A thermal and electrochemical properties research on gel polymer electrolyte membrane of lithium ion battery

2016 ◽  
Vol 99 ◽  
pp. 159-166 ◽  
Author(s):  
Libo Li ◽  
Yue Ma ◽  
Wentao Wang ◽  
Yanping Xu ◽  
Jun You ◽  
...  
Keyword(s):  
Electrochemical Properties ◽  
Lithium Ion Battery ◽  
Polymer Electrolyte ◽  
Polymer Electrolyte Membrane ◽  
Gel Polymer Electrolyte ◽  
Lithium Ion ◽  
Electrolyte Membrane

scholarly journals PERFORMANCE STUDY OF LiBOB/LiTFSI ELECTROLYTE SALT IN THE ALL-SOLID-STATE LITHIUM-ION BATTERY

2020 ◽  
Vol 21 (3) ◽  
pp. 102
Author(s):  
Christin Ratri ◽  
Titik Lestariningsih ◽  
Qolby Sabrina
Keyword(s):  
Lithium Ion Battery ◽  
Polymer Electrolyte ◽  
Electrode Materials ◽  
Polymer Electrolyte Membrane ◽  
Lithium Ion ◽  
Solid Polymer ◽  
Performance Study ◽  
Battery Cell ◽  
Current Output ◽  
Electrolyte Membrane

PERFORMANCE STUDY OF LiBOB/LiTFSI ELECTROLYTE SALT IN THE ALL-SOLIDSTATE LITHIUM-ION BATTERY. Solid polymer electrolyte is developed mainly to provide safer lithiumion battery upon high temperature operation. In this research, we employ LiBOB and LiTFSI electrolyte salt in various concentration to replace commercially used LiPF6 salt. Solution cast method was performed to produce polymer electrolyte membrane. PVdF-HFP was chosen as polymer matrix due to high dielectric constant, and compatibility to wide array of electrode materials as well as electrolyte salts. Higher amount of electrolyte salts contributes to thicker membrane and hence higher current output of the lithium-ion battery half-cells. SEM, FT-IR spectroscopy, and cyclic voltammetry measurement was conducted to evaluate li-ion battery cell performance. Between the two electrolyte salts used in this experiment, LiTFSI salt exhibited better performance compared to LiBOB.

A Single Ion Conducting Gel Polymer Electrolyte Based on Poly(lithium 2-Acrylamido-2-Methylpropanesulfonic Acid-Co-Vinyl Triethoxysilane) and its Electrochemical Properties

2012 ◽  
Vol 535-537 ◽  
pp. 2053-2056
Author(s):  
Wei Wei Cui ◽  
Dong Yan Tang ◽  
Li Li Guan
Keyword(s):  
Electrochemical Properties ◽  
Polymer Electrolyte ◽  
Polymer Electrolytes ◽  
Polymer Electrolyte Membrane ◽  
Gel Polymer Electrolyte ◽  
Linear Sweep Voltammetry ◽  
Amorphous Structure ◽  
Electrolyte Membrane ◽  
Ion Conducting ◽  
Vinyl Triethoxysilane

Single ion conducting polymer electrolytes synthesized through a copolymer poly(lithium 2-acrylamido-2-methylpropanesulfonic acid-co-vinyl triethoxysilane) and a crosslinker poly(etheylene glycol) dimethacrylate (PEGDMA) were prepared. Scanning electron microscope (SEM) was used to observe the morphology of the surface and cross-section of the polymer electrolyte membrane. AC impedance and linear sweep voltammetry were used to investigate the electrochemical properties of the polymer electrolytes. It was found that the obtained membrane had a typical amorphous structure and possessed a smooth surface. The bulk resistance of the polymer electrolyte increased with the increase in the plasticizer uptake. The electrochemical stability increased with the increase in the content of VTES.

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