Dipole moment and heat capacity in the ideal gas state derived from relative permittivity and speed of sound measurements for HFO-1123 and HCFO-1224yd(Z)

2020 ◽  
Vol 118 ◽  
pp. 354-364 ◽  
Author(s):  
Yuya Kano ◽  
Yohei Kayukawa ◽  
Yoshitaka Fujita
Keyword(s):  
Heat Capacity ◽  
Dipole Moment ◽  
Speed Of Sound ◽  
Relative Permittivity ◽  
Ideal Gas ◽  
The Ideal

Speed of sound and ideal-gas heat capacity at constant pressure of gaseous trifluoroiodomethane (CF3I)

1997 ◽  
Vol 137 (1-2) ◽  
pp. 121-131 ◽  
Author(s):  
Y.Y. Duan ◽  
L.Q. Sun ◽  
L. Shi ◽  
M.S. Zhu ◽  
L.Z. Han
Keyword(s):  
Heat Capacity ◽  
Speed Of Sound ◽  
Constant Pressure ◽  
Ideal Gas

FALSIFICATIONS OF POISSON ADIABATE, HUGONIO ADIABATE, LAPLACE SOUND SPEEDS. MODERNIZATION OF FOUNDATIONS OF THERMODYNAMICS

2020 ◽  
Vol 5 (333) ◽  
pp. 58-67
Author(s):  
K.B. Jakupov ◽  
Keyword(s):  
Shock Wave ◽  
Heat Capacity ◽  
Specific Heat ◽  
Specific Heat Capacity ◽  
Speed Of Sound ◽  
Constant Pressure ◽  
Energy Balance Equation ◽  
Ideal Gas ◽  
Constant Volume ◽  
Capacity Coefficient

The inequality of the universal gas constant of the difference in the heat capacity of a gas at constant pressure with the heat capacity of a gas at a constant volume is proved. The falsifications of using the heat capacity of a gas at constant pressure, false enthalpy, Poisson adiabat, Laplace sound speed, Hugoniot adiabat, based on the use of the false equality of the universal gas constant difference in the heat capacity of a gas at constant pressure with the heat capacity of a gas at a constant volume, have been established. The dependence of pressure on temperature in an adiabatic gas with heat capacity at constant volume has been established. On the basis of the heat capacity of a gas at a constant volume, new formulas are derived: the adiabats of an ideal gas, the speed of sound, and the adiabats on a shock wave. The variability of pressure in the field of gravity is proved and it is indicated that the use of the specific coefficient of ideal gas at constant pressure in gas-dynamic formulas is pointless. It is shown that the false “basic formula of thermodynamics” implies the falseness of the equation with the specific heat capacity at constant pressure. New formulas are given for the adiabat of an ideal gas, adiabat on a shock wave, and the speed of sound, which, in principle, do not contain the coefficient of the specific heat capacity of a gas at constant pressure. It is shown that the well-known equation of heat conductivity with the gas heat capacity coefficient at constant pressure contradicts the basic energy balance equation with the gas heat capacity coefficient at constant volume.

Ideal Gas Heat Capacity Derived from Speed of Sound Measurements in the Gaseous Phase for trans-1,3,3,3-Tetrafluoropropene

2013 ◽  
Vol 58 (11) ◽  
pp. 2966-2969 ◽  
Author(s):  
Yuya Kano ◽  
Yohei Kayukawa ◽  
Kenichi Fujii ◽  
Haruki Sato
Keyword(s):  
Heat Capacity ◽  
Gaseous Phase ◽  
Speed Of Sound ◽  
Ideal Gas

Extremes in Dependences of Enthalpy and Entropy of Saturated Vapour on Temperature

1997 ◽  
Vol 62 (5) ◽  
pp. 679-695
Author(s):  
Josef P. Novák ◽  
Anatol Malijevský ◽  
Jaroslav Dědek ◽  
Jiří Oldřich
Keyword(s):  
Heat Capacity ◽  
Equation Of State ◽  
Ideal Gas ◽  
Corresponding States ◽  
Saturated Vapour ◽  
Enthalpy And Entropy ◽  
The Ideal

It was proved that the enthalpy of saturated vapour as a function of temperature has a maximum for all substances. The dependence of the entropy of saturated vapour on temperature can be monotonous, has a minimum and a maximum, or has only a maximum. The thermodynamic relations were derived for the existence of the extremes which enable their computation from the knowledge of dependence of the ideal-gas heat capacity on temperature and an equation of state. A method based on the theorem of corresponding states was proposed for estimating the extremes, and its results were compared with literature data. The agreement between the literature and estimated temperatures corresponding to the extremes is very good. The procedure proposed can serve for giving precision to the H-p and T-S diagrams commonly used in applied thermodynamics.

AN APPLICATION OF NONEXTENSIVE PARAMETER: THE NONEXTENSIVE GAS AND REAL GAS

2007 ◽  
Vol 21 (06) ◽  
pp. 947-953 ◽  
Author(s):  
YAHUI ZHENG ◽  
JIULIN DU
Keyword(s):  
Heat Capacity ◽  
Second Virial Coefficient ◽  
Ideal Gas ◽  
Quasi Equilibrium ◽  
Equilibrium System ◽  
Real Gas ◽  
Nonextensive Statistics ◽  
Thomson Coefficient ◽  
Ideal Gas Model ◽  
The Ideal

By application of the nonextensive statistics to the ideal gas model, we establish a nonextensive gas model. If we regard the nonextensive gas as a real gas, we can use the nonextensive parameter q ∈ ℝ in Tsallis statistics to describe Joule coefficient, Joule–Thomson coefficient, second virial coefficient and etc. We also derive an expression, with a multiplier T1-q, of the heat capacity of the nonextensive gas. We can prove that in the quasi-equilibrium system there is 1 - q > 0, 2 so the heat capacity still vanishes if temperature tends to zero, just as that in Boltzmann-Gibbs statistics.

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