Evolution of organo-clay composites with respect to thermal maturity in type II organic-rich source rocks

2016 ◽  
Vol 195 ◽  
pp. 68-83 ◽  
Author(s):  
Jeremie Berthonneau ◽  
Olivier Grauby ◽  
Muhannad Abuhaikal ◽  
Roland J.-M. Pellenq ◽  
Franz J. Ulm ◽  
...  
Keyword(s):  
Rich Source ◽  
Source Rocks ◽  
Type Ii ◽  
Thermal Maturity ◽  
Organo Clay

Liquid hydrocarbon characterization of the lacustrine Yanchang Formation, Ordos Basin, China: Organic-matter source variation and thermal maturity

2017 ◽  
Vol 5 (2) ◽  
pp. SF225-SF242 ◽  
Author(s):  
Xun Sun ◽  
Quansheng Liang ◽  
Chengfu Jiang ◽  
Daniel Enriquez ◽  
Tongwei Zhang ◽  
...  
Keyword(s):  
Organic Matter ◽  
Source Rock ◽  
Ordos Basin ◽  
Depositional Environments ◽  
Source Rocks ◽  
Type I ◽  
Hydrocarbon Generation ◽  
Type Ii ◽  
Thermal Maturity ◽  
Yanchang Formation

Source-rock samples from the Upper Triassic Yanchang Formation in the Ordos Basin of China were geochemically characterized to determine variations in depositional environments, organic-matter (OM) source, and thermal maturity. Total organic carbon (TOC) content varies from 4 wt% to 10 wt% in the Chang 7, Chang 8, and Chang 9 members — the three OM-rich shale intervals. The Chang 7 has the highest TOC and hydrogen index values, and it is considered the best source rock in the formation. Geochemical evidence indicates that the main sources of OM in the Yanchang Formation are freshwater lacustrine phytoplanktons, aquatic macrophytes, aquatic organisms, and land plants deposited under a weakly reducing to suboxic depositional environment. The elevated [Formula: see text] sterane concentration and depleted [Formula: see text] values of OM in the middle of the Chang 7 may indicate the presence of freshwater cyanobacteria blooms that corresponds to a period of maximum lake expansion. The OM deposited in deeper parts of the lake is dominated by oil-prone type I or type II kerogen or a mixture of both. The OM deposited in shallower settings is characterized by increased terrestrial input with a mixture of types II and III kerogen. These source rocks are in the oil window, with maturity increasing with burial depth. The measured solid-bitumen reflectance and calculated vitrinite reflectance from the temperature at maximum release of hydrocarbons occurs during Rock-Eval pyrolysis ([Formula: see text]) and the methylphenanthrene index (MPI-1) chemical maturity parameters range from 0.8 to [Formula: see text]. Because the thermal labilities of OM are associated with the kerogen type, the required thermal stress for oil generation from types I and II mixed kerogen has a higher and narrower range of temperature for hydrocarbon generation than that of OM dominated by type II kerogen or types II and III mixed kerogen deposited in the prodelta and delta front.

Prospect Evaluation Based on Integrated Petroleum System Analysis: Block E Case Study, South-Eastern Edge of Precaspian Basin Kazakhstan

2021 ◽  
Author(s):  
Ainura Zhanserkeyeva ◽  
Akzhan Kassenov
Keyword(s):  
Vertical Migration ◽  
Oil And Gas ◽  
Source Rocks ◽  
Late Triassic ◽  
Lower Permian ◽  
Type Ii ◽  
Thermal Maturity ◽  
Type Iii ◽  
South Eastern ◽  
Oil Generation

