Magnetic properties and shape memory effect of Fe–Cr–Ni–Si–Mn alloys produced by melt spinning technique

2007 ◽  
Vol 181 (1-3) ◽  
pp. 217-221 ◽  
Author(s):  
Takashi Todaka ◽  
Seiju Teshima ◽  
Masato Enokizono
ChemInform ◽  
2012 ◽  
Vol 43 (12) ◽  
pp. no-no
Author(s):  
R. Kainuma ◽  
W. Ito ◽  
R. Y. Umetsu ◽  
V. V. Khovaylo ◽  
T. Kanomata

2012 ◽  
Vol 189 ◽  
pp. 189-208 ◽  
Author(s):  
Vijay Srivastava ◽  
Kanwal Preet Bhatti

Although Heusler alloys have been known for more than a century, but since the last decade there has been a quantum jump in research in this area. Heusler alloys show remarkable properties, such as ferromagnetic shape memory effect, magnetocaloric effect, half metallicity, and most recently it has been shown that it can be used for direct conversion of heat into electricity. Heusler alloys Ni-Mn-Z (Z=Ga, Al, In, Sn, Sb), show a reversible martensitic transformation and unusual magnetic properties. Other classes of intermetallic Heusler alloy families that are half metallic (such as the half Heusler alloys Ni-Mn-Sb and the full Heusler alloy Co2MnGe) are attractive because of their high Curie temperature and structural similarity to binary semiconductors. Unlike Ni-Mn-Ga, Ni-Mn-In and Ni-Mn-Sn transform from ferromagnetic austenite to non-ferromagnetic martensite. As is consistent with the Clausius-Clapeyron equation, the martensitic phase transformation can be manipulated by a magnetic field, leading to possible applications of these materials enabling the magnetic shape memory effect, energy conversion and solid state refrigeration. In this paper, we summarize the salient features of Heusler alloys, like the structure, magnetic properties and potential application of this family of alloys in industry.


1998 ◽  
Vol 46 (1) ◽  
pp. 137-147 ◽  
Author(s):  
M.O. Prado ◽  
F.C. Lovey ◽  
L. Civale

Polymers ◽  
2019 ◽  
Vol 11 (10) ◽  
pp. 1599 ◽  
Author(s):  
Xiaoming Qi ◽  
Wentong Yang ◽  
Laiming Yu ◽  
Wenjun Wang ◽  
Haohao Lu ◽  
...  

One-dimensional shape memory polymer fibers (SMPFs) have obvious advantages in mechanical properties, dispersion properties, and weavability. In this work, a method for fabricating semi-crystallization ethylene-vinyl acetate copolymer (EVA) fiber with two-way shape memory effect by melt spinning and ultraviolet (UV) curing was developed. Here, the effect of crosslink density on its performance was systematically analyzed by gel fraction measurement, tensile tests, DSC, and TMA analysis. The results showed that the crosslink density and shape memory properties of EVA fiber could be facilely adjusted by controlling UV curing time. The resulting EVA fiber with cylindrical structure had a diameter of 261.86 ± 13.07 μm, and its mechanical strength and elongation at break were 64.46 MPa and 114.33%, respectively. The critical impact of the crosslink density and applied constant stress on the two-way shape memory effect were analyzed. Moreover, the single EVA fiber could lift more than 143 times its own weight and achieve 9% reversible actuation strain. The reversible actuation capability was significantly enhanced by a simple winding design of the single EVA fiber, which provided great potential applications in smart textiles, flexible actuators, and artificial muscles.


2009 ◽  
Vol 635 ◽  
pp. 23-31 ◽  
Author(s):  
Ryosuke Kainuma ◽  
K. Ito ◽  
W. Ito ◽  
R.Y. Umetsu ◽  
T. Kanomata ◽  
...  

