scholarly journals Carbonation of subduction-zone serpentinite (high-pressure ophicarbonate; Ligurian Western Alps) and implications for the deep carbon cycling

2016 ◽  
Vol 441 ◽  
pp. 155-166 ◽  
Author(s):  
Marco Scambelluri ◽  
Gray E. Bebout ◽  
Donato Belmonte ◽  
Mattia Gilio ◽  
Nicola Campomenosi ◽  
...  
2019 ◽  
Vol 60 (6) ◽  
pp. 1229-1262 ◽  
Author(s):  
Mattia Gilio ◽  
Marco Scambelluri ◽  
Samuele Agostini ◽  
Marguerite Godard ◽  
Daniel Peters ◽  
...  

AbstractIn the Western Alps, the ophiolitic Zermatt–Saas Zone (ZSZ) and the Lago di Cignana Unit (LCU) record oceanic lithosphere subduction to high (540°C, 2·3GPa) and ultra-high pressure (600°C, 3·2GPa), respectively. The top of the Zermatt–Saas Zone in contact with the Lago di Cignana Unit consists of olivine + Ti-clinohumite-bearing serpentinites (the Cignana serpentinite) hosting olivine + Ti-clinohumite veins and dykelets of olivine + Ti-chondrodite + Ti-clinohumite. The composition of this serpentinite reveals a refertilized oceanic mantle peridotite protolith that became subsequently enriched in fluid-mobile elements (FME) during oceanic serpentinization. The olivine + Ti-clinohumite veins in the Cignana serpentinite display Rare Earth Element (REE) and FME compositions quite similar to the host-rock, which suggests closed-system dehydration of this serpentinite during subduction. The Ti-chondrodite-bearing dykelets are richer in REE and FME than the host-rock and the dehydration olivine + Ti-clinohumite veins: their Nd composition points to a mafic protolith, successively overprinted by oceanic metasomatism and by subduction zone recrystallization. These dykelets are comparable in composition to eclogites within the ultra-high pressure LCU that derive from subducted oceanic mafic crust. Different from the LCU, serpentinites from the core domains of the ZSZ display REE compositions indicating a depleted mantle protolith. The oceanic serpentinization of these rocks led to an increase in FME and to seawater-like Sr isotope compositions. The serpentinites sampled at increasing distance from the ultra-high pressure LCU reveal different mantle protoliths, still preserve an oceanic geochemical imprint and contain mafic dykelets affected by oceanic metasomatism. The subduction zone history of these rocks thus occurred under relatively closed system conditions, the only possible change during subduction being an enrichment in As and Sb recorded by the serpentinites closer to the crustal LCU. The ZSZ and Cignana serpentinites thus likely evolved in a slab setting and were weakly exposed to interaction with slab-derived fluids characteristic of plate interface settings. Our data suggest two possible scenarios for the evolution of the studied ZSZ and Cignana serpentinites. They are either part of a coherent ophiolite unit whose initial lithospheric mantle was variably affected by depletion and re-fertilization processes, or they belong to separate tectonic slices derived from two different oceanic mantle sections. In the Cignana serpentinite atop the ZSZ, the presence of Ti-chondrodite dykelets similar in composition to the LCU eclogites suggests these two domains were closely associated in the oceanic lithosphere and shared the same evolution to ultra-high pressure conditions during Alpine subduction.


Minerals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 411
Author(s):  
Paola Tartarotti ◽  
Silvana Martin ◽  
Andrea Festa ◽  
Gianni Balestro

Ophiolites of the Alpine belt derive from the closure of the Mesozoic Tethys Ocean that was interposed between the palaeo-Europe and palaeo-Adria continental plates. The Alpine orogeny has intensely reworked the oceanic rocks into metaophiolites with various metamorphic imprints. In the Western Alps, metaophiolites and continental-derived units are distributed within two paired bands: An inner band where Alpine subduction-related high-pressure (HP) metamorphism is preserved, and an outer band where blueschist to greenschist facies recrystallisation due to the decompression path prevails. The metaophiolites of the inner band are hugely important not just because they provide records of the prograde tectonic and metamorphic evolution of the Western Alps, but also because they retain the signature of the intra-oceanic tectono-sedimentary evolution. Lithostratigraphic and petrographic criteria applied to metasediments associated with HP metaophiolites reveal the occurrence of distinct tectono-stratigraphic successions including quartzites with marbles, chaotic rock units, and layered calc schists. These successions, although sliced, deformed, and superposed in complex ways during the orogenic stage, preserve remnants of their primary depositional setting constraining the pre-orogenic evolution of the Jurassic Tethys Ocean.


