Preparation of highly porous activated carbons from peanut shells as low-cost electrode materials for supercapacitors

2021 ◽  
Vol 34 ◽  
pp. 102180
Author(s):  
Yinbo Zhan ◽  
Huiming Zhou ◽  
Feiqiang Guo ◽  
Beile Tian ◽  
Shilin Du ◽  
...  
Keyword(s):  
Electrode Materials ◽  
Activated Carbons ◽  
Low Cost ◽  
Peanut Shells ◽  
Highly Porous

Design and Synthesis of Highly Porous Activated Carbons from Sargassum as Advanced Electrode Materials for Supercapacitors

2019 ◽  
Vol 166 (14) ◽  
pp. A3109-A3118 ◽  
Author(s):  
Feiqiang Guo ◽  
Xiaopeng Jia ◽  
Shuang Liang ◽  
Xiaochen Jiang ◽  
Kuangye Peng ◽  
...  
Keyword(s):  
Electrode Materials ◽  
Activated Carbons ◽  
Design And Synthesis ◽  
Highly Porous

scholarly journals Highly Porous Graphitic Activated Carbons from Lignite via Microwave Pretreatment and Iron-Catalyzed Graphitization at Low-Temperature for Supercapacitor Electrode Materials

Processes ◽  
2019 ◽  
Vol 7 (5) ◽  
pp. 300 ◽  
Author(s):  
Dongdong Liu ◽  
Xiaoman Zhao ◽  
Rui Su ◽  
Zhengkai Hao ◽  
Boyin Jia ◽  
...  
Keyword(s):  
Low Temperature ◽  
Electrode Materials ◽  
Activated Carbons ◽  
Chemical Activation ◽  
Scale Up ◽  
Physical Activation ◽  
Supercapacitor Electrode ◽  
Microwave Pretreatment ◽  
Wide Range ◽  
Highly Porous

At present, the preparation of highly porous graphitic activated carbons (HPGACs) using the usual physical and chemical activation methods has met a bottleneck. In this study, HPGACs are directly synthesized from lignite at 900 °C. The whole process is completed by a microwave pretreatment, a graphitization conversion of the carbon framework at a low temperature using a small amount of FeCl3 (10–30 wt%), and a subsequent physical activation using CO2. Consequently, the dispersed and mobile iron species, in the absence of oxygen functional groups (removed during the microwave pretreatment), can greatly promote catalytic graphitization during pyrolysis, and, as an activating catalyst, can further facilitate the porosity development during activation. The as-obtained AC-2FeHLH-5-41.4(H) presents a low defect density, high purity, and specific surface area of 1852.43 m2 g−1, which is far greater than the AC-HLH-5-55.6(H) obtained solely by physical activation. AC-2FeHLH-5-41.4(H) as a supercapacitor electrode presents an excellent performance in the further electrochemical measurements. Such a convenient and practical method with low cost proves a scalable method to prepare HPGACs from a wide range of coal/biomass materials for industrial scale-up and applications.

Highly porous graphitic biomass carbon as advanced electrode materials for supercapacitors

2017 ◽  
Vol 19 (17) ◽  
pp. 4132-4140 ◽  
Author(s):  
Youning Gong ◽  
Delong Li ◽  
Chengzhi Luo ◽  
Qiang Fu ◽  
Chunxu Pan
Keyword(s):  
Electrode Materials ◽  
Low Cost ◽  
Biomass Carbon ◽  
Step Method ◽  
Supercapacitor Electrode ◽  
One Step ◽  
Supercapacitor Electrode Materials ◽  
Highly Porous

3D porous graphitic biomass carbon as advanced supercapacitor electrode materials synthesized by a low-cost and effective one-step method.

scholarly journals Highly Porous Carbons Synthesized from Tannic Acid via a Combined Mechanochemical Salt-Templating and Mild Activation Strategy

