Effect of high pressure on the fluctuation conductivity and the charge transfer of YBa2Cu3O7−δ single crystals

2008 ◽  
Vol 453 (1-2) ◽  
pp. 69-74 ◽  
Author(s):  
R.V. Vovk ◽  
M.A. Obolenskii ◽  
A.A. Zavgorodniy ◽  
A.V. Bondarenko ◽  
I.L. Goulatis ◽  
...  
Keyword(s):  
High Pressure ◽  
Charge Transfer ◽  
Single Crystals ◽  
Fluctuation Conductivity

scholarly journals Single Crystal Growth and Physical Properties of Pyroxene CoGeO3

Crystals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 378
Author(s):  
Li Zhao ◽  
Zhiwei Hu ◽  
Hanjie Guo ◽  
Christoph Geibel ◽  
Hong-Ji Lin ◽  
...  
Keyword(s):  
High Pressure ◽  
Magnetic Properties ◽  
Magnetic Susceptibility ◽  
Crystal Growth ◽  
Physical Properties ◽  
Single Crystal ◽  
Single Crystals ◽  
Magnetic Moments ◽  
Single Crystal Growth ◽  
The Impact

We report on the synthesis and physical properties of cm-sized CoGeO3 single crystals grown in a high pressure mirror furnace at pressures of 80 bar. Direction dependent magnetic susceptibility measurements on our single crystals reveal highly anisotropic magnetic properties that we attribute to the impact of strong single ion anisotropy appearing in this system with TN∼33.5 K. Furthermore, we observe effective magnetic moments that are exceeding the spin only values of the Co ions, which reveals the presence of sizable orbital moments in CoGeO3.

scholarly journals From Slater to Mott physics by epitaxially engineering electronic correlations in oxide interfaces

2021 ◽  
Vol 7 (1) ◽  
Author(s):  
Carla Lupo ◽  
Evan Sheridan ◽  
Edoardo Fertitta ◽  
David Dubbink ◽  
Chris J. Pickard ◽  
...  
Keyword(s):  
Phase Diagram ◽  
High Pressure ◽  
Charge Transfer ◽  
Lower Mantle ◽  
Random Structure ◽  
Titanium Oxides ◽  
Oxide Interfaces ◽  
Electronic Correlations ◽  
Epitaxial Strain ◽  
Magnetic Switching

AbstractUsing spin-assisted ab initio random structure searches, we explore an exhaustive quantum phase diagram of archetypal interfaced Mott insulators, i.e. lanthanum-iron and lanthanum-titanium oxides. In particular, we report that the charge transfer induced by the interfacial electronic reconstruction stabilises a high-spin ferrous Fe2+ state. We provide a pathway to control the strength of correlation in this electronic state by tuning the epitaxial strain, yielding a manifold of quantum electronic phases, i.e. Mott-Hubbard, charge transfer and Slater insulating states. Furthermore, we report that the electronic correlations are closely related to the structural oxygen octahedral rotations, whose control is able to stabilise the low-spin state of Fe2+ at low pressure previously observed only under the extreme high pressure conditions in the Earth’s lower mantle. Thus, we provide avenues for magnetic switching via THz radiations which have crucial implications for next generation of spintronics technologies.

scholarly journals Synthesis and Photobehavior of a NewDehydrobenzoannulene-Based HOF with Fluorine Atoms: From Solution to Single Crystals Observation

2021 ◽  
Vol 22 (9) ◽  
pp. 4803
Author(s):  
Eduardo Gomez ◽  
Ichiro Hisaki ◽  
Abderrazzak Douhal
Keyword(s):  
Charge Transfer ◽  
Single Crystals ◽  
Parent Compound ◽  
Time Resolved ◽  
Strong Basis ◽  
Triplet Structure ◽  
Carboxylic Groups ◽  
Potential Applications ◽  
A Charge ◽  
Further Development

