Ultraviolet photolysis of amino acids on the surface of icy Solar System bodies

Icarus ◽  
2012 ◽  
Vol 221 (2) ◽  
pp. 800-805 ◽  
Author(s):  
Paul V. Johnson ◽  
Robert Hodyss ◽  
Victoria F. Chernow ◽  
Dawn M. Lipscomb ◽  
Jay D. Goguen
Keyword(s):  
Amino Acids ◽  
Solar System ◽  
Solar System Bodies ◽  
Ultraviolet Photolysis

Ultraviolet photolysis of amino acids in a 100 K water ice matrix: Application to the outer Solar System bodies

Icarus ◽  
2007 ◽  
Vol 187 (2) ◽  
pp. 584-591 ◽  
Author(s):  
Grazyna E. Orzechowska ◽  
Jay D. Goguen ◽  
Paul V. Johnson ◽  
Alexandre Tsapin ◽  
Isik Kanik
Keyword(s):  
Amino Acids ◽  
Solar System ◽  
Outer Solar System ◽  
Water Ice ◽  
Matrix Application ◽  
Solar System Bodies ◽  
Ultraviolet Photolysis

Homochirality as the Signature of Extra-Terrestrial Life

1997 ◽  
Vol 161 ◽  
pp. 505-510
Author(s):  
Alexandra J. MacDermott ◽  
Laurence D. Barron ◽  
Andrè Brack ◽  
Thomas Buhse ◽  
John R. Cronin ◽  
...  
Keyword(s):  
Amino Acids ◽  
Protein Synthesis ◽  
Optical Rotation ◽  
Physical Origin ◽  
Natural Choice ◽  
Rosetta Mission ◽  
Terrestrial Life ◽  
Subsurface Layers ◽  
Solar System Bodies ◽  
Origin Of Homochirality

AbstractThe most characteristic hallmark of life is its homochirality: all biomolecules are usually of one hand, e.g. on Earth life uses only L-amino acids for protein synthesis and not their D mirror images. We therefore suggest that a search for extra-terrestrial life can be approached as a Search for Extra- Terrestrial Homochirality (SETH). The natural choice for a SETH instrument is optical rotation, and we describe a novel miniaturized space polarimeter, called the SETH Cigar, which could be used to detect optical rotation as the homochiral signature of life on other planets. Moving parts are avoided by replacing the normal rotating polarizer by multiple fixed polarizers at different angles as in the eye of the bee. We believe that homochirality may be found in the subsurface layers on Mars as a relic of extinct life, and on other solar system bodies as a sign of advanced pre-biotic chemistry. We discuss the chiral GC-MS planned for the Roland lander of the Rosetta mission to a comet and conclude with theories of the physical origin of homochirality.

Hydrogen Cyanide Polymers from the Impact of Comet P/Shoemaker-Levy 9 on Jupiter

1997 ◽  
Vol 161 ◽  
pp. 179-187
Author(s):  
Clifford N. Matthews ◽  
Rose A. Pesce-Rodriguez ◽  
Shirley A. Liebman
Keyword(s):  
Amino Acids ◽  
Solar System ◽  
Hydrogen Cyanide ◽  
Nitrogen Heterocycles ◽  
Laboratory Studies ◽  
Heterogeneous Solids ◽  
The Many ◽  
Comet Halley ◽  
The Impact ◽  
By Products

AbstractHydrogen cyanide polymers – heterogeneous solids ranging in color from yellow to orange to brown to black – may be among the organic macromolecules most readily formed within the Solar System. The non-volatile black crust of comet Halley, for example, as well as the extensive orangebrown streaks in the atmosphere of Jupiter, might consist largely of such polymers synthesized from HCN formed by photolysis of methane and ammonia, the color observed depending on the concentration of HCN involved. Laboratory studies of these ubiquitous compounds point to the presence of polyamidine structures synthesized directly from hydrogen cyanide. These would be converted by water to polypeptides which can be further hydrolyzed to α-amino acids. Black polymers and multimers with conjugated ladder structures derived from HCN could also be formed and might well be the source of the many nitrogen heterocycles, adenine included, observed after pyrolysis. The dark brown color arising from the impacts of comet P/Shoemaker-Levy 9 on Jupiter might therefore be mainly caused by the presence of HCN polymers, whether originally present, deposited by the impactor or synthesized directly from HCN. Spectroscopic detection of these predicted macromolecules and their hydrolytic and pyrolytic by-products would strengthen significantly the hypothesis that cyanide polymerization is a preferred pathway for prebiotic and extraterrestrial chemistry.

