Concentration effects on the selective extraction of ethanol from aqueous solution using silicalite-1 and decanol isomers

2014 ◽  
Vol 362 ◽  
pp. 118-124 ◽  
Author(s):  
Samuel J. Keasler ◽  
Peng Bai ◽  
Michael Tsapatsis ◽  
J. Ilja Siepmann
2019 ◽  
Vol 7 (9) ◽  
pp. 8885-8892 ◽  
Author(s):  
Zhiyong Zhou ◽  
Haotian Liu ◽  
Jiahui Fan ◽  
Xueting Liu ◽  
Yafei Hu ◽  
...  

2016 ◽  
Vol 8 (14) ◽  
pp. 9523-9531 ◽  
Author(s):  
Huijin Zhang ◽  
Rocklan G. McDowell ◽  
Leigh R. Martin ◽  
You Qiang

2001 ◽  
Vol 79 (4) ◽  
pp. 448-454 ◽  
Author(s):  
Antonio Rojas ◽  
Alfonso Perez-Encabo ◽  
Ignacio Herraiz-Sierra ◽  
Carlos A Blanco

NMR and kinetics studies of the tautomeric equilibrium of 2-acetylcycloalkanones, 2-acetyl-1,3-cycloalkanediones, and methyl 2-oxocycloalkanecarboxylates of five- and six-membered rings have been carried out. By comparing 1H NMR and 13C NMR spectra recorded in D2O–DOCD3 and CDCl3, with those results derived using a bromination kinetic procedure in dilute aqueous solution, information concerning tautomeric interconversion is provided. Some discussions considering ionisation equilibria and rate constants involved have also been considered. Solvent and concentration effects on keto-enol equilibria have also been discussed.Key words: 2-acetylcycloalkanones, 2-acetyl-1,3-cycloalkanediones, methyl 2-oxocycloalkanecarboxylates, equilibrium, tautomerization, ionization.


2014 ◽  
Vol 49 (17) ◽  
pp. 2721-2727 ◽  
Author(s):  
Zhuqing Wang ◽  
Chen Dong ◽  
Min Wang ◽  
Youcun Chen ◽  
Genhua Wu

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