Partial and integral thermodynamic properties in the sodium chloride–water–1-butanol(iso-butanol) ternary systems

2011 ◽  
Vol 309 (1) ◽  
pp. 20-29 ◽  
Author(s):  
N.M. Konstantinova ◽  
M.S. Motornova ◽  
M.N. Mamontov ◽  
D.I. Shishin ◽  
I.A. Uspenskaya
Keyword(s):  
Sodium Chloride ◽  
Thermodynamic Properties ◽  
Ternary Systems ◽  
Chloride Water

Solubility of Indium Trichloride and Some Double Salts

1974 ◽  
Vol 52 (20) ◽  
pp. 3459-3462 ◽  
Author(s):  
Elinor M. Kartzmark
Keyword(s):  
Sodium Chloride ◽  
Calcium Chloride ◽  
Ternary Systems ◽  
Indium Chloride ◽  
Double Salts ◽  
Chloride Water

The solubility of indium trichloride in water has been determined in the range 25 to 110 °C. The ternary systems: indium chloride – sodium chloride–water; indium chloride–calcium chloride–water, and indium chloride–dioxane–water, have been investigated at 25 &([a-z]+);C. Three double salts have been found to occur, having the formulas: 6(InCl3•3H2O)•5(CaCl2•4H2O); InCl3•3C4H8O2•2H2O, and InCl3•2C4H8O2•2H2O.

THE RECIPROCAL SALT-PAIR SYSTEM: SODIUM CHLORIDE – AMMONIUM SULPHITE – SODIUM SULPHITE – AMMONIUM CHLORIDE – WATER AT 20 °C. AND 60 °C.: PART I. TERNARY SYSTEMS

1955 ◽  
Vol 33 (5) ◽  
pp. 774-786 ◽  
Author(s):  
J. A. Labash ◽  
G. R. Lusby
Keyword(s):  
Sodium Chloride ◽  
Ammonium Chloride ◽  
Solid Solutions ◽  
Ternary Systems ◽  
Sodium Sulphate ◽  
Sodium Sulphite ◽  
Solubility Data ◽  
Published Data ◽  
Double Salts ◽  
Chloride Water

Solubility data have been obtained at 20 °C. and 60 °C. for the following ternary systems:[Formula: see text]No evidence of the formation of double salts or of solid solutions in the first three systems was obtained. Ammonium sulphite monohydrate does not appear to dehydrate at 60 °C. in solutions saturated with sodium sulphite or ammonium chloride. In the study of the NaCl–NH4Cl–H2O system, the data agree with average values obtained from the literature and some discrepancies in the published data have been noted. In the NaCl–Na2SO3–H2O system some anomalous results can be explained on the basis of the existence of solid solutions of the hydrated and anhydrous forms of sodium sulphite and sodium sulphate.

The thermodynamic properties of solutions of sodium chloride, water, and 1-propanol

2010 ◽  
Vol 84 (7) ◽  
pp. 1098-1105 ◽  
Author(s):  
M. N. Mamontov ◽  
N. M. Konstantinova ◽  
E. S. Veryaeva ◽  
I. A. Uspenskaya
Keyword(s):  
Sodium Chloride ◽  
Thermodynamic Properties ◽  
Chloride Water

Calculation of phase diagrams and thermodynamic properties of 14 additive and reciprocal ternary systems containing Li2CO3, Na2CO3, K2CO3, Li2SO4, Na2SO4, K2SO4, LiOH, NaOH, and KOH

1984 ◽  
Vol 62 (3) ◽  
pp. 457-474 ◽  
Author(s):  
A. D. Pelton ◽  
C. W. Bale ◽  
P. L. Lin
Keyword(s):  
Phase Diagram ◽  
Thermodynamic Properties ◽  
Molten Salt ◽  
Phase Diagrams ◽  
Binary Systems ◽  
Ternary Phase ◽  
Ternary Phase Diagram ◽  
Ternary Systems ◽  
Maximum Error ◽  
Critical Assessment

Phase diagrams and thermodynamic properties of five additive molten salt ternary systems and nine reciprocal molten salt ternary systems containing the ions Li+, Na+, [Formula: see text], OH− are calculated from the thermodynamic properties of their binary subsystems which were obtained previously by a critical assessment of the thermodynamic data and the phase diagrams in these binary systems. Thermodynamic properties of ternary liquid phases are estimated from the binary properties by means of the Conformal Ionic Solution Theory. The ternary phase diagrams are then calculated from these thermodynamic properties by means of computer programs designed for the purpose. It is found that a ternary phase diagram can generally be calculated in this way with a maximum error about twice that of the maximum error in the binary phase diagrams upon which the calculations are based. If, in addition, some reliable ternary phase diagram measurements are available, these can be used to obtain small ternary correction terms. In this way, ternary phase diagram measurements can be smoothed and the isotherms drawn in a thermodynamically correct way. The thermodynamic approach permits experimental data to be critically assessed in the light of thermodynamic principles and accepted solution models. A critical assessment of error limits on all the calculated ternary diagrams is made, and suggestions as to which composition regions merit further experimental study are given.

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