scholarly journals Iron-catalyzed indolo[2,3-c]quinoline synthesis from nitroarenes and benzylic alcohols/aldehydes promoted by elemental sulfur

2021 ◽  
Author(s):  
Rong Li ◽  
Shuxin Jiang ◽  
Haolin Zheng ◽  
Hanwen Lei ◽  
Zhi Huang ◽  
...  
Keyword(s):  
Elemental Sulfur ◽  
Benzylic Alcohols

Scanning Electron Microscope Study of Bacteria on Mineral Surfaces

1976 ◽  
Vol 34 ◽  
pp. 130-131
Author(s):  
V.K. Berry
Keyword(s):  
Oxidation Reaction ◽  
Electron Microscope Study ◽  
Elemental Sulfur ◽  
Thiobacillus Ferrooxidans ◽  
Physical Contact ◽  
Metal Sulfides ◽  
Low Grade ◽  
Mineral Surfaces ◽  
Mineral Surface ◽  
Scanning Electron Microscope Study

There are two strains of bacteria viz. Thiobacillus thiooxidansand Thiobacillus ferrooxidanswidely mentioned to play an important role in the leaching process of low-grade ores. Another strain used in this study is a thermophile and is designated Caldariella .These microorganisms are acidophilic chemosynthetic aerobic autotrophs and are capable of oxidizing many metal sulfides and elemental sulfur to sulfates and Fe2+ to Fe3+. The necessity of physical contact or attachment by bacteria to mineral surfaces during oxidation reaction has not been fairly established so far. Temple and Koehler reported that during oxidation of marcasite T. thiooxidanswere found concentrated on mineral surface. Schaeffer, et al. demonstrated that physical contact or attachment is essential for oxidation of sulfur.

A Solvent Free Synthetic Route for Cerium(IV) Metal-Organic Frame-works with UiO-66 Architecture and Their Photocatalytic Application

2019 ◽  
Author(s):  
Matteo Campanelli ◽  
Tiziana Del Giacco ◽  
Filippo De Angelis ◽  
Edoardo Mosconi ◽  
Marco Taddei ◽  
...  
Keyword(s):  
Density Functional ◽  
Chemical Oxidation ◽  
Solvent Free ◽  
Cerium Ammonium Nitrate ◽  
Benzylic Alcohols ◽  
Near Ultraviolet ◽  
Photocatalytic Application ◽  
Activity Density ◽  
Ultraviolet Light Irradiation ◽  
Metal Organic

<div> <p>A novel solvent-free synthesis for Ce-UiO-66 metal-organic frameworks (MOFs) is presented. The MOFs are obtained by simply grinding the reagents, cerium ammonium nitrate (CAN) and the carboxylic linkers, in a mortar for few minutes with the addition of a small amount of acetic acid (AcOH) as modulator (1.75 eq, o.1 ml). The slurry is then transferred into a 1 ml vial and heated at 120°C for 1 day. The MOFs have been characterized for their composition, crystallinity and porosity and employed as heterogenous catalysts for the photo-oxidation reaction of substituted benzylic alcohols to benzaldaldehydes under near ultraviolet light irradiation. The catalytic performances, such as yield, conversion and kinetics, exceed those of similar systems studied by chemical oxidation and using Ce-MOF as catalyst. Moreover, the MOFs were found to be reusable up to three cycles without loss of activity. Density functional theory (DFT) calculations gave an estimation of the band-gap shift due to the different nature of the linkers used and provide useful information on the catalytic activity experimentally observed.</p> </div>

Elemental sulfur in Eddy County, New Mexico

Circular ◽  
1970 ◽  
Author(s):  
Jim S. Hinds ◽  
Richard R. Cunningham
Keyword(s):  
New Mexico ◽  
Elemental Sulfur

Identification of Taste and Odour Compounds from Western Lake Ontario

1984 ◽  
Vol 19 (1) ◽  
pp. 111-118 ◽  
Author(s):  
B.G. Brownlee ◽  
D.S. Painter ◽  
R.J. Boone
Keyword(s):  
Water Supply ◽  
Water Samples ◽  
Elemental Sulfur ◽  
Lake Ontario ◽  
Direct Link ◽  
Municipal Water Supply ◽  
Municipal Water ◽  
Western Lake ◽  
Odour Concentration

Abstract During August, 1983 geosmin was identified in a municipal water supply drawn from western Lake Ontario. The geosmin concentrations were 0.01-0.07 μg L-1, within the range for threshold odour concentration of 0.01-0.2 μg L-1. 2-Methylisoborneol was not detected. The odour 'event' coincided with a dieoff of Cladophora in the lake, but we were not able to establish a direct link between the dieoff and geosmin production. Decomposing Cladophora in shoreline areas produced a strong odour in the air. 3-Methylindole, elemental sulfur, dimethyl tetrasulfide, and dimethyl pentasulfide were tentatively identified in water samples collected from these areas, but geosmin and 2-methylisoborneol were not detected.

scholarly journals Remediation of arsenic-contaminated paddy soil: Effects of elemental sulfur and gypsum fertilizer application

2021 ◽  
Vol 223 ◽  
pp. 112606
Author(s):  
Dengxiao Zhang ◽  
Guanghui Du ◽  
Wenjing Zhang ◽  
Ya Gao ◽  
Hongbin Jie ◽  
...  
Keyword(s):  
Paddy Soil ◽  
Elemental Sulfur ◽  
Fertilizer Application ◽  
Soil Effects ◽  
Contaminated Paddy Soil
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