Molecules ◽  
2021 ◽  
Vol 26 (7) ◽  
pp. 1826
Author(s):  
Sylwia Głowniak ◽  
Barbara Szczęśniak ◽  
Jerzy Choma ◽  
Mietek Jaroniec
Keyword(s):  
Specific Surface ◽  
Tannic Acid ◽  
Activated Carbons ◽  
Low Cost ◽  
Chemical Activation ◽  
Total Pore Volume ◽  
Co2 Uptake ◽  
Potassium Oxalate ◽  
Templating Method ◽  
Highly Porous

Highly porous activated carbons were synthesized via the mechanochemical salt-templating method using both sustainable precursors and sustainable chemical activators. Tannic acid is a polyphenolic compound derived from biomass, which, together with urea, can serve as a low-cost, environmentally friendly precursor for the preparation of efficient N-doped carbons. The use of various organic and inorganic salts as activating agents afforded carbons with diverse structural and physicochemical characteristics, e.g., their specific surface areas ranged from 1190 m2·g−1 to 3060 m2·g−1. Coupling the salt-templating method and chemical activation with potassium oxalate appeared to be an efficient strategy for the synthesis of a highly porous carbon with a specific surface area of 3060 m2·g−1, a large total pore volume of 3.07 cm3·g−1 and high H2 and CO2 adsorption capacities of 13.2 mmol·g−1 at −196 °C and 4.7 mmol·g−1 at 0 °C, respectively. The most microporous carbon from the series exhibited a CO2 uptake capacity as high as 6.4 mmol·g−1 at 1 bar and 0 °C. Moreover, these samples showed exceptionally high thermal stability. Such activated carbons obtained from readily available sustainable precursors and activators are attractive for several applications in adsorption and catalysis.

scholarly journals Nanoporous Carbon Materials Derived from Washnut Seed with Enhanced Supercapacitance

Materials ◽  
2020 ◽  
Vol 13 (10) ◽  
pp. 2371 ◽  
Author(s):  
Ram Lal Shrestha ◽  
Timila Shrestha ◽  
Birendra Man Tamrakar ◽  
Rekha Goswami Shrestha ◽  
Subrata Maji ◽  
...  
Keyword(s):  
Surface Area ◽  
Electrode Materials ◽  
Carbon Materials ◽  
Activated Carbons ◽  
Low Cost ◽  
Rate Capability ◽  
Nanoporous Carbon ◽  
High Rate ◽  
Supercapacitor Electrode ◽  
Nanoporous Carbon Materials

Nanoporous activated carbons-derived from agro-waste have been useful as suitable and scalable low-cost electrode materials in supercapacitors applications because of their better surface area and porosity compared to the commercial activated carbons. In this paper, the production of nanoporous carbons by zinc chloride activation of Washnut seed at different temperatures (400–1000 °C) and their electrochemical supercapacitance performances in aqueous electrolyte (1 M H2SO4) are reported. The prepared nanoporous carbon materials exhibit hierarchical micro- and meso-pore architectures. The surface area and porosity increase with the carbonization temperature and achieved the highest values at 800 °C. The surface area was found in the range of 922–1309 m2 g−1. Similarly, pore volume was found in the range of 0.577–0.789 cm3 g−1. The optimal sample obtained at 800 °C showed excellent electrochemical energy storage supercapacitance performance. Specific capacitance of the electrode was calculated 225.1 F g−1 at a low current density of 1 A g−1. An observed 69.6% capacitance retention at 20 A g−1 indicates a high-rate capability of the electrode materials. The cycling stability test up to 10,000 cycles revealed the outstanding stability of 98%. The fascinating surface textural properties with outstanding electrochemical performance reveal that Washnut seed would be a feasible agro-waste precursor to prepare nanoporous carbon materials as a low-cost and scalable supercapacitor electrode.

scholarly journals Development of a simplified gas ultracleaning process: experiments in biomass residue-based fixed-bed gasification syngas

