Probing the SmRhSn magnetic state by AC/DC magnetic measurements and 119Sn Mössbauer spectroscopy

2012 ◽  
Vol 22 ◽  
pp. 154-159 ◽  
Author(s):  
J. Gurgul ◽  
K. Łątka ◽  
A.W. Pacyna ◽  
R. Pöttgen
Keyword(s):  
Mössbauer Spectroscopy ◽  
Mossbauer Spectroscopy ◽  
Magnetic State ◽  
Magnetic Measurements ◽  
119Sn Mössbauer Spectroscopy ◽  
Mößbauer Spectroscopy

scholarly journals Testing the Applicability of 119Sn Mössbauer Spectroscopy for the Internal Stress Study in Ternary and Co-Doped Ni-Mn-Sn Metamagnetic Alloys

Metals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 450
Author(s):  
I. Unzueta ◽  
J. López-García ◽  
V. Sánchez-Alarcos ◽  
V. Recarte ◽  
J. I. Pérez-Landazábal ◽  
...  
Keyword(s):  
Mössbauer Spectroscopy ◽  
Internal Stress ◽  
Mossbauer Spectroscopy ◽  
Magnetic Measurements ◽  
Ternary Alloys ◽  
119Sn Mössbauer Spectroscopy ◽  
Mößbauer Spectroscopy ◽  
Structural Recovery ◽  
Singlet Component ◽  
Co Doped

The influence of both the Co addition and the internal stress on the atomic level magnetism is comparatively studied in Ni50Mn37Sn13 and Ni45Mn38Sn13Co4 alloys by magnetic measurements and 119Sn Mössbauer spectroscopy. The results show that the saturation magnetization and the hyperfine field follow the same temperature trend. The internal stress state is investigated by subjecting the samples to milling and annealing treatments, and tracking the singlet component revealed by 119Sn Mössbauer spectroscopy. Contrary to what was expected, in the Co-doped Ni-Mn-Sn sample the singlet component can be resolved between the milled and annealed states in both martensite and austenite phases. Therefore, the results demonstrate the feasibility of tracking the singlet component upon the structural recovery in Co-doped Ni-Mn-Sn alloys in a much wider range than in ternary alloys. In addition, it is concluded that the transferred dipolar field at Sn from the neighbor magnetic atoms depends very strongly on the stress field and on the microstructural order surrounding Sn atoms. The observed sensitivity of Sn Mössbauer probe atoms to slight microstructural distortions make 119Sn a powerful technique for the characterization of the stress present in Sn containing metamagnetic shape memory alloys.

In situ 119Sn Mössbauer spectroscopy study of Sn-based electrode materials

2006 ◽  
Vol 167 (1-3) ◽  
pp. 733-738 ◽  
Author(s):  
Abdelmaula Aboulaich ◽  
Florent Robert ◽  
Pierre Emmanuel Lippens ◽  
Laurent Aldon ◽  
Josette Olivier-Fourcade ◽  
...  
Keyword(s):  
Mössbauer Spectroscopy ◽  
Electrode Materials ◽  
Mossbauer Spectroscopy ◽  
Spectroscopy Study ◽  
119Sn Mössbauer Spectroscopy ◽  
Mößbauer Spectroscopy

Inhomogeneous Magnetic State of Се2Fe17 Evidenced by Mössbauer Spectroscopy

2018 ◽  
Vol 60 (9) ◽  
pp. 1718-1726
Author(s):  
S. P. Naumov ◽  
V. V. Serikov ◽  
N. M. Kleinerman ◽  
A. G. Kuchin ◽  
N. V. Mushnikov ◽  
...  
Keyword(s):  
Mössbauer Spectroscopy ◽  
Mossbauer Spectroscopy ◽  
Magnetic State ◽  
Mößbauer Spectroscopy

Ternary Stannides RE3Ru4Sn13 (RE = La, Ce, Pr, Nd) – Structure, Magnetic Properties, and 119Sn Mössbauer Spectroscopy

2011 ◽  
Vol 66 (7) ◽  
pp. 664-670
Author(s):  
◽  
Christian Schwickert ◽  
Thorsten Langer ◽  
Rainer Pöttgen
Keyword(s):  
Mössbauer Spectroscopy ◽  
Mossbauer Spectroscopy ◽  
Three Dimensional ◽  
Magnetic Ordering ◽  
119Sn Mössbauer Spectroscopy ◽  
X Ray Diffraction ◽  
Temperature Dependent ◽  
Mößbauer Spectroscopy ◽  
Arc Melting ◽  
Different Types

The ternary stannides RE3Ru4Sn13 (RE = La, Ce, Pr, Nd) were obtained by arc-melting of the elements. The polycrystalline samples were characterized by powder X-ray diffraction. The structures of three compounds were refined from single-crystal diffractometer data: Yb3Rh4Sn13 type, Pm3̄n, a = 977.74(3) pm, wR2 = 0.0379, 280 F2 values for La3Ru4Sn13, a = 971.34(9) pm, wR2 = 0.0333, 274 F2 values for Ce3Ru4Sn13, a = 970.68(8) pm, wR2 = 0.0262, 272 F2 values for Nd3Ru4Sn13 with 13 variables per refinement. The structures consist of three-dimensional networks of condensed RuSn6/2 trigonal prisms with the RE (CN 16) and Sn2 (CN 12) atoms in two different types of cavities of the networks. The two crystallographically independent tin sites have been resolved by 119Sn Mössbauer spectroscopy. Temperature-dependent magnetic susceptibility measurements of Ce3Ru4Sn13 gave a reduced magnetic moment of 2.32 μB per Ce atom, indicating intermediate cerium valence. No magnetic ordering was evident down to 3 K.

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