Vibrational relaxation and vibration-rotation energy transfer between highly vibrationally excited KH(X1Σ+, v=14–21) and CO2

2012 ◽  
Vol 113 (16) ◽  
pp. 2081-2087 ◽  
Author(s):  
Xiu-hua Cui ◽  
Bao-xia Mu ◽  
Yi-fan Shen ◽  
Kang Dai
Keyword(s):  
Energy Transfer ◽  
Vibrational Relaxation ◽  
Vibrationally Excited ◽  
Vibration Rotation ◽  
Rotation Energy

On the Vibration–Rotation Energy Transfer of Fast Rotating Molecules

1974 ◽  
Vol 52 (10) ◽  
pp. 854-860 ◽  
Author(s):  
W. G. Tam
Keyword(s):  
Energy Transfer ◽  
Classical Theory ◽  
Semiclassical Theory ◽  
Vibration Rotation ◽  
Rotation Energy ◽  
Fast Rotating

A semiclassical theory of the vibration–rotation energy transfer of fast rotating molecules is presented. The formulation is based on the same model as that of Shin's classical theory. The semiclassical theory is simpler to derive and more rigorous. We show that it necessarily gives more accurate results than the classical theory. Applications to the systems HF and DF indicate that the two theories agree reasonably well in these cases.

Mechanism of quasiresonant vibration–rotation energy transfer in atom–diatom encounters

1992 ◽  
Vol 97 (5) ◽  
pp. 3348-3356 ◽  
Author(s):  
Adolf Miklavc ◽  
Nikola Marković ◽  
Gunnar Nyman ◽  
Vili Harb ◽  
Sture Nordholm
Keyword(s):  
Energy Transfer ◽  
Vibration Rotation ◽  
Rotation Energy

Statistical intramolecular vibration–rotation energy transfer in isolated polyatomic molecules: Electric deflection studies

1988 ◽  
Vol 88 (2) ◽  
pp. 1460-1461 ◽  
Author(s):  
Francis W. Farley ◽  
Leo V. Novakoski ◽  
Manvendra K. Dubey ◽  
Gilbert M. Nathanson ◽  
Gary M. McClelland
Keyword(s):  
Energy Transfer ◽  
Polyatomic Molecules ◽  
Intramolecular Vibration ◽  
Electric Deflection ◽  
Vibration Rotation ◽  
Rotation Energy

Energy transfer in the quenching of singlet molecular oxygen - II. The rates of formation and quenching of vibrationally excited molecules

1977 ◽  
Vol 356 (1686) ◽  
pp. 295-306 ◽  
Keyword(s):  
Energy Transfer ◽  
Molecular Oxygen ◽  
Vibrational Relaxation ◽  
Vibrational Excitation ◽  
Rate Coefficients ◽  
Singlet Molecular Oxygen ◽  
Vibrationally Excited ◽  
The Absolute ◽  
Excited Molecules ◽  
Kinetics Of

The absolute efficiencies for the vibrational excitation of molecules which quench singlet molecular oxygen have been determined from measurements of their infrared chemiluminescence and kinetics of relaxation. The systems studied were NO and CO with O 2 ( 1 ∆ g ) and NO, CO, HCl, DCl, H 2 O, D 2 O, CO 2 , N 2 O, NH 3 and C 2 H 2 with O 2 ( 1 ∑ + g ). Rate coefficients for the vibrational relaxation of a number of these molecules by molecular oxygen were also determined.

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