Activity coefficients of rubidium chloride and cesium chloride in methanol–water mixtures and a comparative study of Pitzer and Pitzer–Simonson–Clegg models (298.15K)

2007 ◽  
Vol 251 (2) ◽  
pp. 137-144 ◽  
Author(s):  
Rui-Fang Cui ◽  
Man-Cheng Hu ◽  
Li-Hua Jin ◽  
Shu-Ni Li ◽  
Yu-Cheng Jiang ◽  
...  
2004 ◽  
Vol 33 (3) ◽  
pp. 487-498 ◽  
Author(s):  
Jawwad A. Qureshi ◽  
Lawrent L. Buschman ◽  
Sonny B. Ramaswamy ◽  
James E. Throne ◽  
Paul M. Whaley

2004 ◽  
Vol 33 (4) ◽  
pp. 930-940 ◽  
Author(s):  
Jawwad A. Qureshi ◽  
Lawrent L. Buschman ◽  
James E. Throne ◽  
Paul M. Whaley ◽  
Sonny B. Ramaswamy

2011 ◽  
Vol 32 (2) ◽  
pp. 135-154 ◽  
Author(s):  
Zdzisław Jaworski ◽  
Małgorzata Czernuszewicz ◽  
Łukasz Gralla

A comparative study of thermodynamic electrolyte models applied to the Solvay soda system Fast development of computation techniques for electrolyte activities contributed recently to introduction of a few substantial programmes for thermodynamic computing of multiphase systems. The presented study comprises useful information for practical computing using selected thermodynamic models of aqueous electrolyte solutions. Those models enable quantitative description of both phase and ionic equilibria and provide values of activity coefficients. The carried out analysis of individual models involved a comparison of their practical effectiveness features along with problems encountered in evaluation of the coefficients. The authors conclude that for the Solvay soda system the exUNIQUAC model for an in-house code or the MSE model for a commercial one can be used.


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