scholarly journals Petrogeochemical assessment of rock units and identification of alteration/mineralization indicators using portable X-ray fluorescence measurements: Applications to the Fire Tower Zone (W-Mo-Bi) and the North Zone (Sn-Zn-In), Mount Pleasant deposit, New Brunswick, Canada

2017 ◽  
Vol 177 ◽  
pp. 61-72 ◽  
Author(s):  
Wei Zhang ◽  
David R. Lentz ◽  
Brittany E. Charnley
Keyword(s):  
New Brunswick ◽  
X Ray ◽  
The North ◽  
Fluorescence Measurements ◽  
Mount Pleasant

scholarly journals Fluorescent Orthopalladated Complexes of 4-Aryliden-5(4H)-Oxazolones from the Kaede Protein: Synthesis and Characterization

Molecules ◽  
2021 ◽  
Vol 26 (5) ◽  
pp. 1238
Author(s):  
Eduardo Laga ◽  
David Dalmau ◽  
Sofía Arregui ◽  
Olga Crespo ◽  
Ana I. Jimenez ◽  
...  
Keyword(s):  
Intramolecular Interactions ◽  
Ortho Position ◽  
Fluorescent Properties ◽  
Ancillary Ligands ◽  
X Ray ◽  
Mononuclear Complexes ◽  
Fluorescence Measurements ◽  
Anionic Ligands ◽  
Order Of Magnitude

The goal of the work reported here was to amplify the fluorescent properties of 4-aryliden-5(4H)-oxazolones by suppression of the hula-twist non-radiative deactivation pathway. This aim was achieved by simultaneous bonding of a Pd center to the N atom of the heterocycle and the ortho carbon of the arylidene ring. Two different 4-((Z)-arylidene)-2-((E)-styryl)-5(4H)-oxazolones, the structures of which are closely related to the chromophore of the Kaede protein and substituted at the 2- and 4-positions of the arylidene ring (1a OMe; 1b F), were used as starting materials. Oxazolones 1a and 1b were reacted with Pd(OAc)2 to give the corresponding dinuclear orthometalated palladium derivates 2a and 2b by regioselective C–H activation of the ortho-position of the arylidene ring. Reaction of 2a (2b) with LiCl promoted the metathesis of the bridging carboxylate by chloride ligands to afford dinuclear 3a (3b). Mononuclear complexes containing the orthopalladated oxazolone and a variety of ancillary ligands (acetylacetonate (4a, 4b), hydroxyquinolinate (5a), aminoquinoline (6a), bipyridine (7a), phenanthroline (8a)) were prepared from 3a or 3b through metathesis of anionic ligands or substitution of neutral weakly bonded ligands. All species were fully characterized and the X-ray determination of the molecular structure of 7a was carried out. This structure has strongly distorted ligands due to intramolecular interactions. Fluorescence measurements showed an increase in the quantum yield (QY) by up to one order of magnitude on comparing the free oxazolone (QY < 1%) with the palladated oxazolone (QY = 12% for 6a). This fact shows that the coordination of the oxazolone to the palladium efficiently suppresses the hula-twist deactivation pathway.

X-ray computed microtomography for the structural analysis of jewelry from the Museum “Royal Tombs of Sipán”

2020 ◽  
Vol 35 (S1) ◽  
pp. S38-S42
Author(s):  
Soraia Rodrigues de Azeredo ◽  
Roberto Cesareo ◽  
Angel Guillermo Bustamante Dominguez ◽  
Ricardo Tadeu Lopes
Keyword(s):  
Structural Analysis ◽  
High Resolution ◽  
Copper Alloys ◽  
North Coast ◽  
Flat Panel ◽  
X Ray ◽  
The North ◽  
Gold Silver ◽  
Computed Microtomography ◽  
X Ray Computed