2021 ◽  
Author(s):  
Christian Frilund ◽  
Esa Kurkela ◽  
Ilkka Hiltunen
Keyword(s):  
Activated Carbons ◽  
Low Cost ◽  
Fixed Bed ◽  
Carbonyl Sulfide ◽  
Gas Analysis ◽  
Small Scale ◽  
Cleaning Process ◽  
Medium Temperature ◽  
Gas Cleaning ◽  
Adsorption Affinity

AbstractFor the realization of small-scale biomass-to-liquid (BTL) processes, low-cost syngas cleaning remains a major obstacle, and for this reason a simplified gas ultracleaning process is being developed. In this study, a low- to medium-temperature final gas cleaning process based on adsorption and organic solvent-free scrubbing methods was coupled to a pilot-scale staged fixed-bed gasification facility including hot filtration and catalytic reforming steps for extended duration gas cleaning tests for the generation of ultraclean syngas. The final gas cleaning process purified syngas from woody and agricultural biomass origin to a degree suitable for catalytic synthesis. The gas contained up to 3000 ppm of ammonia, 1300 ppm of benzene, 200 ppm of hydrogen sulfide, 10 ppm of carbonyl sulfide, and 5 ppm of hydrogen cyanide. Post-run characterization displayed that the accumulation of impurities on the Cu-based deoxygenation catalyst (TOS 105 h) did not occur, demonstrating that effective main impurity removal was achieved in the first two steps: acidic water scrubbing (AWC) and adsorption by activated carbons (AR). In the final test campaign, a comprehensive multipoint gas analysis confirmed that ammonia was fully removed by the scrubbing step, and benzene and H2S were fully removed by the subsequent activated carbon beds. The activated carbons achieved > 90% removal of up to 100 ppm of COS and 5 ppm of HCN in the syngas. These results provide insights into the adsorption affinity of activated carbons in a complex impurity matrix, which would be arduous to replicate in laboratory conditions.

Mesoporous Bi2S3 nanorods with graphene-assistance as low-cost counter-electrode materials in dye-sensitized solar cells

Nanoscale ◽  
2014 ◽  
Vol 6 (23) ◽  
pp. 14433-14440 ◽  
Author(s):  
Sheng-qi Guo ◽  
Tian-zeng Jing ◽  
Xiao Zhang ◽  
Xiao-bing Yang ◽  
Zhi-hao Yuan ◽  
...  
Keyword(s):  
Solar Cells ◽  
Conversion Efficiency ◽  
Counter Electrode ◽  
Electrode Materials ◽  
Low Cost ◽  
Dye Sensitized Solar Cells ◽  
Hydrothermal Conditions ◽  
Catalytic Activities ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

In this work, we report the synthesis of mesoporous Bi2S3 nanorods under hydrothermal conditions without additives, and investigated their catalytic activities as the CE in DSCs by I–V curves and tested conversion efficiency.

scholarly journals Synthesis of catalysts with fine platinum particles supported by high-surface-area activated carbons and optimization of their catalytic activities for polymer electrolyte fuel cells

RSC Advances ◽  
2021 ◽  
Vol 11 (33) ◽  
pp. 20601-20611
Author(s):  
Md. Mijanur Rahman ◽  
Kenta Inaba ◽  
Garavdorj Batnyagt ◽  
Masato Saikawa ◽  
Yoshiki Kato ◽  
...  
Keyword(s):  
Fuel Cells ◽  
Polymer Electrolyte ◽  
High Performance ◽  
Activated Carbons ◽  
Low Cost ◽  
High Surface ◽  
High Surface Area ◽  
Polymer Electrolyte Fuel Cells ◽  
Supported Platinum ◽  
Platinum Particles

Herein, we demonstrated that carbon-supported platinum (Pt/C) is a low-cost and high-performance electrocatalyst for polymer electrolyte fuel cells (PEFCs).

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