4,4′-dinonyl-2,2′-bipyridine as an alternative electrolyte additive for improving the thermal stability of ruthenium dyes in dye-sensitized solar cells

2018 ◽  
Vol 122 ◽  
pp. 234-238 ◽  
Author(s):  
Phuong Tuyet Nguyen ◽  
Nghi Phuong Do Nguyen ◽  
Le Thi Nguyen
2009 ◽  
Vol 93 (6-7) ◽  
pp. 1110-1115 ◽  
Author(s):  
Hiroshi Matsui ◽  
Kenichi Okada ◽  
Takayuki Kitamura ◽  
Nobuo Tanabe

ChemPlusChem ◽  
2018 ◽  
Vol 83 (7) ◽  
pp. 682-690 ◽  
Author(s):  
Mahyar Mohammadnezhad ◽  
Gurpreet Singh Selopal ◽  
Zhiming M. Wang ◽  
Barry Stansfield ◽  
Haiguang Zhao ◽  
...  

2018 ◽  
Vol 62 (4) ◽  
Author(s):  
Viola Nagygyörgy ◽  
Elias Stathatos ◽  
György Pokol ◽  
János Madarász

A comparative study on thermal stability of hybrid (organic / inorganic) electrolytes for dye-sensitized solar cells (DSSCs) in various ethylene oxide oligomers / silica based gelly matrices, containing also some efficiency-promoter additives is presented. Using thermogravimetry combined with two evolved gas analytical (EGA-FTIR and EGA-MS) techniques, the released gases and volatile decomposition products from the composite electrolytes during dynamic heating programs have been identified and monitored. First methanol (arising from condensation of tetramethoxysilane, TMOS) and acetonitrile (solvent) are evolved followed by elongated release of 4-tert-butylpyridine, than carbonyl sulfide, which is one of the degradation products of guanidinium thiocyanate, and various alkyl iodides, as well as iodine, later various oxidized species with >C=O groups (arising from oxidative degradation of oligo(ethylene glycolic) parts, ammonia (originated from guanidine) have been observed and traced during the accelerated heating tests, before final burning out of the organic residue with CO2 evolution. Thermal behavior of pure guanidinium thiocyanate, one of the most important additives improving thermal stability of Grätzel type solar cells (DSSCs), combined with identification of its eight gaseous decomposition products and their release pattern is also reported.


ChemPlusChem ◽  
2018 ◽  
Vol 83 (7) ◽  
pp. 546-546
Author(s):  
Mahyar Mohammadnezhad ◽  
Gurpreet Singh Selopal ◽  
Zhiming M. Wang ◽  
Barry Stansfield ◽  
Haiguang Zhao ◽  
...  

2015 ◽  
Vol 44 (23) ◽  
pp. 8386-8398 ◽  
Author(s):  
Catherine E. Housecroft ◽  
Edwin C. Constable

The development of bis(diimine)copper(i) complexes as dyes in dye-sensitized solar cells is described. We assess the progress made in terms of light-harvesting and overall photoconversion efficiencies, and highlight areas that remain ripe for development and improvement, and the advantages of copper dyes over conventional ruthenium dyes.


2018 ◽  
Vol 314 ◽  
pp. 98-102 ◽  
Author(s):  
Phuong Tuyet Nguyen ◽  
Thu Anh Pham Phan ◽  
Nhung Hong Thi Ngo ◽  
Tuan Van Huynh ◽  
Torben Lund

2016 ◽  
Vol 307 ◽  
pp. 416-425 ◽  
Author(s):  
Guohua Wu ◽  
Ryuji Kaneko ◽  
Yaohong Zhang ◽  
Yoshinao Shinozaki ◽  
Kosuke Sugawa ◽  
...  

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