The magnetic properties of the parent and martensite phases of the Ni2Mn1+xSn1-x and Ni2Mn1+xIn1-x ternary alloys and the magnetic field-induced shape memory effect obtained in NiCoMnIn alloys are reviewed, and our recent work on powder metallurgy performed for NiCoMnSn alloys is also introduced. The concentration dependence of the total magnetic moment for the parent phase in the NiMnSn alloys is very different from that in the NiMnIn alloys, and the magnetic properties of the martensite phase with low magnetization in both NiMnSn and NiMnIn alloys has been confirmed by Mössbauer examination as being paramagnetic, but not antiferromagnetic. The ductility of NiCoMnSn alloys is drastically improved by powder metallurgy using the spark plasma sintering technique, and a certain degree of metamagnetic shape memory effect has been confirmed.


2015 ◽  
Vol 79 (9) ◽  
pp. 1134-1140 ◽  
Author(s):  
A. V. Shelyakov ◽  
N. N. Sitnikov ◽  
A. P. Menushenkov ◽  
R. N. Rizakhanov ◽  
A. A. Ashmarin

2013 ◽  
Vol 738-739 ◽  
pp. 247-251 ◽  
Author(s):  
Ana Druker ◽  
Paulo La Roca ◽  
Philippe Vermaut ◽  
Patrick Ochim ◽  
Jorge Malarría

At room temperature, Fe-15Mn-5Si-9Cr-5Ni alloys are usually austenitic and the application of a stress induces a reversible martensitic transformation leading to a shape memory effect (SME). However, when a ribbon of this material is obtained by melt-spinning, the rapid solidification stabilizes a high-temperature ferritic phase. The goals of this work were to find the appropriate heat treatment in order to recover the equilibrium austenitic phase, characterize the ribbon form of this material and evaluate its shape memory behaviour. We found that annealing at 1050°C for 60 min, under a protective argon atmosphere, followed by a water quenching stabilizes the austenite to room temperature. The yield stress, measured by tensile tests, is 250 MPa. Shape-memory tests show that a strain recovery of 55% can be obtained, which is enough for certain applications.


2021 ◽  
Vol 31 (4) ◽  
Author(s):  
Dan Nguyen Huy ◽  
Xuan Hau Kieu ◽  
Hai Yen Nguyen ◽  
Thi Thanh Pham ◽  
Huy Ngoc Nguyen ◽  
...  

Shape memory alloys (SMAs) are ones which can return to their original shape under impact of temperature or external magnetic field. The SMAs are capable of many applications in the fields of biomedical, aerospace, microelectronics, automation, for examples, orthodontics, stents, bone anchors, automatic valves, heat sensors, nanotweezers, robots... Recently, researchers have discovered the shape memory effect (SME) on high entropy alloys (HEAs). The combination of superior properties of SMAs and HEAs (high strength, heat resistance, low diffusion coefficient...) would bring useful practical applications in practice. In this paper, we will present an overview of the research situation of SMAs and our initial results obtained on Ni-Ti based alloys of Ni-Ti, Ni-Ti-Zr-Cu-Cr, Ni-Ti-Zr-Cu-Co, Ni-Ti-Zr-Cu-Nb, and Ni-Ti-Zr-Cu-Hf prepared by melt-spinning method.


2008 ◽  
Vol 59 ◽  
pp. 24-29 ◽  
Author(s):  
Yoichi Kishi ◽  
Zenjiro Yajima ◽  
Teiko Okazaki ◽  
Yasubumi Furuya ◽  
Manfred Wuttig

It is well known that FePd alloys are effective as a magneto-thermoelastic actuator material, because they have large magnetostriction and shape memory effect. In order to use the alloys for a micro-actuator, magnetic properties and microstructures have been examined as for rapidly solidified Fe-29.6 at% Pd alloy ribbons. The ribbons exhibit a large magnetostriction at room temperature and good shape memory effect. Magnetostriction and coercive force of the ribbons markedly depend on the direction of the applied magnetic field. Maximum values of magnetostriction and coercive force are obtained at θ = 85 degree (θ is the angle between the magnetic field and the ribbon plane). Relief effects corresponding to the formation of FCT martensite variants are observed on the grains. X-ray diffraction profile at room temperature shows that FCT martensitic phase and FCC parent phase coexist in the ribbon. Dense striations are observed in the TEM bright field images of FCT martensite plates. Selected area electron diffraction patterns revealed the striations to be thin twins.


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