Core shell like behavior of PdMo nanoparticles on multiwall carbon nanotubes and their methanol oxidation activity in alkaline medium

2012 ◽  
Vol 37 (24) ◽  
pp. 19055-19064 ◽  
Author(s):  
N. Kakati ◽  
J. Maiti ◽  
S.H. Lee ◽  
Y.S. Yoon
NANO ◽  
2016 ◽  
Vol 11 (02) ◽  
pp. 1650022 ◽  
Author(s):  
Chunhui Tan ◽  
Juhui Sa ◽  
Feipeng Cai ◽  
Bo Jiang ◽  
Gai Yang ◽  
...  

PtRu nanoparticles (NPs) supported on acid treated multiwall carbon nanotubes (Pt1Ru1/MWCNTs) were prepared by a modified polyol method without adding any other surfactant or protective agent. The structural and compositional properties of the as-obtained samples were characterized by transmission electron microscopy (TEM), energy dispersive X-ray analysis (EDX), X-ray diffraction (XRD) and X-ray photoelectron (XPS) spectroscopy. The electrocatalytic performance of the catalyst was evaluated by cyclic voltammetry (CV), CO stripping voltammetry and chronoamperometry, indicating a high catalytic activity, excellent CO tolerance and stability for methanol oxidation. Interestingly, a series of accurate controllable experiments have been designed to explore the enhancement mechanism of Pt1Ru1/MWCNTs for methanol oxidation reaction. Most importantly, Pt1Ru1/MWCNTs composites were used as an anode catalyst in the direct methanol fuel cells (DMFCs) exhibiting outstanding power density (126.1 mW/cm[Formula: see text] 1.7 times higher than that of the commercial catalyst of Pt1Ru1/C (74.1 mW/cm[Formula: see text] (E-TEK).


Carbon ◽  
2014 ◽  
Vol 77 ◽  
pp. 722-737 ◽  
Author(s):  
Emilio Munoz-Sandoval ◽  
Nestor Perea-Lopez ◽  
Rodolfo Lima-Juarez ◽  
Gladis J. Labrada-Delgado ◽  
Beatriz Adriana Rivera–Escoto ◽  
...  

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