Numerical study on the impact of a temperature step on the electrical double layer

2018 ◽  
Vol 95 ◽  
pp. 13-23 ◽  
Author(s):  
Paul Daniel Stanley Clermont ◽  
Thierry Paillat ◽  
Paul Leblanc
Keyword(s):  
Double Layer ◽  
Electrical Double Layer ◽  
Numerical Study ◽  
Temperature Step ◽  
The Impact

scholarly journals Numerical Study on Propagation of Ice Breaking Shock Waves in Process of Breaking Ice by Double-Layer Charge Blasting

2021 ◽  
pp. 91-98
Author(s):  
Xuemei Zhang ◽  
Yuanli Wu ◽  
Zhigang Xie ◽  
Chaosong Kong ◽  
Zhizong Tian
Keyword(s):  
Shock Wave ◽  
Double Layer ◽  
Delay Time ◽  
Peak Pressure ◽  
Numerical Study ◽  
Layer Charge ◽  
Wave Pressure ◽  
Shock Wave Pressure ◽  
Double Charge ◽  
The Impact

The ice-breaking process of the double-layer charge at a depth of 150 cm underwater is simulated by LS-DYNA. This paper analyzes the load type, shock wave pressure characteristics and propagation behavior of the double-layer charge during underwater explosion. By analyzing the impact of the shock wave pressure in the water under different charge intervals and time intervals on the shock wave pressure of the double charge, it is concluded that the peak pressure of the double charge explosion shock wave is jointly determined by the double charge. In this range, the second peak pressure value of the drug is greater than the pressure value of the first peak of the drug, and the attenuation is slow; the delay time of the upper charge has little effect on the peak pressure value of the shock wave in the water; the delay time is higher than that of the lower charge Initiation, at the same position, the total pressure peak of the shock wave formed by the delay of the upper charge is larger.

Modeling the Electrical Double Layer to Understand the Reaction Environment in a CO2 Electrocatalytic System

2019 ◽  
Author(s):  
Divya Bohra ◽  
Jehanzeb Chaudhry ◽  
Thomas Burdyny ◽  
Evgeny Pidko ◽  
wilson smith
Keyword(s):  
Electric Field ◽  
Double Layer ◽  
Electrical Double Layer ◽  
Surface Reaction ◽  
Catalyst Surface ◽  
Local Reaction ◽  
Reaction Diffusion ◽  
Alkali Metal Cations ◽  
Applied Potential ◽  
Critical Aspect

<p>The environment of a CO<sub>2</sub> electroreduction (CO<sub>2</sub>ER) catalyst is intimately coupled with the surface reaction energetics and is therefore a critical aspect of the overall system performance. The immediate reaction environment of the electrocatalyst constitutes the electrical double layer (EDL) which extends a few nanometers into the electrolyte and screens the surface charge density. In this study, we resolve the species concentrations and potential profiles in the EDL of a CO<sub>2</sub>ER system by self-consistently solving the migration, diffusion and reaction phenomena using the generalized modified Poisson-Nernst-Planck (GMPNP) equations which include the effect of volume exclusion due to the solvated size of solution species. We demonstrate that the concentration of solvated cations builds at the outer Helmholtz plane (OHP) with increasing applied potential until the steric limit is reached. The formation of the EDL is expected to have important consequences for the transport of the CO<sub>2</sub> molecule to the catalyst surface. The electric field in the EDL diminishes the pH in the first 5 nm from the OHP, with an accumulation of protons and a concomitant depletion of hydroxide ions. This is a considerable departure from the results obtained using reaction-diffusion models where migration is ignored. Finally, we use the GMPNP model to compare the nature of the EDL for different alkali metal cations to show the effect of solvated size and polarization of water on the resultant electric field. Our results establish the significance of the EDL and electrostatic forces in defining the local reaction environment of CO<sub>2</sub> electrocatalysts.</p>

scholarly journals Model of thermal buoyancy in cavity-ventilated roof constructions

2021 ◽  
pp. 174425912098418
Author(s):  
Toivo Säwén ◽  
Martina Stockhaus ◽  
Carl-Eric Hagentoft ◽  
Nora Schjøth Bunkholt ◽  
Paula Wahlgren
Keyword(s):  
Analytical Model ◽  
Flow Rate ◽  
Numerical Study ◽  
Air Flow ◽  
Wind Pressure ◽  
Air Flow Rate ◽  
Test Set ◽  
Air Cavity ◽  
Thermal Buoyancy ◽  
The Impact

Timber roof constructions are commonly ventilated through an air cavity beneath the roof sheathing in order to remove heat and moisture from the construction. The driving forces for this ventilation are wind pressure and thermal buoyancy. The wind driven ventilation has been studied extensively, while models for predicting buoyant flow are less developed. In the present study, a novel analytical model is presented to predict the air flow caused by thermal buoyancy in a ventilated roof construction. The model provides means to calculate the cavity Rayleigh number for the roof construction, which is then correlated with the air flow rate. The model predictions are compared to the results of an experimental and a numerical study examining the effect of different cavity designs and inclinations on the air flow rate in a ventilated roof subjected to varying heat loads. Over 80 different test set-ups, the analytical model was found to replicate both experimental and numerical results within an acceptable margin. The effect of an increased total roof height, air cavity height and solar heat load for a given construction is an increased air flow rate through the air cavity. On average, the analytical model predicts a 3% higher air flow rate than found in the numerical study, and a 20% lower air flow rate than found in the experimental study, for comparable test set-ups. The model provided can be used to predict the air flow rate in cavities of varying design, and to quantify the impact of suggested roof design changes. The result can be used as a basis for estimating the moisture safety of a roof construction.

scholarly journals Numerical Simulation of the Impact of the Heat Source Position on Melting of a Nano-Enhanced Phase Change Material

Nanomaterials ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 1425
Author(s):  
Tarek Bouzennada ◽  
Farid Mechighel ◽  
Kaouther Ghachem ◽  
Lioua Kolsi
Keyword(s):  
Heat Transfer ◽  
Phase Change ◽  
Phase Change Material ◽  
Numerical Study ◽  
Melting Rate ◽  
Heat Transfer Fluid ◽  
Commercial Code ◽  
Tube Position ◽  
The Impact ◽  
Change Material

A 2D-symmetric numerical study of a new design of Nano-Enhanced Phase change material (NEPCM)-filled enclosure is presented in this paper. The enclosure is equipped with an inner tube allowing the circulation of the heat transfer fluid (HTF); n-Octadecane is chosen as phase change material (PCM). Comsol-Multiphysics commercial code was used to solve the governing equations. This study has been performed to examine the heat distribution and melting rate under the influence of the inner-tube position and the concentration of the nanoparticles dispersed in the PCM. The inner tube was located at three different vertical positions and the nanoparticle concentration was varied from 0 to 0.06. The results revealed that both heat transfer/melting rates are improved when the inner tube is located at the bottom region of the enclosure and by increasing the concentration of the nanoparticles. The addition of the nanoparticles enhances the heat transfer due to the considerable increase in conductivity. On the other hand, by placing the tube in the bottom area of the enclosure, the liquid PCM gets a wider space, allowing the intensification of the natural convection.

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