A method to estimate the thermal conductivity of organic alcohols in the liquid phase at atmospheric pressure or along the saturation line

2016 ◽  
Vol 427 ◽  
pp. 488-497 ◽  
Author(s):  
Giovanni Latini ◽  
Giovanni Di Nicola ◽  
Mariano Pierantozzi
2021 ◽  
Vol 65 (2-4) ◽  
pp. 212-217
Author(s):  
Giovanni Latini ◽  
Giorgio Passerini

The thermal conductivity λ of the silanes and siloxanes families in the liquid phase at atmospheric pressure or along the saturation line is investigated as function of the reduced temperature. Because of the large scarcity or even of the lack of accurate experimental λ data an empirical equation is proposed as a generalization based on investigations presented in previous works [1, 2]. The families of silanes and siloxanes (21 chlorosilanes, 5 cyclosiloxanes, 10 linear siloxanes, 10 silanes and 19 other silanes) are taken into consideration using a large database [3] in order to extend the use of a general formula valid for organic compounds (alcohols, alkanes, ketones,….) and to improve preceeding results obtained in the case of the cited silanes and siloxanes, for which experimental thermal conductivity data at atmospheric pressure or along the saturation line in the liquid phase are available in very few cases. The equation is proposed as acceptable for engineering purposes and comparable with the existing prediction methods [3]. The database DIPPR [3] in the version 2020 containing a linear correlation with various parameters is taken into account, also considering the results of 7 other prediction methods existing in the technical and scientific literature. An extensive and critical comparison points out that the method proposed in this work can be considered valid with absolute errors usually not greater than 5%.


1988 ◽  
Vol 110 (4a) ◽  
pp. 992-995 ◽  
Author(s):  
A. A. Clifford ◽  
R. Tufeu

The thermal conductivity of gaseous and liquid ammonia has been measured in the range 300–300 K and at pressures up to 50 MPa. The measurements were a necessary preliminary to a fitting of the thermal conductivity surface in the density–temperature plane, which is part of the current program of the Transport Properties Subcommittee of the I.U.P.A.C. Results were obtained that are believed to be accurate to 2 percent. It is difficult to make a good comparison of these results with previous data until a full correlation of the thermal conductivity of ammonia is carried out. A preliminary assessment for the liquid phase indicates that agreement is reasonable over much of the range with differences up to around 5 percent under certain conditions. For the gas phase an approximate extrapolation to atmospheric pressure can be made and the results compared with some recent recommended values. Differences of ±3 percent are observed.


2013 ◽  
Vol 860-863 ◽  
pp. 590-593
Author(s):  
Cha Xiu Guo ◽  
Ding Bao Wang ◽  
Gao Lin Hu

High conductivity porosity materials are proposed to enhance the phase change materials (PCM) in order to solve the problem of low conductivity of PCM in the latent heat storage device (LHSD), and two-dimensional numerical simulation is conducted to predict the performance of the PCM by CFD software. During the phase change process, the PCM is heated from the solid state to the liquid phase in the process of melting and from the liquid phase to the solid state in the solidification process. The results show that porosity materials can improve heat transfer rate effectively, but the effect of heat transfer of Al foam is superior to that of graphite foam although the heat storage capacity is almost the same for both. The heat transfer is enhanced and the solidification time of PCM is decreased since the effective thermal conductivity of composite PCM is increased.


1957 ◽  
Vol 24 (1) ◽  
pp. 25-28
Author(s):  
E. R. G. Eckert ◽  
T. F. Irvine

Abstract A new method is described by which the Prandtl number and indirectly the thermal conductivity of fluids can be measured. The method is based on the fact that a well-established, unique relation exists between the Prandtl number and the recovery factor for laminar high-velocity boundary-layer flow. The test setup is described which has been devised for such measurements, and test results are presented for air at atmospheric pressure and temperatures between 60 and 350 F.


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