In situ sorption of hydrophobic organic compounds to sediment amended with activated carbon

2012 ◽  
Vol 161 ◽  
pp. 23-29 ◽  
Author(s):  
D. Kupryianchyk ◽  
M.I. Rakowska ◽  
J.T.C. Grotenhuis ◽  
A.A. Koelmans
2016 ◽  
Vol 74 (4) ◽  
pp. 852-860 ◽  
Author(s):  
Karin Björklund ◽  
Loretta Y. Li

Treatment of stormwater via sorption has the potential to remove both colloidal and dissolved pollutants. Previous research shows that activated carbon produced from sewage sludge is very efficient in sorbing hydrophobic organic compounds (HOCs), frequently detected in stormwater. The aim of this research was to determine whether the presence of dissolved organic matter (DOM) has a negative effect on the adsorption of HOCs onto sludge-based activated carbon (SBAC) in batch adsorption tests. Batch adsorption tests were used to investigate the influence of two types of DOM – soil organic matter and humic acid (HA) technical standard – on the sorption of HOCs onto SBAC, and whether preloading adsorbent and adsorbates with DOM affects HOC sorption. The results indicate that soil DOM and HAs do not have a significant negative effect on the adsorption of HOCs under tested experimental conditions, except for a highly hydrophobic compound. In addition, preloading SBAC or HOCs with DOM did not lead to lower adsorption of HOCs. Batch adsorption tests appear to be inefficient for investigating DOM effects on HOC adsorption, as saturating the carbon is difficult because of high SBAC adsorption capacity and low HOC solubility, so that limited competition occurs on the sorbent.


2006 ◽  
Vol 14 (2) ◽  
pp. 478-482
Author(s):  
Jamie Robinson ◽  
Russell Thomas ◽  
Steve Wallace ◽  
Paddy Daly ◽  
Robert Kalin

1973 ◽  
Vol 8 (1) ◽  
pp. 110-121
Author(s):  
A. Netzer ◽  
J.D. Norman

Abstract The merits of activated carbon for removal of organic compounds from wastewater have been well documented in the literature. On the other hand there is a lack of published data on the use of activated carbon for the removal of trace metals from wastewater. Experiments were designed to assess the possibility that activated carbon treatment would remove aluminum, cadmium, chromium, cobalt, copper, iron, lead, manganese, mercury, nickel, silver and zinc from wastewater. All metals studied were tested over the pH range 3-11. Greater than 99.5% removal was achieved by pH adjustment and activated carbon treatment for most of the metals tested.


1987 ◽  
Vol 19 (3-4) ◽  
pp. 471-482 ◽  
Author(s):  
W. J. Weber ◽  
B. E. Jones ◽  
L. E. Katz

The addition of powdered activated carbon (PAC) to activated sludge treatment systems to enhance removal of specific toxic organic compounds from wastewater was evaluated. Nine organic compounds encompassing a range of solubility, volatility, biodegradability, and adsorptive properties were studied. Kate and equilibrium investigations were conducted to quantify the removal mechanisms of volatilization, biodegradation, biosorption, and carbon adsorption. Results from steady-state bioreactor studies showed that the addition of less than 100 mg/ℓ powdered activated carbon to the influent did not enhance the removal of the biodegradable target compounds investigated: benzene, toluene, ethylbenzene, o-xylene, chlorobenzene, and nitrobenzene. Significantly improved removals of the poorly degradable and non-biodegradable compounds 1,2-dichlorobenzene, 1,2,4-trichlorobenzene, and lindane occurred at influent powdered carbon concentrations in the 12.5 to 25 mg/ℓ range. Influent powdered carbon concentrations of 100 mg/ℓ effected overall removals of greater than 90%. The addition of powdered activated carbon not only reduced effluent concentrations but also reduced the amounts of the volatile compounds stripped to the atmosphere.


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