Ce(III) and Ce(IV) (re)distribution and fractionation in a laterite profile from Madagascar: Insights from in situ XANES spectroscopy at the Ce LIII-edge

2015 ◽  
Vol 153 ◽  
pp. 134-148 ◽  
Author(s):  
Emilie Janots ◽  
Felix Bernier ◽  
Fabrice Brunet ◽  
Manuel Muñoz ◽  
Nicolas Trcera ◽  
...  
2007 ◽  
Vol 92 (1) ◽  
pp. 44-56 ◽  
Author(s):  
M. Wilke ◽  
F. Farges ◽  
G. M. Partzsch ◽  
C. Schmidt ◽  
H. Behrens

2012 ◽  
Vol 537 ◽  
pp. 80-83 ◽  
Author(s):  
Wolff-Ragnar Kiebach ◽  
Christodoulos Chatzichristodoulou ◽  
Rebecka M. Larsen Werchmeister ◽  
Anke Hagen

2010 ◽  
Vol 132 (4) ◽  
pp. 1296-1301 ◽  
Author(s):  
Jörg Polte ◽  
T. Torsten Ahner ◽  
Friedmar Delissen ◽  
Sergey Sokolov ◽  
Franziska Emmerling ◽  
...  

2012 ◽  
Vol 1383 ◽  
Author(s):  
Hao Yan ◽  
Robert A. Mayanovic ◽  
Joseph Demster ◽  
Alan J. Anderson

ABSTRACTIn situ x-ray absorption spectroscopy (XAS) measurements were made on Fe3O4 nanoparticles in supercritical aqueous fluids to 500 °C in order to study their reactivity with Co2+ aqua ions and to investigate the structural properties of the reacted nanoparticles. The analyses of the x-ray absorption near edge structure (XANES) of XAS indicate that reactivity of Fe3O4 nanoparticles with Co2+ ions is minimal to 200 °C but becomes significant in the 250–500 °C temperature range. XANES and angular momentum projected density of states (l-DOS) calculations were carried out using the FEFF8.2 code and analyses were made using multi-peak fitting to determine the origin of the features exhibited in the spectra.


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