Hydrogen-bonded organic frameworks (HOFs) are the focus of intense scientific research due their potential applications in science and technology. Here, we report on the synthesis, characterization, and photobehavior of a new HOF (T12F-1(124TCB)) based on a dehydrobenzoannulene derivative containing fluorine atoms (T12F-COOH). This HOF exhibits a 2D porous sheet, which is hexagonally networked via H-bonds between the carboxylic groups, and has an interlayers distance (4.3 Å) that is longer than that of a typical π–π interaction. The presence of the fluorine atoms in the DBA molecular units largely increases the emission quantum yield in DMF (0.33, T12F-COOH) when compared to the parent compound (0.02, T12-COOH). The time-resolved dynamics of T12F-COOH in DMF is governed by the emission from a locally excited state (S1, ~ 0.4 ns), a charge-transfer state (S1(CT), ~ 2 ns), and a room temperature emissive triplet state (T1, ~ 20 ns), in addition to a non-emissive triplet structure with a charge-transfer character (T1(CT), τ = 0.75 µs). We also report on the results using T12F-ester. Interestingly, FLIM experiments on single crystals unravel that the emission lifetimes of the crystalline HOF are almost twice those of the amorphous ones or the solid T12F-ester sample. This shows the relevance of the H-bonds in the photodynamics of the HOF and provides a strong basis for further development and study of HOFs based on DBAs for potential applications in photonics.

Femtosecond pump-probe characterization of high-pressure grown Al x Ga 1-x N single crystals

2009 ◽  
Author(s):  
Jie Zhang ◽  
A. Belousov ◽  
S. Katrych ◽  
J. Jun ◽  
J. Karpinski ◽  
...  
Keyword(s):  
High Pressure ◽  
Single Crystals ◽  
Pump Probe

Crystal Field Analysis of the Magnetization Curves of HoFe11Ti under High Pressure

2013 ◽  
Vol 818 ◽  
pp. 72-76 ◽  
Author(s):  
Gang Su
Keyword(s):  
High Pressure ◽  
Hydrogen Atom ◽  
Electric Field ◽  
Single Crystals ◽  
High Pressures ◽  
Field Analysis ◽  
Magnetization Curves ◽  
Crystalline Electric Field ◽  
Crystalline Anisotropy ◽  
Magneto Crystalline Anisotropy

The crystalline electric field parameters Anmfor HoFe11Ti under different pressures were evaluated by fitting calculations to the magnetization curves measured on the single crystals at several temperatures. It was found that magneto-crystalline anisotropy has been changed by high pressure and the Anmfor HoFe11Ti under high pressures are strikingly different from Anmfor the corresponding HoFe11Ti H with interstitial hydrogen atom.

Front Cover: Piezofluorochromism in Charge-Transfer Inclusion Crystals: The Influence of High Pressure versus Mechanical Grinding (ChemPhotoChem 5/2018)

ChemPhotoChem ◽  
2018 ◽  
Vol 2 (5) ◽  
pp. 382-382
Author(s):  
Toshikazu Ono ◽  
Yoshifumi Tsukiyama ◽  
Ai Taema ◽  
Hiroyasu Sato ◽  
Hidetoshi Kiyooka ◽  
...  
Keyword(s):  
High Pressure ◽  
Charge Transfer ◽  
Mechanical Grinding ◽  
Front Cover

Ultraviolet light emission from self-organized p–n domains in cubic boron nitride bulk single crystals grown under high pressure

2002 ◽  
Vol 81 (22) ◽  
pp. 4145-4147 ◽  
Author(s):  
T. Taniguchi ◽  
K. Watanabe ◽  
S. Koizumi ◽  
I. Sakaguchi ◽  
T. Sekiguchi ◽  
...  
Keyword(s):  
High Pressure ◽  
Boron Nitride ◽  
Single Crystals ◽  
Ultraviolet Light ◽  
Light Emission ◽  
Cubic Boron Nitride ◽  
Self Organized ◽  
Bulk Single Crystals

Growth direction dependent separate-channel charge transport in organic weak charge-transfer co-crystal of anthracene-DTTCNQ

2022 ◽  
Author(s):  
Hui Jiang ◽  
Jun Ye ◽  
Peng Hu ◽  
Shengli Zhu ◽  
Yanqin Liang ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Charge Transport ◽  
Electronic Properties ◽  
Single Crystals ◽  
Organic Semiconductors ◽  
Crystal Engineering ◽  
Molecular Crystal ◽  
Growth Direction ◽  
Weak Charge ◽  
Separate Channel

Co-crystallization is an efficient way of molecular crystal engineering to tune the electronic properties of organic semiconductors. In this work, we synthesized anthracene-4,8-bis(dicyanomethylene)4,8-dihydrobenzo[1,2-b:4,5-b’]-dithiophene (DTTCNQ) single crystals as a template to...

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