaux ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
Nitrous Oxide ◽  
Nitric Acid ◽  
Water Vapour

Dichlorosilylene: Rate constant for reaction with carbon monoxide and nitrous oxide

1989 ◽  
Vol 11 (3) ◽  
pp. 235-244 ◽  
Author(s):  
V. Sandhu ◽  
O. P. Strausz ◽  
T. N. Bell
Keyword(s):  
Carbon Monoxide ◽  
Nitrous Oxide ◽  
Rate Constant

Effect of Water Vapour on Explosions of Carbon Monoxide

Nature ◽  
1952 ◽  
Vol 170 (4333) ◽  
pp. 838-839 ◽  
Author(s):  
D. E. HOARE ◽  
A. D. WALSH
Keyword(s):  
Carbon Monoxide ◽  
Water Vapour ◽  
Effect Of Water

scholarly journals The Formation of Gaseous Atmosphere in a Molten Cast Iron/Moulding Sand Contact System

2014 ◽  
Vol 14 (1) ◽  
pp. 79-84 ◽  
Author(s):  
J. Mocek
Keyword(s):  
Carbon Monoxide ◽  
Cast Iron ◽  
Water Vapour ◽  
Molten Iron ◽  
Gaseous Atmosphere ◽  
Furan Resin ◽  
Molten Cast Iron ◽  
Benzene Toluene ◽  
Moulding Sand ◽  
Lower Temperature

Abstract Drops of molten cast iron were placed on moulding sand substrates. The composition of the forming gaseous atmosphere was examined. It was found that as a result of the cast iron contact with water vapour released from the sand, a significant amount of hydrogen was evolved. In all the examined moulding sands, including sands without carbon, a large amount of CO was formed. The source of carbon monoxide was carbon present in cast iron. In the case of bentonite moulding sand with seacoal and sand bonded with furan resin, in the composition of the gases, the trace amounts of hydrocarbons, i.e. benzene, toluene, styrene and naphthalene (BTX), appeared. As the formed studies indicate much higher content of BTX at lower temperature it was concluded that the hydrocarbons are unstable in contact with molten iron.

3-D tomographic observations of Rossby wave breaking over the Northern Atlantic during the WISE aircraft campaign in 2017

2021 ◽  
Author(s):  
Lukas Krasauskas ◽  
Jörn Ungermann ◽  
Peter Preusse ◽  
Felix Friedl-Vallon ◽  
Andreas Zahn ◽  
...  
Keyword(s):  
Nitric Acid ◽  
Water Vapour ◽  
Rossby Wave ◽  
Wave Breaking ◽  
Thin Filament ◽  
Small Scale ◽  
Data Sets ◽  
Mixing Processes ◽  
Air Masses ◽  
Rossby Wave Breaking

<p>We present measurements of ozone, water vapour and nitric acid in the upper troposphere/lower stratosphere (UTLS) over North Atlantic and Europe. The measurements were acquired with the Gimballed Limb Observer for Radiance Imaging of the Atmosphere (GLORIA) during the Wave Driven Isentropic Exchange (WISE) campaign in October 2017. GLORIA is an airborne limb imager capable of acquiring both 2-D data sets (curtains along the flight path) and, when the carrier aircraft is flying around the observed air mass, spatially highly resolved 3-D tomographic data. We show a case study of a Rossby wave (RW) breaking event observed during two subsequent flights two days apart. RW breaking is known to steepen tracer gradients and facilitate stratosphere-troposphere exchange (STE). Our measurements reveal complex spatial structures in stratospheric tracers (ozone and nitric acid) with multiple vertically stacked filaments. Backward trajectory analysis is used to demonstrate that these features are related to several previous Rossby wave breaking events and that the small-scale structure of the UTLS in the Rossby wave breaking region, which is otherwise very hard to observe, can be understood as stirring and mixing of air masses of tropospheric and stratospheric origin. It is also shown that a strong nitric acid enhancement observed just above the tropopause is likely a result of NO<sub>x</sub> production by lightning activity. The measurements showed signatures of enhanced mixing between stratospheric and tropospheric air near the polar jet with some transport of water vapour into the stratosphere. Some of the air masses seen in 3-D data were encountered again two days later, stretched to very thin filament (horizontal thickness down to 30 km at some altitudes) rich in stratospheric tracers. This repeated measurement allowed us to directly observe and analyse the progress of mixing processes in a thin filament over two days. Our results provide direct insight into small-scale dynamics of the UTLS in the Rossby wave breaking region, witch is of great importance to understanding STE and poleward transport in the UTLS.</p>

Two-component gas sensing with MIR dual comb spectroscopy

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Leonard Nitzsche ◽  
Jens Goldschmidt ◽  
Armin Lambrecht ◽  
Jürgen Wöllenstein
Keyword(s):  
Carbon Monoxide ◽  
Nitrous Oxide ◽  
Gas Sensing ◽  
Integration Time ◽  
Relative Precision ◽  
Acquisition Rate ◽  
Mid Infrared ◽  
Two Component ◽  
Absorption Features

Abstract A dual comb spectrometer is used as gas sensor for the parallel detection of nitrous oxide (N2O) and carbon monoxide (CO). These gases have overlapping absorption features in the mid-infrared (MIR) at a wavelength of 4.6 µm. With a spectra acquisition rate of 10 Hz, concentrations of 50 ppm N2O and 30 ppm CO are monitored with a relative precision of 6 × 10 − 3 6\times {10^{-3}} and 3 × 10 − 3 3\times {10^{-3}} respectively. The limit of detections are 91 ppb for N2O and 50 ppb for CO for an integration time of 25 s. The system exhibits a linear sensitivity from 2 ppm to 100 ppm with coefficients of determination of 0.99998 for N2O and 0.99996 for CO.

Removal of Nitrous Oxide in Nitric Acid Production

2019 ◽  
Vol 60 (6) ◽  
pp. 744-760 ◽  
Author(s):  
L. A. Isupova ◽  
Yu. A. Ivanova
Keyword(s):  
Nitrous Oxide ◽  
Nitric Acid ◽  
Acid Production

scholarly journals Chemical reactions during sintering of Fe-Cr-Mn-Si-Ni-Mo-C-steels with special reference to processing in semi-closed containers

2015 ◽  
Vol 47 (1) ◽  
pp. 61-69 ◽  
Author(s):  
A. Cias
Keyword(s):  
Mechanical Properties ◽  
Carbon Monoxide ◽  
Special Reference ◽  
Water Vapour ◽  
Chemical Reactions ◽  
Thermodynamic Data ◽  
Alloying Elements ◽  
Bearing Steels ◽  
Kinetics Of

Sintering of Cr, Mn and Si bearing steels has recently attracted both experimental and theoretical attention and processing in semiclosed containers has been reproposed. This paper brings together relevant thermodynamic data and considers the kinetics of some relevant chemical reactions. These involve iron and carbon, water vapour, carbon monoxide and dioxide, hydrogen and nitrogen of the sintering atmospheres and the alloying elements Cr, Mn, Mo and Si. The paper concludes by presenting mechanical properties data for three steels sintered in local microatmosphere with nitrogen, hydrogen, nitrogen-5% hydrogen and air as the furnace gas.

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