Prediction of ionic liquids phase equilibrium with the COSMO-RS model

2016 ◽  
Vol 424 ◽  
pp. 16-31 ◽  
Author(s):  
Michał Wlazło ◽  
Efthimia I. Alevizou ◽  
Epaminondas C. Voutsas ◽  
Urszula Domańska
Keyword(s):  
Ionic Liquids ◽  
Phase Equilibrium

Prediction of Phase Equilibrium of Methane Hydrates in the Presence of Ionic Liquids

2013 ◽  
Vol 52 (47) ◽  
pp. 16985-16992 ◽  
Author(s):  
Huai-Ying Chin ◽  
Bong-Seop Lee ◽  
Yan-Ping Chen ◽  
Po-Chun Chen ◽  
Shiang-Tai Lin ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Phase Equilibrium ◽  
Methane Hydrates

Hybrid Particle Swarm-Ant Colony Algorithm to Describe the Phase Equilibrium of Systems Containing Supercritical Fluids with Ionic Liquids

2013 ◽  
Vol 14 (1) ◽  
pp. 107-125 ◽  
Author(s):  
Juan A. Lazzús
Keyword(s):  
Ionic Liquids ◽  
Phase Equilibrium ◽  
Supercritical Fluids ◽  
Ant Colony Algorithm ◽  
Particle Swarm ◽  
Ant Colony ◽  
Complex Mixtures ◽  
Binary Interaction ◽  
Binary Complex ◽  
Hybrid Particle

AbstractBased on biologically inspired algorithms, a thermodynamic model to describe the vapor-liquid equilibrium of binary complex mixtures containing supercritical fluids and ionic liquids, is presented. The Peng-Robinson equation of state with the Wong-Sandler mixing rules are used to evaluate the fugacity coefficient on the systems. Then, a hybrid particle swarm-ant colony optimization was used to minimize the difference between calculated and experimental bubble pressure, and calculate the binary interaction parameters for the excess Gibbs free energy of all systems used. Simulations are carried out in nine systems with imidazolium-based ionic liquids. The results show that the bubble pressures were correlated with low deviations between experimental and calculated values. These deviations show that the proposed hybrid algorithm is the preferable method to describe the phase equilibrium of these complex mixtures, and can be used for other similar systems.

Thermodynamic representation of ionic liquids phase equilibrium with the PDH-UNIQUAC-NRF model

2021 ◽  
pp. 118072
Author(s):  
Mahboobeh Ahmadi Gilakjani ◽  
Aliakbar Paraj ◽  
MohammadSaeed Afsharian
Keyword(s):  
Ionic Liquids ◽  
Phase Equilibrium
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