Electrospray ionization as a convenient new method for the generation of catalytically active iron-oxide ions in the gas phase

2006 ◽  
Vol 254 (3) ◽  
pp. 197-201 ◽  
Author(s):  
Detlef Schröder ◽  
Jana Roithová ◽  
Helmut Schwarz
Keyword(s):  
Iron Oxide ◽  
Electrospray Ionization ◽  
Gas Phase ◽  
New Method ◽  
Active Iron ◽  
Catalytically Active ◽  
Oxide Ions

Low-temperature (150°C) carbon nanotube growth on a catalytically active iron oxide–graphene nano-structural system

2013 ◽  
Vol 299 ◽  
pp. 307-315 ◽  
Author(s):  
Enkeleda Dervishi ◽  
Alexandru R. Biris ◽  
Joshua A. Driver ◽  
Fumiya Watanabe ◽  
Shawn Bourdo ◽  
...  
Keyword(s):  
Carbon Nanotube ◽  
Iron Oxide ◽  
Low Temperature ◽  
Structural System ◽  
Active Iron ◽  
Catalytically Active ◽  
Carbon Nanotube Growth ◽  
Nanotube Growth

scholarly journals Exploiting the Potential of Biosilica from Rice Husk as Porous Support for Catalytically Active Iron Oxide Nanoparticles

Nanomaterials ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 1259
Author(s):  
Ana Franco ◽  
Rafael Luque ◽  
Carolina Carrillo-Carrión
Keyword(s):  
Iron Oxide ◽  
Iron Oxide Nanoparticles ◽  
Rice Husk ◽  
Heterogeneous Catalysts ◽  
Catalytic Performance ◽  
Added Value ◽  
Oxide Nanoparticles ◽  
Porous Support ◽  
Green Materials ◽  
Catalytically Active

Biomass-derived materials are put forward as eco-friendly alternatives to design heterogeneous catalysts. To contribute in this field, we explored the potential of mesoporous biogenic silica (RH-Silica) obtained from lignocellulosic waste, in particular from rice husk, as an inorganic support to prepare heterogenized iron oxide-based catalysts. Mechanochemistry, considered as a green and sustainable technique, was employed to synthetize iron oxide nanoparticles in pure hematite phase onto the biosilica (α-Fe2O3/RH-Silica), making this material a good candidate to perform catalyzed organic reactions. The obtained material was characterized by different techniques, and its catalytic activity was tested in the selective oxidation of styrene under microwave irradiation. α-Fe2O3/RH-Silica displayed a good catalytic performance, achieving a conversion of 45% under optimized conditions, and more importantly, with a total selectivity to benzaldehyde. Furthermore, a good reusability was achieved without decreasing its activity after multiple catalytic cycles. This work represents a good example of using sustainable approaches and green materials as alternatives to conventional methods in the production of high-added value products.

New method for determination of heats of thermal gas-phase reactions yielding intermediates

1996 ◽  
Vol 45 (1) ◽  
pp. 56-59
Author(s):  
N. N. Buravtsev ◽  
Yu. A. Kolbanovskii ◽  
A. A. Ovsyannikov
Keyword(s):  
Gas Phase ◽  
New Method ◽  
Gas Phase Reactions

Hydrogen Production via the Iron/Iron Oxide Looping Cycle

2011 ◽  
Author(s):  
A. Singh ◽  
F. Al-Raqom ◽  
J. Klausner ◽  
J. Petrasch
Keyword(s):  
Iron Oxide ◽  
Hydrogen Production ◽  
Gas Phase ◽  
Energy Content ◽  
Operation Conditions ◽  
Iron Oxide Reduction ◽  
Temperature Ranges ◽  
Iron Iron ◽  
Gas Phase Separation ◽  
Distinct Temperature

The iron/iron-oxide looping cycle has the potential to produce high purity hydrogen from coal or natural gas without the need for gas phase separation: Hydrogen is produced from steam oxidation of iron or Wustite yielding primarily Magnetite; Magnetite is then reduced back to iron/Wustite using syngas (CO+H2). A system model has been developed to identify favorable operation conditions and process configurations. Process configurations for three distinct temperature ranges, (i) 500–950 K, (ii) 950–1100 K, and (iii) 1100–1200 K have been developed. The energy content of high temperature syngas from conventional coal gasifiers is sufficient to drive the looping process throughout the temperature range considered. Temperatures around 1000 K are advantageous for both the hydrogen production step and the iron oxide reduction step. Simulations of a large number of subsequent cycles indicate that quasi-steady operation is reached after approximately 5 cycles. Comparison of simulations and experiments indicate that the process is currently limited by chemical kinetics at lower temperatures. Therefore, product recirculation should be used for a scaled-up process to increase reactant residence times while maintaining sufficient fluidization velocity.

Sign in / Sign up

Export Citation Format

Share Document