2012 ◽  
Vol 4 (1) ◽  
pp. 745-781 ◽  
Author(s):  
C. J. Warren

Abstract. The exhumation of high and ultra-high pressure rocks is ubiquitous in Phanerozoic orogens created during continental collisions, and is common in many ocean-ocean and ocean-continent subduction zone environments. Three different tectonic environments have previously been reported, which exhume deeply buried material by different mechanisms and at different rates. However it is becoming increasingly clear that no single mechanism dominates in any particular tectonic environment, and the mechanism may change in time and space within the same subduction zone. In order for buoyant continental crust to subduct, it must remain attached to a stronger and denser substrate, but in order to exhume, it must detach (and therefore at least locally weaken) and be initially buoyant. Denser oceanic crust subducts more readily than more buoyant continental crust but exhumation must be assisted by entrainment within more buoyant and weak material such as serpentinite or driven by the exhumation of structurally lower continental crustal material. Weakening mechanisms responsible for the detachment of crust at depth include strain, hydration, melting, grain size reduction and the development of foliation. These may act locally or may act on the bulk of the subducted material. Metamorphic reactions, metastability and the composition of the subducted crust all affect buoyancy and overall strength. Subduction zones change in style both in time and space, and exhumation mechanisms change to reflect the tectonic style and overall force regime within the subduction zone. Exhumation events may be transient and occur only once in a particular subduction zone or orogen, or may be more continuous or occur multiple times.


2017 ◽  
Vol 60 (10) ◽  
pp. 1817-1825 ◽  
Author(s):  
RenBiao Tao ◽  
LiFei Zhang ◽  
Vincenzo Stagno ◽  
Xu Chu ◽  
Xi Liu

2018 ◽  
Vol 8 (1) ◽  
Author(s):  
Esther M. Schwarzenbach ◽  
Mark J. Caddick ◽  
Matthew Petroff ◽  
Benjamin C. Gill ◽  
Emily H. G. Cooperdock ◽  
...  

2002 ◽  
Vol 173 (1) ◽  
pp. 3-15 ◽  
Author(s):  
André Michard ◽  
Ahmed Chalouan ◽  
Hugues Feinberg ◽  
Bruno Goffé ◽  
Raymond Montigny

Abstract The Betic-Rif arcuate mountain belt (southern Spain, northern Morocco) has been interpreted as a symmetrical collisional orogen, partly collapsed through convective removal of its lithospheric mantle root, or else as resulting of the African plate subduction beneath Iberia, with further extension due either to slab break-off or to slab retreat. In both cases, the Betic-Rif orogen would show little continuity with the western Alps. However, it can be recognized in this belt a composite orocline which includes a deformed, exotic terrane, i.e. the Alboran Terrane, thrust through oceanic/transitional crust-floored units onto two distinct plates, i.e. the Iberian and African plates. During the Jurassic-Early Cretaceous, the yet undeformed Alboran Terrane was part of a larger, Alkapeca microcontinent bounded by two arms of the Tethyan-African oceanic domain, alike the Sesia-Margna Austroalpine block further to the northeast. Blueschist- and eclogite-facies metamorphism affected the Alkapeka northern margin and adjacent oceanic crust during the Late Cretaceous-Eocene interval. This testifies the occurrence of a SE-dipping subduction zone which is regarded as the SW projection of the western Alps subduction zone. During the late Eocene-Oligocene, the Alkapeca-Iberia collision triggered back-thrust tectonics, then NW-dipping subduction of the African margin beneath the Alboran Terrane. This Maghrebian-Apenninic subduction resulted in the Mediterranean basin opening, and drifting of the deformed Alkapeca fragments through slab roll back process and back-arc extension, as reported in several publications. In the Gibraltar area, the western tip of the Apenninic-Maghrebian subduction merges with that of the Alpine-Betic subduction zone, and their Neogene roll back resulted in the Alboran Terrane collage astride the Azores-Gibraltar transpressive plate boundary. Therefore, the Betic-Rif belt appears as an asymmetrical, subduction/collision orogen formed through a protracted evolution straightfully related to the Alpine-Apenninic mountain building.


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