Abstract Positive geological and geochemical prerequisites have been identified for the purpose of increasing hydrocarbon resource potential in the under-explored study area. A methodology has been developed for assessing the hydrocarbon potential and prospecting for new promising oil and gas accumulation zones using the technology of basin modeling, provided there is a lack of initial data. A high hydrocarbon source rock generative potential and the degree of thermal maturity of the Lower Permian, Mid Carboniferous and Upper Devonian strata of the south-eastern part of the Precaspian depression have been revealed. Seismostratigraphic and geodynamic analysis was carried out and the main stages of the geodynamic evolution of the study area were reconstructed based on combination of all available geological and geophysical information, recent exploration drilling results and unpublished subsurface studies. The results of thermotectonic modelling confirm the possibility of vertical migration of hydrocarbons generated in Paleozoic sediments. A revision of the previously performed interpretation of 3D seismic data has been carried out; and for the first time, intrasalt sedimentary packets of presumably Upper Permian age have been identified as independent objects, which can be potential hydrocarbon traps. For the Lower Permian deposits, type III kerogen predominates, which may be associated with an increase in collisional processes in the Late Paleozoic time and an active input of plant organic matter. For Mid Carboniferous sediments, mixed type II / III kerogen or type II kerogen prevails. Analysis of the evolution of thermal maturity indicates the unevenness of the entry of potential oil and gas source strata into the main zone of oil generation. For kerogen type III of the Lower Permian source rocks, the peak of oil generation falls on the Late Cretaceous. For predominantly carbonate and terrigenous-carbonate Middle Carboniferous source rocks the peak of generation falls on the Jurassic. The most submerged Devonian source rocks are located mainly in the zone of wet gas generation. The development of salt tectonics from the Late Triassic to the Cenozoic contributed to the vertical migration of hydrocarbons into the post-salt complex. The identified oil fields in the Upper Triassic-Jurassic stratigraphic section are mainly confined to the four-way dip structural closured above the steep flanks of salt structures.

scholarly journals Integration of methyldibenzothiophene and pyrolysis techniques to determine thermal maturity in sulfur-rich Type II-S source rocks and oils

2021 ◽  
pp. 104333
Author(s):  
Poorna Srinivasan ◽  
David Jacobi ◽  
Ibrahim Atwah ◽  
Harald Karg ◽  
Abdulhameed Azzouni
Keyword(s):  
Source Rocks ◽  
Type Ii ◽  
Thermal Maturity

scholarly journals Using aromatic biological markers as a tool for assessing thermal maturity of source rocks in the Campano-Maastrichtian Mamu Formation, southeastern Nigeria

2014 ◽  
Vol 18 (1) ◽  
pp. 51-62 ◽  
Author(s):  
Jude E. Ogala ◽  
Mike I. Akaegbobi
Keyword(s):  
Organic Matter ◽  
Aromatic Hydrocarbons ◽  
Mixed Type ◽  
Higher Plants ◽  
Vitrinite Reflectance ◽  
Source Rocks ◽  
Hydrocarbon Generation ◽  
Type Ii ◽  
Thermal Maturity ◽  
Southeastern Nigeria

<p>The concentration and distribution of aromatic biomarkers in coals and shales from five boreholes penetrating the Maastrichtian Mamu Formation of the Anambra Basin, southeastern Nigeria, were investigated by gas chromatography-mass spectrometryto assess the thermal maturity and organic matter input. The study focused on the variations of the relative abundances of naphthalenes, phenanthrenes, and monaromatic and triaromatic steroids identified on the mass fragmentograms. Trimethylnaphthalene(TMN) is the most abundant member of the naphthalene family while methylphenanthrene (MP) is the most abundant phenanthrene family member. The total of phenanthrenes and their isomers was greater than that of naphthalenes. The distribution of these aromatic hydrocarbons and their akyl derivatives was strongly controlled by a selective expulsion mechanism and thermal maturation of organic matter. The low dibenzothiophene/phenanthrene (DBT/PHEN) ratios (0.01-0.06), as well as the enhanced concentrations of 1,2,5-TMN relative to 1,2,7- TMN,indicates organic matter derived mainly from higher plants,and the extract ternary plot of C<sub>27</sub>, C<sub>28</sub> and C<sub>29</sub> monoaromatic steroids suggests a Type III and mixed Type II/III kerogen. The calculated mean vitrinite reflectance (%R<sub>m</sub>), determined from the distributions of the isomers of methyldibenzothiophene ratio (MDR) in the rock extracts, ranged from 0.51 to 1.43. These maturity values indicate that the coal and shale extracts are marginally mature for hydrocarbon generation.</p><p> </p><p><strong>Resumen</strong></p><p>La concentración y distribución de biomarcadores aromáticos en carbones y esquistos de cinco perforaciones en la formación Maastrichtian Mamu de la cuenca de Anambra, en el sureste de Nigeria, fueron analizados a través de un estudio de espectometría cromatográfico y de masa del gas para medir la madurez termal y la entrada de material orgánico. El estudio está enfocado en las variaciones de la abundancia relativa de naftalinas y fenantrenos, y en los esteroides monoaromáticos y triaromáticos identificados en los fragmentogramas de masas. La trimetinaftalina (TMN) es la más abundante de la familia de las naftalinas mientras el metilfenantreno (MP) es el más abundante de los fenantrenos. El tota de los fenantrenos y sus isómeros fue mayor que el de las naftalinas. La distribución de estos hidrocarbones aromáticos y sus alquilos derivados fue controlada ampliamente por un mecanismo de expulsión selectiva y de la maduración térmica de material orgánico. La baja proporción dibenziotofeno/fenantreno (DBT/ PHEN) (0.01-0.06), al igual que las concentraciones mejoradas de 1,2,5-TMN relativas de 1,2,7-TMN indican que la materia orgánica se deriva principalmente de plantas mayores, y del diagrama terniario de los esteroides monoaromáticos C<sub>27</sub>, C<sub>28</sub> y C<sub>29</sub> sugiere un tipo III mezclado con tipos II/III de querógenos. El valor calculado de la reflectancia de vitrinita (%Rm) determinado de la proporción de isómeros de metildibenziotofeno (MDR) en los extractos rocosos oscila de 0.51 a 1.43. Estos valores de madurez indican que los extractos de carbones y esquistos son marginalmente maduros para la generación de hidrocarbono.</p><p> </p>