Spectropolarimetric device for overatmospheric investigations of Solar system bodies

2008 ◽  
Vol 14 (2) ◽  
pp. 56-67
Author(s):  
Ya.S. Yatskiv ◽  
◽  
A.P. Vidmachenko ◽  
O.V. Morozhenko ◽  
M.G. Sosonkin ◽  
...  
Keyword(s):  
Solar System ◽  
Solar System Bodies

scholarly journals Organic matter and water from asteroid Itokawa

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Q. H. S. Chan ◽  
A. Stephant ◽  
I. A. Franchi ◽  
X. Zhao ◽  
R. Brunetto ◽  
...  
Keyword(s):  
Organic Matter ◽  
Solar System ◽  
Parent Body ◽  
Asteroid Belt ◽  
True Nature ◽  
Water Ice ◽  
Nanocrystalline Graphite ◽  
Terrestrial Water ◽  
Solar System Bodies ◽  
Small Dust

AbstractUnderstanding the true nature of extra-terrestrial water and organic matter that were present at the birth of our solar system, and their subsequent evolution, necessitates the study of pristine astromaterials. In this study, we have studied both the water and organic contents from a dust particle recovered from the surface of near-Earth asteroid 25143 Itokawa by the Hayabusa mission, which was the first mission that brought pristine asteroidal materials to Earth’s astromaterial collection. The organic matter is presented as both nanocrystalline graphite and disordered polyaromatic carbon with high D/H and 15N/14N ratios (δD =  + 4868 ± 2288‰; δ15N =  + 344 ± 20‰) signifying an explicit extra-terrestrial origin. The contrasting organic feature (graphitic and disordered) substantiates the rubble-pile asteroid model of Itokawa, and offers support for material mixing in the asteroid belt that occurred in scales from small dust infall to catastrophic impacts of large asteroidal parent bodies. Our analysis of Itokawa water indicates that the asteroid has incorporated D-poor water ice at the abundance on par with inner solar system bodies. The asteroid was metamorphosed and dehydrated on the formerly large asteroid, and was subsequently evolved via late-stage hydration, modified by D-enriched exogenous organics and water derived from a carbonaceous parent body.

scholarly journals Synthesis of Organic Matter in Aqueous Environments Simulating Small Bodies in the Solar System and the Effects of Minerals on Amino Acid Formation

Life ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 32
Author(s):  
Walaa Elmasry ◽  
Yoko Kebukawa ◽  
Kensei Kobayashi
Keyword(s):  
Amino Acids ◽  
Organic Matter ◽  
Amino Acid ◽  
Solar System ◽  
Acid Formation ◽  
Gel Chromatography ◽  
Small Bodies ◽  
Enhanced Production ◽  
Aqueous Environments ◽  
Heating Duration

The extraterrestrial delivery of organics to primitive Earth has been supported by many laboratory and space experiments. Minerals played an important role in the evolution of meteoritic organic matter. In this study, we simulated aqueous alteration in small bodies by using a solution mixture of H2CO and NH3 in the presence of water at 150 °C under different heating durations, which produced amino acids after acid hydrolysis. Moreover, minerals were added to the previous mixture to examine their catalyzing/inhibiting impact on amino acid formation. Without minerals, glycine was the dominant amino acid obtained at 1 d of the heating experiment, while alanine and β-alanine increased significantly and became dominant after 3 to 7 d. Minerals enhanced the yield of amino acids at short heating duration (1 d); however, they induced their decomposition at longer heating duration (7 d). Additionally, montmorillonite enhanced amino acid production at 1 d, while olivine and serpentine enhanced production at 3 d. Molecular weight distribution in the whole of the products obtained by gel chromatography showed that minerals enhanced both decomposition and combination of molecules. Our results indicate that minerals affected the formation of amino acids in aqueous environments in small Solar System bodies and that the amino acids could have different response behaviors according to different minerals.

scholarly journals The Grand Tack model: a critical review

2014 ◽  
Vol 9 (S310) ◽  
pp. 194-203 ◽  
Author(s):  
Sean N. Raymond ◽  
Alessandro Morbidelli
Keyword(s):  
Solar System ◽  
Building Blocks ◽  
Protoplanetary Disk ◽  
Giant Planets ◽  
Asteroid Belt ◽  
Terrestrial Planets ◽  
Saturn’S Satellites ◽  
Internal Inconsistency ◽  
Solar System Bodies ◽  
Gas Accretion

AbstractThe “Grand Tack” model proposes that the inner Solar System was sculpted by the giant planets' orbital migration in the gaseous protoplanetary disk. Jupiter first migrated inward then Jupiter and Saturn migrated back outward together. If Jupiter's turnaround or “tack” point was at ~ 1.5 AU the inner disk of terrestrial building blocks would have been truncated at ~ 1 AU, naturally producing the terrestrial planets' masses and spacing. During the gas giants' migration the asteroid belt is severely depleted but repopulated by distinct planetesimal reservoirs that can be associated with the present-day S and C types. The giant planets' orbits are consistent with the later evolution of the outer Solar System.Here we confront common criticisms of the Grand Tack model. We show that some uncertainties remain regarding the Tack mechanism itself; the most critical unknown is the timing and rate of gas accretion onto Saturn and Jupiter. Current isotopic and compositional measurements of Solar System bodies – including the D/H ratios of Saturn's satellites – do not refute the model. We discuss how alternate models for the formation of the terrestrial planets each suffer from an internal inconsistency and/or place a strong and very specific requirement on the properties of the protoplanetary disk.We conclude that the Grand Tack model remains viable and consistent with our current understanding of planet formation. Nonetheless, we encourage additional tests of the Grand Tack as well as the construction of alternate models.

Power Laws of Topography and Gravity Spectra of the Solar System Bodies

2018 ◽  
Vol 123 (8) ◽  
pp. 2038-2064 ◽  
Author(s):  
A. I. Ermakov ◽  
R. S. Park ◽  
B. G. Bills
Keyword(s):  
Solar System ◽  
Power Laws ◽  
Solar System Bodies
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