Precious ornaments from the Museum Royal Tombs of Sipán were analyzed by X-ray computed microtomography (microCT). The ornaments analyzed were golden earrings produced by the Moche culture that flourished along the north coast of present-day Peru between approximately 100 and 600 AD. Sipán, also known as Huava Rajada, is a mochica archaeological complex in the north of Peru. In particular, the spectacular jewelry, mainly composed of gold, silver, and copper alloys, gilded copper, and tumbaga, from the Museum “Royal Tombs of Sipán,” in Lambayeque, north of Peru, are some of the most sophisticated metalworking ever produced of pre-Columbian America. A portable microCT system consisting of a high-resolution flat panel detector and a mini X-ray tube were used for the structural analysis of these ornaments. The microCT images show parts of the internal structure, highlighting the manufacturing technique and gold sheets joining techniques of the Moche artisans. Furthermore, the advantage of using the portable microCT system for nondestructive testing is clear when the sample cannot be taken to the laboratory.

X-Ray and Optical Data for a Rare Earth–Poor Eudialyte from the North–Central Alaska Range

1990 ◽  
Vol 5 (2) ◽  
pp. 89-92 ◽  
Author(s):  
Neil E. Johnson ◽  
Mickey E. Gunter ◽  
Diana N. Solie ◽  
Charles R. Knowles
Keyword(s):  
Rare Earth ◽  
Powder Diffraction ◽  
Weight Percent ◽  
Optical Data ◽  
Alaska Range ◽  
North Central ◽  
X Ray ◽  
The North ◽  
Cell Dimensions ◽  
Unit Cell Dimensions

AbstractPowder X-ray and optical data have been recorded for a sample of exceptionally rare earth-poor eudialyte (Na12(Ca, REE)6(Fe2+,Mn,Mg)3Zr3(Zr,Nb)x[Si9O27−y(OH)y]2[Si3O9]2(C1,F)z, with x = 0. 1–0.9, y = 1–3 and z = 0.7–1.4) from a pegmatitic vein associated with the peralkaline Windy Fork granite in the north–central Alaska range. The eudialyte is uniaxial positive with ω= 1.6062(2), ε= 1.6138 (3) and microprobe analyses indicate that the sum of REE + Yis less than 0.1 weight percent. Refined unit cell dimensions are: a = 14.2572(4), c = 30.1338(27), Dx= 2.67, F30= 128 (0.006, 42), M20= 76. An indexed powder diffraction pattern is given.

PREDATION BY INSECTS AND SPIDERS INHABITING COLONIAL WEBS OF HYPHANTRIA CUNEA

1972 ◽  
Vol 104 (8) ◽  
pp. 1197-1207 ◽  
Author(s):  
R. F. Morris
Keyword(s):  
Population Dynamics ◽  
Nova Scotia ◽  
North America ◽  
Population Density ◽  
New Brunswick ◽  
Numerical Response ◽  
Initial Number ◽  
Hyphantria Cunea ◽  
The North ◽  
The Mean

AbstractThe number of predators inhabiting nests of Hyphantria cunea Drury was recorded annually for 13 years in four areas in New Brunswick and two areas on the coast of Nova Scotia. The most common groups were the pentatomids and spiders, which sometimes reproduced within the nests, but the mean number per nest was low in relation to the number of H. cunea larvae in the colonies. The rate of predation on fifth-instar larvae was low. Small or timid predators appeared to prey largely on moribund larvae or small saprophagans during the principal defoliating instars of H. cunea.No relationship could be detected between the number of larvae reaching the fifth instar and the number of predators in the colony; nor could any functional or numerical response of the predators to either the initial number of larvae per colony or the population density of colonies be found. It is concluded that the influence of the nest-inhabiting predators is small and relatively stable, and may be treated as a constant in the development of models to explain the population dynamics of H. cunea.H. cunea is a pest in parts of Europe and Asia, where it has been accidentally introduced from North America. The introduction to other continents of the North American predator, Podisus maculiventiis (Say), is discussed briefly.

The endogranitic tin zone, Mount Pleasant, New Brunswick, Canada and its metallogenesis

2004 ◽  
Vol 113 (4) ◽  
pp. 261-288 ◽  
Author(s):  
Carlos M. C. Inverno ◽  
Richard W. Hutchinson
Keyword(s):  
New Brunswick ◽  
Mount Pleasant
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