scholarly journals Organic Geochemistry and Thermal Maturity Assessment of Cretaceous Balambo Formation from Selected Sites, Kurdistan, NE Iraq

2021 ◽  
pp. 532-554
Author(s):  
Razawa Hamarashid A. Sarraj ◽  
Ibrahim Mohammed J. Mohialdeen
Keyword(s):  
Organic Matter ◽  
Organic Geochemistry ◽  
Source Rocks ◽  
Gas Chromatography Mass Spectrometry ◽  
Distribution Analysis ◽  
Type Ii ◽  
Thermal Maturity ◽  
Peak Oil ◽  
Northern Iraq ◽  
Marine Organic Matter

The Cretaceous Balambo Formation from three sections in Kurdistan Region of Northern Iraq was studied. The selected sections are located in the Zagros Fold -Thrust Belt. Eleven rock samples were analyzed by means of the organic geochemical method, Bitumen extraction method, and gas chromatography/mass spectrometry to determine the bitumen and hydrocarbon content, kerogen types, origin of organic matter, thermal maturity level, and depositional environment. The analyzed samples are considered to have an excellent potential in Baranan-1.G1 and Sazan sections, with poor to fair potential in Baraw section. The Baranan-1.G1 source rocks are of type II kerogen (oil prone), whereas Sazan and Baraw samples are of type II/III (oil/ gas prone). Detailed distribution analysis of biomarkers such as normal alkane, isoprenoids, sterane and terpane was performed on saturated hydrocarbons. The mode of n-alkanes and isoprenoids distribution in all analyzed samples is similar, with a unimodal distribution that indicates non-biodegraded hydrocarbons, with the same range of alkane compounds between C13-C34 alkanes. The results of n-C17, pristane, n-C18 and phytane, and regular steranes show that the source rocks of Balambo Formation in Baranan-1.G1 are mainly rich with algal marine organic matter deposited under a reducing environment, while Baraw and Sazan sections are composed of mixed marine organic matter that refers to terrestrial land plants input deposited under reducing anoxic/dysoxic environments. Thermal maturation appraisal is deduced from Pristane/n-C17 versus Phytane/n-C18 diagram, Carbon Preference Index (CPI), C29 ββ/ (ββ+αα), C29 20S/ (20S +20R), C32 22S/ (22S+22R), and Ts/ (Ts+Tm). All these parameters indicate that the analyzed samples are mature and have entered the oil window (early to peak oil window). Biomarker ratios of C22/C21, C24/C23 and C26/C25, C31R/C30H show that the Balambo Formation is composed mostly of carbonates with less shale beds.

