Solid–liquid equilibria and the physical properties of binary systems of diphenyl carbonate, dimethyl carbonate, methyl phenyl carbonate, anisole, methanol and phenol

2014 ◽  
Vol 376 ◽  
pp. 105-110 ◽  
Author(s):  
Sang Hong Shin ◽  
In-Yong Jeong ◽  
Yeong-Seok Jeong ◽  
So-Jin Park
Keyword(s):  
Physical Properties ◽  
Binary Systems ◽  
Dimethyl Carbonate ◽  
Diphenyl Carbonate ◽  
Solid Liquid ◽  
Methyl Phenyl

A green metrics assessment of phosgene and phosgene-free syntheses of industrially important commodity chemicals

2011 ◽  
Vol 84 (3) ◽  
pp. 827-860 ◽  
Author(s):  
John Andraos
Keyword(s):  
Dimethyl Carbonate ◽  
Phenyl Isocyanate ◽  
Diphenyl Carbonate ◽  
Commodity Chemicals ◽  
Methyl Phenyl

Synthesis plans for the following important industrial commodity chemicals using phosgene and phosgene-free chemistries have been analyzed and compared by green metrics to determine the most material-efficient routes so far developed (number of plans given in parentheses): dimethyl carbonate (DMC) (31), diphenyl carbonate (DPC) (40), diphenylurea (DPU) (23), methyl carbamate (MC) (8), methyl chloroformate (MCF) (6), methyl N-phenylcarbamate (MNPC) (25), methyl phenyl carbonate (MPC) (32), phenyl isocyanate (PI) (19), phenyl chloroformate (PCF) (10), and urea (13). Implications of these results are discussed.

scholarly journals Reaction from Dimethyl Carbonate (DMC) to Diphenyl Carbonate (DPC). 2. Kinetics of the Reactions from DMC via Methyl Phenyl Carbonate to DPC

2008 ◽  
Vol 47 (24) ◽  
pp. 9862-9870 ◽  
Author(s):  
J. Haubrock ◽  
W. Wermink ◽  
G. F. Versteeg ◽  
H. A. Kooijman ◽  
R. Taylor ◽  
...  
Keyword(s):  
Dimethyl Carbonate ◽  
Diphenyl Carbonate ◽  
Kinetics Of ◽  
Methyl Phenyl

Solid–liquid equilibria for selected binary systems containing diphenyl carbonate

2019 ◽  
Vol 479 ◽  
pp. 17-24
Author(s):  
Hiroyuki Matsuda ◽  
Yuki Ohashi ◽  
Kiyofumi Kurihara ◽  
Katsumi Tochigi ◽  
Kenji Ochi
Keyword(s):  
Binary Systems ◽  
Diphenyl Carbonate ◽  
Solid Liquid

scholarly journals Solubility of Anthraquinone Derivatives in Supercritical Carbon Dioxide: New Correlations

Molecules ◽  
2021 ◽  
Vol 26 (2) ◽  
pp. 460
Author(s):  
Ratna Surya Alwi ◽  
Chandrasekhar Garlapati ◽  
Kazuhiro Tamura
Keyword(s):  
Carbon Dioxide ◽  
Liquid Phase ◽  
Supercritical Carbon Dioxide ◽  
Binary Systems ◽  
Relative Deviation ◽  
Anthraquinone Derivatives ◽  
New Models ◽  
Solubility Isotherms ◽  
Solid Liquid ◽  
Supercritical Carbon

Solubility of several anthraquinone derivatives in supercritical carbon dioxide was readily available in the literature, but correcting ability of the existing models was poor. Therefore, in this work, two new models have been developed for better correlation based on solid–liquid phase equilibria. The new model has five adjustable parameters correlating the solubility isotherms as a function of temperature. The accuracy of the proposed models was evaluated by correlating 25 binary systems. The proposed models observed provide the best overall correlations. The overall deviation between the experimental and the correlated results was less than 11.46% in averaged absolute relative deviation (AARD). Moreover, exiting solubility models were also evaluated for all the compounds for the comparison purpose.

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