Theoretical aspects of dynamic nuclear polarization in the solid state – The cross effect

2012 ◽  
Vol 214 ◽  
pp. 29-41 ◽  
Author(s):  
Yonatan Hovav ◽  
Akiva Feintuch ◽  
Shimon Vega
Keyword(s):  
Solid State ◽  
Dynamic Nuclear Polarization ◽  
Nuclear Polarization ◽  
Cross Effect ◽  
The Cross

Dynamic nuclear polarization in the solid state: a transition between the cross effect and the solid effect

2012 ◽  
Vol 14 (16) ◽  
pp. 5729 ◽  
Author(s):  
Daphna Shimon ◽  
Yonatan Hovav ◽  
Akiva Feintuch ◽  
Daniella Goldfarb ◽  
Shimon Vega
Keyword(s):  
Solid State ◽  
Dynamic Nuclear Polarization ◽  
Nuclear Polarization ◽  
Cross Effect ◽  
Solid Effect ◽  
The Cross

Static 1H dynamic nuclear polarization with the biradical TOTAPOL: a transition between the solid effect and the cross effect

2014 ◽  
Vol 16 (14) ◽  
pp. 6687-6699 ◽  
Author(s):  
Daphna Shimon ◽  
Akiva Feintuch ◽  
Daniella Goldfarb ◽  
Shimon Vega
Keyword(s):  
High Temperatures ◽  
Dynamic Nuclear Polarization ◽  
Low Temperatures ◽  
Nuclear Polarization ◽  
Cross Effect ◽  
Solid Effect ◽  
The Cross

Static 1H-DNP with TOTAPOL: the solid effect (SE) dominant at low temperatures; the cross effect (CE) dominant at high temperatures; and DNP-buildup: Tbu(SE) < Tbu(CE).

scholarly journals Optimizing nitroxide biradicals for cross-effect MAS-DNP: the role of g-tensors’ distance

2020 ◽  
Vol 22 (6) ◽  
pp. 3643-3652 ◽  
Author(s):  
Frédéric Mentink-Vigier
Keyword(s):  
Solid State ◽  
Dynamic Nuclear Polarization ◽  
Solid State Nmr ◽  
Nuclear Polarization ◽  
Magic Angle Spinning ◽  
Magic Angle ◽  
Cross Effect ◽  
Angle Spinning

Nitroxide biradicals are common polarizing agents used to enhance the sensitivity of solid-state NMR experiments via Magic Angle Spinning Dynamic Nuclear Polarization (MAS-DNP).

scholarly journals Many-body kinetics of dynamic nuclear polarization by the cross effect

2018 ◽  
Vol 97 (3) ◽  
Author(s):  
A. Karabanov ◽  
D. Wiśniewski ◽  
F. Raimondi ◽  
I. Lesanovsky ◽  
W. Köckenberger
Keyword(s):  
Dynamic Nuclear Polarization ◽  
Nuclear Polarization ◽  
Many Body ◽  
Cross Effect ◽  
The Cross ◽  
Kinetics Of

scholarly journals Effects of biradical deuteration on the performance of DNP: towards better performing polarizing agents

2016 ◽  
Vol 18 (1) ◽  
pp. 65-69 ◽  
Author(s):  
Frédéric A. Perras ◽  
Regina R. Reinig ◽  
Igor I. Slowing ◽  
Aaron D. Sadow ◽  
Marek Pruski
Keyword(s):  
Dynamic Nuclear Polarization ◽  
Nuclear Polarization ◽  
Cross Effect ◽  
The Cross

We study the effects of the deuteration of biradical polarizing agents on the efficiency of dynamic nuclear polarization (DNP) via the cross-effect.

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