scholarly journals Combined analysis of trace elements and isotopic composition of particulate organic matter in suspended sediment to assess their origin and flux in a tropical disturbed watershed

2016 ◽  
Vol 218 ◽  
pp. 844-854 ◽  
Author(s):  
Alexandre Martins Fernandes ◽  
Christophe Hissler ◽  
Fabiano Tomazini da Conceição ◽  
Eder Paulo Spatti Junior ◽  
Jefferson Mortatti
Keyword(s):  
Trace Elements ◽  
Organic Matter ◽  
Isotopic Composition ◽  
Suspended Sediment ◽  
Particulate Organic Matter ◽  
Combined Analysis

Structural and dynamic properties of soil organic-matter as reflected by 13C natural-abundance, pyrolysis mass-spectrometry and solid-state 13C NMR-spectroscopy in density fractions of an oxisol under forest and pasture

Soil Research ◽  
1995 ◽  
Vol 33 (1) ◽  
pp. 59 ◽  
Author(s):  
A Golchin ◽  
JM Oades ◽  
JO Skjemstad ◽  
P Clarke
Keyword(s):  
Organic Matter ◽  
Soil Organic Matter ◽  
Isotopic Composition ◽  
Particulate Organic Matter ◽  
Organic Materials ◽  
Natural Abundance ◽  
13C Natural Abundance ◽  
Clay Particles ◽  
Density Fractions ◽  
Soil Organic Matter Turnover

Changes in the content and isotopic composition of organic carbon as a consequence of deforestation and pasture establishment were studied in three neighbouring areas on an Oxisol from Australia and used to measure the turnover of forest-derived carbon (C3) under pasture (C4) over 35 and 83 year time scales. The results indicated that the quantity of forest-derived carbon declined rapidly during the first 35 years under pasture but the content remained nearly stable thereafter, suggesting the presence of two pools of carbon with different turnover times. The calculated values for turnover time of labile and resistant fractions of forest-derived carbon were 35 and 144 years respectively. The soil samples were separated into five fractions with densities <1.6 (free and occluded), 1.6-1.8, 1.8-2.0 and >2.0 Mg m-3. Based on the spatial distribution of organic materials within the mineral matrix of soil, the soil organic matter contained in different density fractions was classified as free particulate organic matter (1.6 free), occluded particulate organic matter (<1.6 occluded, 1.6-1.8 and 1.8-2.0) and clay associated organic matter (>2.0 Mg m-3). The 13C natural abundance showed that the free particulate organic matter formed a significant pool for soil organic matter turnover when the forest was replaced by pasture. Compared with free particulate organic matter, the organic materials occluded within aggregates had slower turnover times. The occluded organic materials were in different stages of decomposition and had different chemical stabilities. Comparison of the chemistry and isotopic composition of occluded organic materials indicated that the O-alkyl C content of the occluded organic materials was inversely related to their stabilities whereas their aromatic C content was directly related to their stabilities. In soils under pasture, a considerable amount of forest-derived carbon was associated with clay particles in the fractions .2.0 Mg m-3. The rate of accumulation of pasture-derived carbon was also rapid in this fraction, indicating the presence of two different pools of carbon (C3 and C4) associated with clay particles. The forest-derived carbon had the highest stability in the fractions >2.0 Mg m-3, probably due to strong interaction with active aluminium or iron and aluminium oxides associated with clay surfaces.

scholarly journals Isotopic composition of nitrate and particulate organic matter in a pristine dam reservoir of western India: implications for biogeochemical processes

2017 ◽  
Vol 14 (4) ◽  
pp. 767-779 ◽  
Author(s):  
Pratirupa Bardhan ◽  
Syed Wajih Ahmad Naqvi ◽  
Supriya G. Karapurkar ◽  
Damodar M. Shenoy ◽  
Siby Kurian ◽  
...  
Keyword(s):  
Organic Matter ◽  
Isotopic Composition ◽  
Particulate Organic Matter ◽  
Nitrogen Isotopes ◽  
Indian Subcontinent ◽  
Southwest Monsoon ◽  
Early Summer ◽  
Western India ◽  
N Fixation ◽  
Nitrogen Transformations

Abstract. Isotopic composition of nitrate (δ15N and δ18O) and particulate organic matter (POM; δ15N and δ13C) were measured in the Tillari Reservoir, located at the foothills of the Western Ghats, Maharashtra, western India. The reservoir, which is stratified during spring–summer and autumn seasons but gets vertically mixed during the southwest monsoon (SWM) and winter, is characterized by diverse redox nitrogen transformations in space and time. The δ15N and δ18O values of nitrate were low (δ15N  =  2–10 ‰, δ18O  =  5–8 ‰) during normoxic conditions but increased gradually (the highest at δ15N  =  27 ‰, δ18O  =  29 ‰) when anoxic conditions facilitated denitrification in the hypolimnion during spring–early summer. Once nitrate was fully utilized and sulfidic conditions set in, NH4+ became the dominant inorganic N species, with δ15N ranging from 1.3 to 2.6 ‰. Low δ15N (∼ −5 ‰) and δ13C (−37 to −32 ‰) of POM co-occurring with high NH4+ and CH4 in sulfidic bottom waters were probably the consequence of microbial chemosynthesis. Assimilation of nitrate in the epilimnion was the major controlling process on the N isotopic composition of POM (δ15N  =  2–6 ‰). Episodic low δ15N values of POM (−2 to 0 ‰) during early summer, coinciding with the absence of nitrate, might arise from N fixation, although further work is required to confirm the hypothesis. δ13C POM in the photic zone ranged between −29 and −27 ‰ for most parts of the year. The periods of mixing were characterized by uniform δ15N–NO3− and δ18O–NO3− at all depths. Higher POM (particulate organic carbon, POC, as well as particulate organic nitrogen, PON) contents and C ∕ N values with lower δ13C POM during the SWM point to allochthonous inputs. Overall, this study, the first of its kind in the Indian subcontinent, provides an insight into biogeochemistry of Indian reservoirs, using stable carbon and nitrogen isotopes as a tool, where the monsoons play an important role in controlling vertical mixing and dynamics of carbon and nutrients.

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