The influence of soil age and regional climate on clay mineralogy and cation exchange capacity of moist tropical soils: A case study from Late Quaternary chronosequences in Costa Rica

Geoderma ◽  
2017 ◽  
Vol 308 ◽  
pp. 130-148 ◽  
Author(s):  
L.N. Pincus ◽  
P.C. Ryan ◽  
F.J. Huertas ◽  
G.E. Alvarado
Keyword(s):  
Costa Rica ◽  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Late Quaternary ◽  
Regional Climate ◽  
Clay Mineralogy ◽  
Tropical Soils ◽  
Exchange Capacity ◽  
Soil Age

scholarly journals Exchange Characteristics of Lead, Zinc, and Cadmium in Selected Tropical Soils

2014 ◽  
Vol 2014 ◽  
pp. 1-7
Author(s):  
Tope O. Bolanle-Ojo ◽  
Abiodun D. Joshua ◽  
Opeyemi A. Agbo-Adediran ◽  
Ademola S. Ogundana ◽  
Kayode A. Aiyeyika ◽  
...  
Keyword(s):  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Tropical Soils ◽  
Exchange Capacity ◽  
Exchange Reactions ◽  
Soil System ◽  
Soil Systems ◽  
Wide Range ◽  
Lead Zinc ◽  
High Base

Conducting binary-exchange experiments is a common way to identify cationic preferences of exchangeable phases in soil. Cation exchange reactions and thermodynamic studies of Pb2+/Ca2+, Cd2+/Ca2+, and Zn2+/Ca2+were carried out on three surface (0–30 cm) soil samples from Adamawa and Niger States in Nigeria using the batch method. The physicochemical properties studies of the soils showed that the soils have neutral pH values, low organic matter contents, low exchangeable bases, and low effective cation exchange capacity (mean: 3.27 cmolc kg−1) but relatively high base saturations (≫50%) with an average of 75.9%. The amount of cations sorbed in all cases did not exceed the soils cation exchange capacity (CEC) values, except for Pb sorption in the entisol-AD2 and alfisol-AD3, where the CEC were exceeded at high Pb loading. Calculated selectivity coefficients were greater than unity across a wide range of exchanger phase composition, indicating a preference for these cations over Ca2+. TheKeqvalues obtained in this work were all positive, indicating that the exchange reactions were favoured and equally feasible. These values indicated that the Ca/soil systems were readily converted to the cation/soil system. The thermodynamic parameters calculated for the exchange of these cations were generally low, but values suggest spontaneous reactions.

scholarly journals Cation exchange capacity of an oxisol amended with an effluent from domestic sewage treatment

2005 ◽  
Vol 62 (6) ◽  
pp. 552-558 ◽  
Author(s):  
Adriel Ferreira da Fonseca ◽  
Luís Reynaldo Ferracciú Alleoni ◽  
Adolpho José Melfi ◽  
Célia Regina Montes
Keyword(s):  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Sewage Treatment ◽  
Barium Chloride ◽  
Dry Weight ◽  
Tropical Soils ◽  
Exchange Capacity ◽  
Strong Positive Correlation ◽  
Ionic Force ◽  
Barium Chloride Solution

The addition of Na-rich anthropogenic residues to tropical soils has stimulated the scientific community to study the role of sodium in both the soil solution and the exchange complex. In this study, several different methods were used to calculate the concentration of exchangeable and soluble cations and this data was then used to establish correlations between the level of these cations and both the accumulation of various elements and the dry weight of maize grown in a greenhouse under different conditions. In the closed environments of the pots, the most suitable method for calculating the effective cation exchange capacity (ECEC) was the cation exchange capacity calculated by cations removed with barium chloride solution (CEC S). Then again, the actual cation exchange capacity (CEC A) should be measured by using Mg adsorption to prevent ionic force from influencing electric charges. A strong positive correlation was obtained between the concentrations of Na in the 1:2 soil:water extracts and the accumulation of Na in the maize plants, indicating saline or double acid extractors are not needed when monitoring the Na concentration only.

