scholarly journals Ionic liquids/deep eutectic solvents for CO2 capture: Reviewing and evaluating

Author(s):  
Yanrong Liu ◽  
Zhengxing Dai ◽  
Zhibo Zhang ◽  
Shaojuan Zeng ◽  
Fangfang Li ◽  
...  
2022 ◽  
Author(s):  
Ze Wang ◽  
Zonghua Wang ◽  
Huang Xin ◽  
Dezhong Yang ◽  
Congyi Wu ◽  
...  

Deep eutectic solvents (DESs) formed by bio-phenol-derived superbase ionic liquids (ILs) and ethylene glycol (EG) perform a high CO2 capacity, up to 1.0 mol CO2/ mol DESs, which is much...


Crystals ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 978
Author(s):  
Yanrong Liu ◽  
Zhengxing Dai ◽  
Fei Dai ◽  
Xiaoyan Ji

The CO2 solubilities (including CO2 Henry’s constants) and viscosities in ionic liquids (ILs)/deep eutectic solvents (DESs)-based hybrid solvents were comprehensively collected and summarized. The literature survey results of CO2 solubility illustrated that the addition of hybrid solvents to ILs/DESs can significantly enhance the CO2 solubility, and some of the ILs-based hybrid solvents are super to DESs-based hybrid solvents. The best hybrid solvents of IL–H2O, IL–organic, IL–amine, DES–H2O, and DES–organic are [DMAPAH][Formate] (2.5:1) + H2O (20 wt %) (4.61 mol/kg, 298 K, 0.1 MPa), [P4444][Pro] + PEG400 (70 wt %) (1.61 mol/kg, 333.15 K, 1.68 MPa), [DMAPAH][Formate] (2.0:1) + MEA (30 wt %) (6.24 mol/kg, 298 K, 0.1 MPa), [TEMA][Cl]-GLY-H2O 1:2:0.11 (0.66 mol/kg, 298 K, 1.74 MPa), and [Ch][Cl]-MEA 1:2 + DBN 1:1 (5.11 mol/kg, 298 K, 0.1 MPa), respectively. All of these best candidates show higher CO2 solubility than their used pure ILs or DESs, evidencing that IL/DES-based hybrid solvents are remarkable for CO2 capture. For the summarized viscosity results, the presence of hybrid solvents in ILs and DESs can decrease their viscosities. The lowest viscosities acquired in this work for IL–H2O, IL–amine, DES–H2O, and DES–organic hybrid solvents are [DEA][Bu] + H2O (98.78 mol%) (0.59 mPa·s, 343.15 K), [BMIM][BF4] + DETA (94.9 mol%) (2.68 mPa·s, 333.15 K), [L-Arg]-GLY 1:6 + H2O (60 wt %) (2.7 mPa·s, 353.15 K), and [MTPP][Br]-LEV-Ac 1:3:0.03 (16.16 mPa·s, 333.15 K) at 0.1 MPa, respectively.


2016 ◽  
Vol 13 (1) ◽  
pp. 53
Author(s):  
Siti Nabihah Jamaludin ◽  
Ruzitah Mohd Salleh

Anthropogenic CO2 emissions has led to global climate change and widely contributed to global warming since its concentration has been increasing over time. It has attracted vast attention worldwide. Currently, the different CO2 capture technologies available include absorption, solid adsorption and membrane separation. Chemical absorption technology is regarded as the most mature technology and is commercially used in the industry. However, the key challenge is to find the most efficient solvent in capturing CO2. This paper reviews several types of CO2 capture technologies and the various factors influencing the CO2 absorption process, resulting in the development of a novel solvent for CO2 capture.


Author(s):  
Tao Zhang ◽  
Thomas Doert ◽  
Hui Wang ◽  
Suojiang Zhang ◽  
Michael Ruck

RSC Advances ◽  
2021 ◽  
Vol 11 (20) ◽  
pp. 12398-12422
Author(s):  
Amir Sada Khan ◽  
Taleb H. Ibrahim ◽  
Nabil Abdel Jabbar ◽  
Mustafa I. Khamis ◽  
Paul Nancarrow ◽  
...  

Extraction of phenol from aqueous phase to ionic liquid phase.


Chemosphere ◽  
2021 ◽  
Vol 277 ◽  
pp. 130227
Author(s):  
Ana M.O. Azevedo ◽  
André G. Vilaranda ◽  
Ana F.D.C. Neves ◽  
Maria João Sousa ◽  
João L.M. Santos ◽  
...  

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