Synthesis of FeCoNiCuZn single-phase high-entropy alloy by high-frequency electromagnetic-field assisted ball milling

2020 ◽  
Vol 498 ◽  
pp. 166151 ◽  
Author(s):  
Zhang Yingzhe ◽  
Chen Yudao ◽  
Qin Qingdong ◽  
Li Wei
Keyword(s):  
Electromagnetic Field ◽  
Ball Milling ◽  
High Frequency ◽  
Single Phase ◽  
High Entropy Alloy ◽  
High Entropy ◽  
High Frequency Electromagnetic Field

scholarly journals Formation of Cu2O Solid Solution via High-Frequency Electromagnetic Field-Assisted Ball Milling: The Reaction Mechanism

Materials ◽  
2020 ◽  
Vol 13 (3) ◽  
pp. 618 ◽  
Author(s):  
Yingzhe Zhang ◽  
Yudao Chen ◽  
Juan Li ◽  
Wei Li ◽  
Ding Chen ◽  
...  
Keyword(s):  
Solid Solution ◽  
Electromagnetic Field ◽  
Ball Milling ◽  
High Frequency ◽  
Environmental Water ◽  
Phenol Red ◽  
Degradation Of Dyes ◽  
Catalytically Active ◽  
High Frequency Electromagnetic Field ◽  
Aqueous Conditions

The contamination of environmental water with organic pollutants poses significant challenges for society, and much effort has been directed toward the development of catalysts and methods that can decompose these pollutants. While effort has been directed toward the fabrication of Cu2O catalysts by ball milling, this technique can involve long preparation times and provide low yields. In this study, we synthesized a solid solution of Cu2O in 22 h by high-frequency electric-field-assisted ball milling below 40 °C in only one step under aqueous conditions. We investigated the catalytic activities of the produced Cu2O solid solution in the microwave-assisted degradation of dyes, namely rhodamine B, phenol red and methyl orange. The prepared Cu2O solid solution was very catalytically active and completely degraded the above-mentioned dyes within 2 min. The one-dimensional diffusion model and the phase boundary (planar) model were found to describe the kinetics well. Synergism between ball milling and the high-frequency electromagnetic field plays a key role in the preparation of Cu2O solid solution nanoparticles. Ball milling facilitates the relaxation of the Cu2O lattice and high-frequency electromagnetic radiation accelerates the diffusion of Fe atoms into the Cu2O crystal along the (111) crystal plane, quickly leading to the formation of a Cu2O solid solution.

scholarly journals Effect of high-frequency electromagnetic field on microstructure of mold flux

2020 ◽  
Vol 39 (1) ◽  
pp. 368-376
Author(s):  
Xingjuan Wang ◽  
Hebin Jin ◽  
Liguang Zhu ◽  
Ran Liu ◽  
Tushun Song
Keyword(s):  
Electromagnetic Field ◽  
High Frequency ◽  
Mold Flux ◽  
Film Structure ◽  
Glass Layer ◽  
Slag Film ◽  
Flux Flow ◽  
Layer Form ◽  
Finite Element Software ◽  
High Frequency Electromagnetic Field

AbstractSoft-contact of molten steel can be achieved by applying a high-frequency electromagnetic field above the mold of continuous casting, which can effectively eliminate surface defects and achieve billets with no cracks and no oscillation marks. It also has some influence on the mold flux. In this study, the effect of a high-frequency electromagnetic field (20 kHz) on a mold flux flow field was simulated using a finite element software, and the slag film was extracted using a slag film simulator. The effect of the high-frequency magnetic field on the microstructure of the mold flux was analyzed using X-ray diffraction, Raman spectroscopy, and mineral phase testing. The results show that the high-frequency electromagnetic field disrupts the orderly movement and increases the movement rate of the liquid flux. The precipitate phase of the slag film did not change, but the silicate dimer Q1 decreased, the chain Q2 increased, and the network degree was increased. The slag film structure changed from the original two-layer form of crystalline layer–glass layer into a three-layer form of crystal layer–glass layer–crystal, and the crystallization ratio increased by 35% on average. The grain-size melilite granularity was reduced from the original 0.12 to 0.005 mm.