Clay mineralogy and cation exchange capacity of Brazilian soils from water contents determined by thermal analysis

2004 ◽  
Vol 413 (1-2) ◽  
pp. 73-79 ◽  
Author(s):  
Antonio Carlos S Costa ◽  
Jerry M Bigham ◽  
Cássio A Tormena ◽  
José Carlos Pintro
Keyword(s):  
Thermal Analysis ◽  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Clay Mineralogy ◽  
Exchange Capacity ◽  
Brazilian Soils ◽  
Water Contents

scholarly journals Short communication: Predicting cation exchange capacity from hygroscopic moisture in agricultural soils of Western Europe

2015 ◽  
Vol 13 (4) ◽  
pp. e11SC01 ◽  
Author(s):  
José Torrent ◽  
María C. Del Campillo ◽  
Vidal Barrón
Keyword(s):  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Western Europe ◽  
Agricultural Soils ◽  
Clay Mineralogy ◽  
Exchange Capacity ◽  
Carbonate Content ◽  
Moisture Regime ◽  
Organic Carbon Content ◽  
Hygroscopic Moisture

<p>Soil cation exchange capacity (CEC) depends on the extent and negative charge density of surfaces of soil mineral and organic components. Soil water sorption also depends on the extent of such surfaces, giving thus way to significant relationships between CEC and hygroscopic moisture (HM) in many soils. In this work, we explored whether CEC could be accurately predicted from HM in agricultural soils of Mediterranean and humid temperate areas in Western Europe. For this purpose, we examined 243 soils across a wide variation range of their intrinsic properties. Soil CEC was determined using 1 M ammonium acetate at pH 7 and HM at an equilibrium air relative humidity (RH) of 43% (HM<sub>43</sub>). Most of the variation of soil CEC was explained by HM<sub>43</sub> through a linear function (CEC = 1.4 + 0.78HM<sub>43</sub>; <em>R</em><sup>2</sup> = 0.962; standard deviation = 2.30 cmol<sub>c</sub>/kg). Coefficients of the regression equation were similar for subgroups of soils differing in moisture regime, clay mineralogy, carbonate content and organic carbon content. Therefore, soil hygroscopic moisture measurements at a fixed RH level provided a simple, robust, inexpensive method for predicting soil CEC.</p>

scholarly journals Contribution of the chemical and mineralogical properties of sandy-loam tropical soils to the cation exchange capacity

2020 ◽  
Vol 44 ◽  
Author(s):  
Antonio Carlos Saraiva da Costa ◽  
Ivan Granemann de Souza ◽  
Leila Cristina Canton ◽  
Luciano Grillo Gil ◽  
Rodolfo Figueiredo
Keyword(s):  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Sandy Loam ◽  
Tropical Soils ◽  
Exchange Capacity ◽  
Mineralogical Properties

scholarly journals Evaluation of the lime requirement of tropical soils in terms of other soil characteristics

1969 ◽  
Vol 36 (2) ◽  
pp. 155-160
Author(s):  
M. A. Lugo López ◽  
F. Abruña ◽  
J. Roldán
Keyword(s):  
Cation Exchange ◽  
Clay Mineral ◽  
Cation Exchange Capacity ◽  
Ph Value ◽  
Organic Matter Content ◽  
Clay Content ◽  
Tropical Soils ◽  
Exchange Capacity ◽  
Matter Content ◽  
Significant Regression

The quantity of limestone required to bring the pH of various acid Puerto Rican soils to 6.5 was investigated and found to vary from several hundred to several thousands pounds per acre. To investigate the relation of clay-mineral type, clay content, cation-exchange capacity, organic-matter content, and pH to lime requirement, these properties were determined for several soils. A highly significant regression of lime requirement on pH was obtained which can be expressed by the equation: Y = 18.39 — 3.196 X, where Y is the lime requirement and X is the pH value. Multiple regressions including other factors did not significantly increase the variability which could be explained on terms of the first regression. Further analysis were made by arranging the data according to the predominant clay mineral. For kaolinitic soils highly significant correlations were obtained between lime requirement and either pH or cation exchange capacity. The regressions were: (a) Y = 15.26 — 2.632 pH, and (b) Y = 3.048 + 0.5774 (cation-exchange capacity), where Y is the lime requirement. A regression of lime requirement on both factors did not significantly increase the variability explained by the second equation. No significant regressions were obtained for beidellitic soils.

Sign in / Sign up

Export Citation Format

Share Document