scholarly journals Micropore clogging by leachable pyrogenic organic carbon: A new perspective on sorption irreversibility and kinetics of hydrophobic organic contaminants to black carbon

2017 ◽  
Vol 220 ◽  
pp. 1349-1358 ◽  
Author(s):  
Bingyu Wang ◽  
Wei Zhang ◽  
Hui Li ◽  
Heyun Fu ◽  
Xiaolei Qu ◽  
...  
Keyword(s):  
Organic Carbon ◽  
Black Carbon ◽  
Organic Contaminants ◽  
Hydrophobic Organic Contaminants ◽  
New Perspective ◽  
Kinetics Of

scholarly journals An investigation on hygroscopic properties of 15 black carbon (BC) from different carbon sources: Roles of organic and inorganic components

2020 ◽  
Author(s):  
Minli Wang ◽  
Yiqun Chen ◽  
Heyun Fu ◽  
Xiaolei Qu ◽  
Bengang Li ◽  
...  
Keyword(s):  
Water Vapor ◽  
Relative Humidity ◽  
Organic Carbon ◽  
Black Carbon ◽  
Water Uptake ◽  
Carbon Sources ◽  
High Relative Humidity ◽  
Gravimetric Analysis ◽  
Hygroscopic Properties ◽  
Kinetics Of

Abstract. The hygroscopic behavior of black carbon (BC) has a significant impact on global and regional climate change. However, the mechanism and factors controlling the hygroscopicity of BC from different carbon sources are not well understood. Here, we systematically measured the equilibrium and kinetics of water uptake by 15 different BC (10 herb-derived BC, 2 wood-derived BC, and 3 soot) using gravimetric water vapor sorption method combined with in-situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS). In the gravimetric analysis, the sorption/desorption equilibrium isotherms were measured under continuous-stepwise water vapor pressure conditions, while the kinetics was measured at a variety of humidity levels obtained by different saturated aqueous salt solutions. The equilibrium water uptake of the BC pool at high relative humidity (> 80 %) positively correlated to the dissolved mineral content (0.01–13.0 wt %) (R2 = 0.86, P = 0.0001) as well as the content of the thermogravimetrically analyzed organic carbon (OCTGA, 4.48–15.25 wt %) (R2 = 0.52, P = 0.002) and the alkali-extracted organic carbon (OCAE, 0.14–8.39 wt %) (R2 = 0.80, P = 0.0001). In contrast, no positive correlation was obtained with the content of total organic carbon or elemental carbon. Among the major soluble ionic constituents, chloride and ammonium were each correlated with the equilibrium water uptake at high relative humidity. Compared with the herbal BC and soot, the woody BC had much lower equilibrium water uptake, especially at high relative humidity, likely due to the very low dissolved material content and OC content. The DRIFTS analysis provided generally consistent results at low relative humidity. The kinetics of water uptake (measured by pseudo-second order rate constant) correlated to the content of OCTGA and OCAE as well as the content of chloride and ammonium at low relative humidity (33 %), but to the porosity of bulk BC at high relative humidity (94 %). This was the first study to show that BC of different types and sources has greatly varying hygroscopic properties.

scholarly journals An investigation on hygroscopic properties of 15 black carbon (BC)-containing particles from different carbon sources: roles of organic and inorganic components

2020 ◽  
Vol 20 (13) ◽  
pp. 7941-7954
Author(s):  
Minli Wang ◽  
Yiqun Chen ◽  
Heyun Fu ◽  
Xiaolei Qu ◽  
Bengang Li ◽  
...  
Keyword(s):  
Water Vapor ◽  
Relative Humidity ◽  
Organic Carbon ◽  
Black Carbon ◽  
Water Uptake ◽  
Mineral Content ◽  
Carbon Sources ◽  
High Relative Humidity ◽  
Hygroscopic Properties ◽  
Kinetics Of

Abstract. The hygroscopic behavior of black carbon (BC)-containing particles (BCPs) has a significant impact on global and regional climate change. However, the mechanism and factors controlling the hygroscopicity of BCPs from different carbon sources are not well understood. Here, we systematically measured the equilibrium and kinetics of water uptake by 15 different BCPs (10 herb-derived BCPs, 2 wood-derived BCPs, and 3 soot-type BCPs) using a gravimetric water vapor sorption method combined with in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS). In the gravimetric analysis, the sorption–desorption equilibrium isotherms were measured under continuous-stepwise water vapor pressure conditions, while the kinetics was measured at a variety of humidity levels obtained by different saturated aqueous salt solutions. The equilibrium water uptake of the tested group of BCPs at high relative humidity (>80 %) positively correlated to the dissolved mineral content (0.01–13.0 wt %) (R2=0.86, P=0.0001), the content of the thermogravimetrically analyzed organic carbon (OCTGA, 4.48–15.25 wt %) (R2=0.52, P=0.002), and the content of the alkali-extracted organic carbon (OCAE, 0.14–8.39 wt %) (R2=0.80, P=0.0001). In contrast, no positive correlation was obtained with the content of total organic carbon or elemental carbon. Among the major soluble ionic constituents, chloride and ammonium were each correlated with the equilibrium water uptake at high relative humidity. Compared with the herbal BCPs and soot, the woody BCPs had much lower equilibrium water uptake, especially at high relative humidity, likely due to the very low dissolved mineral content and OC content. The DRIFTS analysis provided generally consistent results at low relative humidity. The kinetics of water uptake (measured by pseudo-second-order rate constant) correlated to the content of OCTGA and OCAE as well as the content of chloride and ammonium at low relative humidity (33 %) but to the porosity of BCPs at high relative humidity (94 %). This was the first study to show that BCPs of different types and sources had greatly varying hygroscopic properties.

Bioavailability of hydrophobic organic contaminants and quality of organic carbon

2004 ◽  
Vol 2 (2) ◽  
Author(s):  
HerbertL. Fredrickson ◽  
John Furey ◽  
JeffreyW. Talley ◽  
Margaret Richmond
Keyword(s):  
Organic Carbon ◽  
Organic Contaminants ◽  
Hydrophobic Organic Contaminants

Kinetics of Organic Carbon Consumption by Yeast Strain UY7

2011 ◽  
Vol 47 (1) ◽  
pp. 1-7
Author(s):  
WATARU TAKATSUJI ◽  
YOSHINOBU YAMAGIWA ◽  
KENJI FURUKAWA
Keyword(s):  
Organic Carbon ◽  
Yeast Strain ◽  
Carbon Consumption ◽  
Kinetics Of

scholarly journals Seasonal and diurnal variations of black carbon and organic carbon aerosols in Bangkok

2011 ◽  
Vol 116 (D15) ◽  
Author(s):  
L. K. Sahu ◽  
Y. Kondo ◽  
Y. Miyazaki ◽  
Prapat Pongkiatkul ◽  
N. T. Kim Oanh
Keyword(s):  
Organic Carbon ◽  
Black Carbon ◽  
Diurnal Variations ◽  
Seasonal And Diurnal Variations ◽  
Carbon Aerosols
Sign in / Sign up

Export Citation Format

Share Document