Liquid phase PVTx properties of (water+tert-butanol) binary mixtures at temperatures from 278.15 to 323.15K and pressures from 0.1 to 100MPa

2013 ◽  
Vol 61 ◽  
pp. 161-168 ◽  
Author(s):  
Gennadiy I. Egorov ◽  
Dmitriy M. Makarov ◽  
Arkadiy M. Kolker
Keyword(s):  
Liquid Phase ◽  
Binary Mixtures ◽  
Tert Butanol ◽  
Pvtx Properties

Catalytic hydrogenation of binary and ternary mixtures of unsaturated substances in the liquid phase on platinum

1979 ◽  
Vol 44 (8) ◽  
pp. 2378-2383 ◽  
Author(s):  
Libor Červený ◽  
Radka Junová ◽  
Vlastimil Růžička
Keyword(s):  
Liquid Phase ◽  
Binary Mixtures ◽  
Silica Gel ◽  
Catalytic Hydrogenation ◽  
Ternary Systems ◽  
Ternary Mixtures ◽  
Unsaturated Alcohol ◽  
Solvent Concentration ◽  
Binary And Ternary Mixtures ◽  
Hydrogenation Selectivity

Hydrogenation of olefinic substrates in binary and ternary mixtures using 5% Pt on silica gel as the catalyst was studied in normal conditions in the liquid phase with methanol or cyclohexane or in solvent-free systems. The effect of the solvent concentration on the selectivity of hydrogenation of the unsaturated alcohol-olefin binary mixtures was investigated. In ternary systems of unsaturated substrates, the effect of each of the substrates on the selectivity of hydrogenation of the remaining two substances was examined. Another system was found in which a jump change of the hydrogenation selectivity occurred on the vanishing of the fastest reacting substance.

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