Oxidation Tmax: A new thermal maturity indicator for hydrocarbon source rocks

2017 ◽  
Vol 113 ◽  
pp. 254-261 ◽  
Author(s):  
Sedat İnan ◽  
Sebastian Henderson ◽  
Salman Qathami
Keyword(s):  
Source Rocks ◽  
Thermal Maturity ◽  
Hydrocarbon Source Rocks

Rock-physics analysis of clay-rich source rocks on the Norwegian Shelf

2015 ◽  
Vol 34 (11) ◽  
pp. 1340-1348 ◽  
Author(s):  
Per Avseth ◽  
José M. Carcione
Keyword(s):  
Rock Physics ◽  
Rich Source ◽  
Source Rocks

Comparisons of pyrolysis parameters between source rocks and their clay-sized fractions: Implication for source material of hydrocarbon generation

2022 ◽  
pp. 1-42
Author(s):  
Xiaojun Zhu ◽  
Jingong Cai ◽  
Feng Liu ◽  
Qisheng Zhou ◽  
Yue Zhao ◽  
...  
Keyword(s):  
Organic Carbon ◽  
Source Material ◽  
Source Rocks ◽  
Natural Environments ◽  
Hydrocarbon Generation ◽  
Petroleum Systems ◽  
Organic Mineral ◽  
Organic Clay ◽  
Organo Clay ◽  
Rock Eval

In natural environments, organic-clay interactions are strong and cause organo-clay composites (a combination between organic matter [OM] and clay minerals) to be one of the predominant forms for OM occurrence, and their interactions greatly influence the hydrocarbon (HC) generation of OM within source rocks. However, despite occurring in nature, dominating the OM occurrence, and having unique HC generation ways, organo-clay composites have rarely been investigated as stand-alone petroleum precursors. To improve this understanding, we have compared the Rock-Eval pyrolysis parameters derived from more than 100 source rocks and their corresponding <2 μm clay-sized fractions (representing organo-clay composites). The results show that all of the Rock-Eval pyrolysis parameters in bulk rocks are closely positively correlated with those in their clay-sized fractions, but in clay-sized fractions the quality of OM for HC generation is poorer, in that the pyrolysable organic carbon levels and hydrogen index values are lower, whereas the residual organic carbon levels are higher than those in bulk rocks. Being integrated with the effects of organic-clay interactions on OM occurrence and HC generation, our results suggest that organo-clay composites are stand-alone petroleum precursors for HC generation occurring in source rocks, even if the source rocks exist in great varieties in their attributes. Our source material for HC generation comprehensively integrates the original OM occurrence and HC generation behavior in natural environments, which differs from kerogen and is much closer to the actual source material of HC generation in source rocks, and it calls for further focus on organic-mineral interactions in studies of petroleum systems.

STABLE HYDROGEN ISOTOPE RATIOS OF SEDIMENTARY HYDROCARBONS: A POTENTIAL METHOD FOR ASSESSING THERMAL MATURITY?

2005 ◽  
Vol 45 (1) ◽  
pp. 253
Author(s):  
D. Dawson ◽  
K. Grice ◽  
R. Alexander
Keyword(s):  
Vitrinite Reflectance ◽  
Potential Method ◽  
Source Rocks ◽  
Crude Oils ◽  
Thermal Maturity ◽  
Peak Oil ◽  
Data Set ◽  
High Maturity ◽  
The Difference ◽  
Hydrogen Isotope Ratios

A relationship has been identified between the maturity level of source rocks and the stable hydrogen isotopic compositions (δD) of extracted saturated hydrocarbons, based on the analysis of nine sediments and five crude oils from the Perth Basin (WA). The sediments cover the immature to late mature range. Distinct δD signatures are observed for the immature sediments where pristane and phytane are significantly depleted in deuterium (D) relative to the n-alkanes. With increasing maturity the difference between the δD values of n-alkanes and isoprenoids reduces as pristane and phytane become progressively enriched in D. The n-alkane–isoprenoid δD signature of the crude oils, including one from a different source facies, is similar to mature–late mature sediments representative of the peak oil–generative window. Enrichment of D in isoprenoids is attributed to isotopic exchange associated with thermal maturation. Average δD values of pristane and phytane correlate well with vitrinite reflectance, as does the biomarker maturity parameter Ts/Tm. The limited data set suggests that δD values of aliphatic hydrocarbons may be useful for establishing thermal maturity, particularly when other maturity parameters are not appropriate. Furthermore, we suggest δD values may be useful over a wider maturity range than traditional parameters, particularly at very high maturity where biomarker parameters are no longer effective.

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