A review on phase prediction in high entropy alloys

2021 ◽  
pp. 095440622110089
Author(s):  
Vinay Kumar Soni ◽  
S Sanyal ◽  
K Raja Rao ◽  
Sudip K Sinha
Keyword(s):  
Solid Solution ◽  
Phase Formation ◽  
Single Phase ◽  
High Entropy Alloy ◽  
High Entropy Alloys ◽  
Modeling Tools ◽  
High Entropy ◽  
Recent Developments ◽  
Phase Prediction ◽  
The Stability

The formation of single phase solid solution in High Entropy Alloys (HEAs) is essential for the properties of the alloys therefore, numerous approach were proposed by many researchers to predict the stability of single phase solid solution in High Entropy Alloy. The present review examines some of the recent developments while using computational intelligence techniques such as parametric approach, CALPHAD, Machine Learning etc. for prediction of various phase formation in multicomponent high entropy alloys. A detail study of this data-driven approaches pertaining to the understanding of structural and phase formation behaviour of a new class of compositionally complex alloys is done in the present investigation. The advantages and drawbacks of the various computational are also discussed. Finally, this review aims at understanding several computational modeling tools complying the thermodynamic criteria for phase formation of novel HEAs which could possibly deliver superior mechanical properties keeping an aim at advanced engineering applications.

Design and deformation characteristics of single-phase Co-Cr-Fe-Ni-V high entropy alloy

2021 ◽  
pp. 161579
Author(s):  
Reliance Jain ◽  
M.R. Rahul ◽  
Poulami Chakraborty ◽  
Rama Krushna Sabat ◽  
Sumanta Samal ◽  
...  
Keyword(s):  
Single Phase ◽  
High Entropy Alloy ◽  
Deformation Characteristics ◽  
High Entropy

scholarly journals Phase stability of single phase Al0.12CrNiFeCo high entropy alloy upon irradiation

2018 ◽  
Vol 160 ◽  
pp. 1208-1216 ◽  
Author(s):  
B. Kombaiah ◽  
K. Jin ◽  
H. Bei ◽  
P.D. Edmondson ◽  
Y. Zhang
Keyword(s):  
Phase Stability ◽  
Single Phase ◽  
High Entropy Alloy ◽  
High Entropy

scholarly journals ЗМІНА ЕЛЕКТРИЧНИХ ВЛАСТИВОСТЕЙ НАСІННЯ ПІД ВПЛИВОМ ВИСОКОЧАСТОТНОГО ЕЛЕКТРОМАГНІТНОГО ОПРОМІНЕННЯ

2014 ◽  
pp. 151-155
Author(s):  
О. М. Петровський
Keyword(s):  
Electromagnetic Field ◽  
High Frequency ◽  
Electric Properties ◽  
Electric Resistance ◽  
Active Resistance ◽  
Exchange Processes ◽  
High Frequency Electromagnetic Field ◽  
Stimulation Of

Розглянуті питання передпосівної стимуляції на-сіння високочастотним електромагнітним полем.Запропоновано спосіб опромінення насіння і визна-чення його електричних характеристик. На основібудови клітин визначені електричні властивості біо-логічної тканини, з якої складається насіння. Пока-зана зміна складових активного опору в залежностівід частоти струму. Експериментально доведено,що еквівалентну електричну схему неможливо звес-ти до простих випадків з’єднання опорів і ємностей,а саме насіння не можна вважати нейтральнимдіелектриком. Розроблена методика оцінки інтенси-вності обмінних процесів залежно від електричногоопору насіння. The questions of stimulation of seed before sowing are considered by the high-frequency electromagnetic field considered. The method of irradiation of seed and determination of him is offered electric descriptions. On the basis of structure of cages electric properties of biological fabric which seed consist of are certain. The change of constituents of active resistance is shown depending on frequency of current. It is experimentally proved that it is impossible to erect an equivalent electric chart to the simple cases of connection of resistances and capacities, namely seed can not be considered a neutral dielectric. The method of estimation of intensity of exchange processes  is developed depending on electric resistance of seed.

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