Recent research works on bulk-metallic glasses (BMGs) have opened a window to create a new
generation of structural materials for applications. Although the mechanical behavior of BMGs is
being studied widely, the fatigue characteristics are poorly understood. The uniaxial tension-tension
high-cycle fatigue (HCF) studies were performed on zirconium (Zr)-based bulk-metallic glasses
(BMGs): Zr50Cu40Al10, Zr50Cu30Al10Ni10, Zr50Cu37Al10Pd3, and Zr41.2Cu12.5Ni10Ti13.8Be22.5, in
atomic percent. The HCF experiments were conducted using an electrohydraulic machine at a
frequency of 10 Hz with a R ratio of 0.1, where R = σmin./σmax., where σmin. and σmax. are the applied
minimum and maximum stresses, respectively. The fatigue-endurance limit of Zr50Cu37Al10Pd3 was
significantly greater than those of Zr50Cu40Al10, Zr50Cu30Al10Ni10, and Zr41.2Ti13.8Cu12.5Ni10Be22.5. In
order to compare the fatigue property with the crystalline alloys, the same HCF experiments were
also performed on Ti-6-4, drill tool steel, and Al 7075. The fatigue lifetime of Zr-based BMGs is
generally comparable to those of Ti-6-4 and drill-tool-steel crystalline alloys and is greater than that
of Al 7075 alloy. The fracture morphology of BMGs indicates that fatigue-crack-propagation
region included the distinct rough striations and the fine striations. The possible mechanism for the
striation formation was proposed.