Preparation of thermally stable anatase TiO2 photocatalyst from TiOF2 precursor and its photocatalytic activity

2011 ◽  
Vol 509 (13) ◽  
pp. 4557-4562 ◽  
Author(s):  
Kangle Lv ◽  
Jiaguo Yu ◽  
Longzhe Cui ◽  
Shulin Chen ◽  
Mei Li
2014 ◽  
Vol 924 ◽  
pp. 260-268 ◽  
Author(s):  
Hao Chen ◽  
Lan Fang Yao ◽  
Song Lin Yang ◽  
Ya Qin Wang ◽  
Xing Liang ◽  
...  

The crystal structures, band structures, density of states, charge density, overlap population and optical properties of pure anatase TiO2 and Pr-doped anatase TiO2 were studied by using the plane-wave pseudopotential method based on the first-principles. After Pr doping, the valence band and the conduction band moved down and became dense, energy gap became narrow and a impurity band which consists of Pr 4f states appeared. And the dipole moment got improved, which is good for the separate of the electron-hole pairs. These effectively overcome two huge shortcomings of TiO2. Besides, Pr-doped anatase TiO2 produced more carriers which have good transport properties and the absorption spectra of Pr-O bond appear in the region that the wavelength is longer. The calculation results of optical properties show that the absorption edge occured red shift, which means the photocatalytic activity of anatase TiO2 got remarkable improved during visible-light region. This conforms to the previous analysis. So the photocatalytic activity of anatase TiO2 got remarkable improved after Pr doping.


2019 ◽  
Vol 733 ◽  
pp. 136676 ◽  
Author(s):  
Hongwei Feng ◽  
Hui Xu ◽  
Hongtu Feng ◽  
Ying Gao ◽  
Xinyuan Jin

2019 ◽  
Vol 22 (6) ◽  
pp. 299-304
Author(s):  
Heny Puspita Dewi ◽  
Joko Santoso ◽  
Nur Firda Trianda ◽  
Rodiansono Rodiansono

Carbon-titanium oxide nanocomposite (denoted as @C-TiO2) was successfully synthesized via hydrothermal method at 150°C for 24 h. The C-TiO2 nanocomposite was furtherly modified by adding an Ag metal dopant (denoted as Ag@C-TiO2) to improve and applied to the photocatalytic degradation of Sasirangan textile wastewater. The composite photocatalysts were characterized by XRD and UV–Vis DRS spectroscopies. XRD patterns showed that TiO2 in @C-TiO2 mainly consisted of a brookite phase, as indicated by a series sharp diffraction peak at 2θ = 27.2° (111), 31.5° (121) and 55.9° (241). The calculated band gap energy (Eg) derived from UV-Vis DRS spectra for TiO2, @C-TiO2, and Ag@C-TiO2 were 2.95 eV, 2.54 eV, and 2.74 eV, respectively. Ag@C-TiO2 photocatalyst was found to be active for the photocatalytic degradation of Sasirangan textile wastewater, as indicated by the change of wastewater color from dark to clear. The quantitative photocatalytic activity of Ag@C-TiO2 was evaluated in the degradation of methylene blue, whereas the conversion of methylene blue was 41.3%. The addition of Ag to @C-TiO2 is believed to play an essential role in the enhancement of photocatalytic activity.


2020 ◽  
Vol 19 (3) ◽  
pp. 399-405
Author(s):  
Joel Molina-Reyes ◽  
Alejandra Romero-Morán ◽  
José L. Sánchez-Salas

Experimental conditions to fabricate rutile-TiO2 nanotubes coated with a conformal anatase-TiO2 thin layer using ALD were reported. A considerable increase in the photocatalytic activity associated with these surface modifications was also observed.


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