Effect of P on glass forming ability, magnetic properties and oxidation behavior of FeSiBP amorphous alloys

2017 ◽  
Vol 84 ◽  
pp. 142-147 ◽  
Author(s):  
Chengjuan Wang ◽  
Aina He ◽  
Anding Wang ◽  
Jing Pang ◽  
Xiaofeng Liang ◽  
...  
2006 ◽  
Vol 21 (4) ◽  
pp. 1019-1024 ◽  
Author(s):  
J.M. Park ◽  
J.S. Park ◽  
D.H. Kim ◽  
J-H. Kim ◽  
E. Fleury

Fe element was partially substituted by Zr and Co in an attempt to enhance the glass-forming ability, and mechanical and soft magnetic properties of Fe74-xNb6B17Y3(Zr, Co)x (x = 3, 5, 8) amorphous alloys. Both partial replacements resulted in the enhancement of the glass-forming ability, and 3-mm diameter rods with a fully amorphous structure were prepared by a copper mold casting method. Zr and Co containing Fe-based bulk amorphous alloys exhibited high compressive fracture strength of about 4 and 3.5 GPa, respectively. However, Zr and Co induced different effects on the magnetic properties. Whereas the partial replacement of Fe by Zr was found to decrease dramatically the saturation magnetization, the partial replacement of Fe by Co provided an increase of about 25% of the saturation magnetization.


2015 ◽  
Vol 1120-1121 ◽  
pp. 440-445
Author(s):  
Hua Man

The glass forming ability and magnetic properties were investigated for adding neodymium to the Fe71-xNb4B25Ndx (x=0, 3, 5, 7,10) alloys prepared by copper suction casting. It was found that proper neodymium (x=5~10 at.%) could improve glass forming ability of Fe-Nb-B alloys effectively. Bulk amorphous Fe66Nd5B25Nb4 and Fe64Nd7B25Nb4 samples were obtained and presented high thermal stability and good soft magnetic properties. The value of activation energy of the first crystallization peak for the bulk amorphous alloy Fe64Nd7B25Nb4 is 683 kJ/mol.


2021 ◽  
Vol 1016 ◽  
pp. 274-279
Author(s):  
Teruo Bitoh ◽  
Takafumi Hibino ◽  
Hisato Koshiba

The thermal and magnetic properties of the ternary Fe-B-C and quaternary Fe-B-C-Si amorphous alloys have been investigated. It has been discovered that the ternary Fe-B-C amorphous alloys with compositions close to Fe79.3B14.3C6.4 exhibit a glass transition prior to crystallization on heating. The alloys also have high mass magnetization of 176–178 A m2/kg at room temperature. In addition, the glass-forming ability (GFA) of the alloys is significantly enhanced by the addition of 4 at% Si while maintaining high magnetization of approximately 170 A m2/kg at room temperature. In was found that the Fe23(B, C)6 phase (Cr23C6-type) is formed during crystallization of the quaternary Fe-B-C-Si alloys with the large GFA. It was also confirmed that the amorphous powders of Fe-Cr-B-C-Si alloys could be produced by a conventional water atomization method and exhibit the low core losses of 305–362 kW/m3 at 100 kHz and 100 mT. The quaternary Fe-B-C-Si amorphous alloys with high GFA, high magnetization and low core losses are suitable for a core material of various magnetic components.


Metals ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 1577
Author(s):  
Xin Wang ◽  
Qiang Wang ◽  
Benzhen Tang ◽  
Ding Ding ◽  
Li Cui ◽  
...  

Elemental substitution is commonly used to improve the formability of metallic glasses and the properties of amorphous alloys over a wide compositional range. Therefore, it is essential to investigate the influence of element content change on the formability as well as magnetic and other properties. The purpose is to achieve tailorable properties in these alloys with enhanced glass forming ability. In this work, the glass-forming ability (GFA) and magnetic properties of the minor Mn-substituted Fe88Zr8B4 amorphous alloy were investigated. The addition of Mn improving the amorphous forming ability of the alloy. With the addition of Mn, the magnetic transition temperature, saturation magnetization and the magnetic entropy changes (−ΔSm) peaks decreased simultaneously, which is possibly caused by the antiferromagnetic coupling between Fe and Mn atoms. The dependence of −ΔSmpeak on Tc displays a positive correlation compared to the −ΔSmpeak- Tc−2/3 relationship proposed by Belo et al.


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